ChemPubSoc Europe Early View Journal Articles

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The Effect of Ambient Carbon Dioxide on Anion‐Exchange Membrane Fuel Cells

Published: 15 March 2018

Author(s): Noga Ziv, William E. Mustain, Dario R. Dekel

Abstract Over the past 10 years, there has been a surge of interest in anion‐exchange membrane fuel cells (AEMFCs) as a potentially lower cost alternative to proton‐exchange membrane fuel cells (PEMFCs). Recent work has shown that AEMFCs achieve nearly identical performance to that of state‐of‐the‐art PEMFCs; however, much of that data has been collected while feeding CO2‐free air or pure oxygen to the cathode. Usually, removing CO2 from the...

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Design of Highly Potent, Dual‐Acting and Central‐Nervous‐System‐Penetrating HIV‐1 Protease Inhibitors with Excellent Potency against Multidrug‐Resistant HIV‐1 Variants

Published: 15 March 2018

Author(s): Arun K. Ghosh, Kalapala Venkateswara Rao, Prasanth R. Nyalapatla, Satish Kovela, Margherita Brindisi, Heather L. Osswald, Bhavanam Sekhara Reddy, Johnson Agniswamy, Yuan‐Fang Wang, Manabu Aoki, Shin‐ichiro Hattori, Irene T. Weber, Hiroaki Mitsuya

Abstract Herein we report the design, synthesis, X‐ray structural, and biological studies of an exceptionally potent HIV‐1 protease inhibitor, compound 5 ((3S,7aS,8S)‐hexahydro‐4H‐3,5‐methanofuro[2,3‐b]pyran‐8‐yl ((2S,3R)‐4‐((2‐(cyclopropylamino)‐N‐isobutylbenzo[d]thiazole)‐6‐sulfonamido)‐1‐(3,5‐difluorophenyl)‐3‐hydroxybutan‐2‐yl)carbamate). Using structure‐based design, we incorporated an unprecedented 6‐5‐5‐ring‐fused crown‐like...

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Novel Peroxides as Promising Anticancer Agents with Unexpected Depressed Antimalarial Activity

Published: 15 March 2018

Author(s): Paolo Coghi, Ivan A. Yaremenko, Parichat Prommana, Peter S. Radulov, Mikhail A. Syroeshkin, Yu Jun Wu, Jia Ying Gao, Floria M. Gordillo, Simon Mok, Vincent Kam Wai Wong, Chairat Uthaipibull, Alexander O. Terent'ev

Abstract Twenty six peroxides belonging to bridged 1,2,4,5‐tetraoxanes, bridged 1,2,4‐trioxolanes (ozonides), and tricyclic monoperoxides were evaluated for their in vitro antimalarial activity against Plasmodium falciparum (3D7) and for their cytotoxic activities against immortalized human normal fibroblast (CCD19Lu), liver (LO2), and lung (BEAS‐2B) cell lines as well as human liver (HepG2) and lung (A549) cancer‐cell lines. Synthetic ozonides were ...

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Stacking Interactions of Heterocyclic Drug Fragments with Protein Amide Backbones

Published: 15 March 2018

Author(s): Andrea N. Bootsma, Steven E. Wheeler

Abstract Stacking interactions can be important enthalpic contributors to drug binding. Among the less well‐studied stacking interactions are those occurring between an arene and the π‐face of an amide group. Given the ubiquity of heterocycles in drugs, combined with the abundance of amides in the protein backbone, optimizing these noncovalent interactions can provide a potential route to enhanced drug binding. Previously, Diederich...

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Wet Imprinting of Channel‐Type Superstructures in Nanostructured Titania Thin Films at Low Temperatures for Hybrid Solar Cells

Published: 15 March 2018

Author(s): Lin Song, Tianyi Wang, Volker Körstgens, Weijia Wang, Nitin Saxena, Christoph J. Schaffer, Thomas Fröschl, Nicola Hüsing, Sigrid Bernstorff, Peter Müller‐Buschbaum

Abstract Hierarchically structured titania films, exhibiting interconnected foam‐like nanostructures and large‐scale channel‐type superstructures, were achieved in an energy‐saving way at low temperatures by a polymer template‐assisted sol–gel synthesis in combination with a wet‐imprinting process. The surface morphology was probed with scanning electron microscopy and atomic force microscopy, whereas the inner morphology was...

