New Concept For Multilayer Films

  • ChemPubSoc Europe Logo
  • Author: ChemViews
  • Published Date: 25 April 2011
  • Source / Publisher: Angewandte Chemie International Edition/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: New Concept For Multilayer Films

Self-assembly of structures such as nanoparticles, lipid bilayers, and phase-separated polymers is mainly observed in the bulk phase of solutions. The self-assembly of monolayers is also possible, but the formation of films extending beyond the monolayer remains a challenge.


A strategy for the electrochemically triggered assembly of films has been reported by Pierre Schaaf and colleagues, Centre National de la Recherche Scientifique, Strasbourg, France. They generate a  Cu(I) morphogen, a concentration dependent response molecule. The morphogens are produced electrochemically at an electrode surface from Cu(II) ions present in the solution. They diffuse away from the electrode surface into a polymer solution containing two functionalized polymers, one bearing azide groups and the other alkyne groups. They catalyze a click reaction which leads to the continuous
buildup of a film through formation of triazole molecules between the azide- and alkyne-bearing units at the film/solution interface.


This is a new method conceptually different to the electropolymerization process and the layer-by-layer method for producing multilayer films which gives researchers another tool in their toolbox.


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