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Tuning a Protein‐Labeling Reaction to Achieve Highly Site Selective Lysine Conjugation

Published: 15 March 2018

Author(s): Grace H. Pham, Weijia Ou, Badry Bursulaya, Michael DiDonato, Ananda Herath, Yunho Jin, Xueshi Hao, Jon Loren, Glen Spraggon, Ansgar Brock, Tetsuo Uno, Bernhard H. Geierstanger, Susan E. Cellitti

Abstract Activated esters are widely used to label proteins at lysine side chains and N termini. These reagents are useful for labeling virtually any protein, but robust reactivity toward primary amines generally precludes site‐selective modification. In a unique case, fluorophenyl esters are shown to preferentially label human kappa antibodies at a single lysine (Lys188) within the light‐chain constant domain. Neighboring residues...

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A Sulfonozanamivir Analogue Has Potent Anti‐influenza Virus Activity

Published: 15 March 2018

Author(s): Ádám Hadházi, Linghui Li, Benjamin Bailly, Andrea Maggioni, Gael Martin, Larissa Dirr, Jeffrey C. Dyason, Robin J. Thomson, George F. Gao, Anikó Borbás, Thomas Ve, Mauro Pascolutti, Mark von Itzstein

Abstract Influenza virus infection continues to cause significant, often severe, respiratory illness worldwide. A validated target for the development of anti‐influenza agents is the virus surface protein sialidase. In the current study, we have discovered a highly potent inhibitor of influenza virus sialidase, based on a novel sialosyl sulfonate template. The synthesised 3‐guanidino sialosyl α‐sulfonate, a sulfonozanamivir...

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Serendipitous Observation of Liquid‐Phase Size Selectivity inside a Mesoporous Silica Nanoreactor in the Reaction of Chromene with Formic Acid

Published: 15 March 2018

Author(s): Paramita Das, Suman Ray, Piyali Bhanja, Asim Bhaumik, Chhanda Mukhopadhyay

Abstract An unprecedented product shape/size selectivity in the hydrolysis/decarboxylation reaction sequences of chromene with formic acid within MCM‐41 as a nanoreactor in the liquid phase is observed. Chromene is expected to form pyrimidine in the reaction with HCOOH. However, here, serendipitously, the product switches from pyrimidine to enol lactones and δ‐keto acids inside the nanoreactor. The shape/size selectivity in the liquid phase is...

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Metal Catalysts for the Efficient Transformation of Biomass‐derived HMF and Furfural to Value Added Chemicals

Published: 15 March 2018

Author(s): Kavita Gupta, Rohit K. Rai, Sanjay K. Singh

Abstract Catalytic transformation of biomass‐derived compounds to different platform chemicals and liquid fuel is a prominent way to reduce the global dependence on fossil resources. In past few decades, biomass‐derived furans such as 2‐furfuraldehyde (furfural) and 5‐hydroxymethyl‐2‐furfural (HMF) have received outstanding attention because of their wide applications in the production of various industrially important value‐added...

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Ultrapermeable Nickel–Cobalt–Manganese/Alumina Inverse Opal as a Coke‐Tolerant and Pressure‐Drop‐Free Catalyst for the Dry Reforming of Methane

Published: 15 March 2018

Author(s): Won Yong Kim, Byung Jun Lee, Hunmin Park, Yo Han Choi, Ju Hun Kim, Jae Sung Lee

Abstract An inverse opal‐structured Ni‐Co‐Mn/Al2O3 catalyst with ultrahigh permeability was prepared by a sol–gel method templated by poly(methyl methacrylate) opal‐structured nanospheres. This catalyst exhibited excellent coke tolerance and a negligible reactor pressure drop in the dry reforming of methane. The highly permeable, unique macroporous structure allowed facile mass transport, which not only reduced the amount of coke...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2018


Nan Zhao, Shuqiang Yin, Shengling Xie, Hao Yan, Pan Ren, Gui Chen, Fang Chen, Jing Xu
Total Synthesis of Astellatol [Communication]
Angew. Chem. Int. Ed. 10.1002/anie.201800167

Aitao Li, Carlos G. Acevedo-Rocha, Zhoutong Sun, Tony Cox, Jia Lucy Xu, Manfred T. Reetz
Beating Bias in the Directed Evolution of Proteins: Combining High-Fidelity on-Chip Solid-Phase Gene Synthesis with Efficient Gene Assembly for Combinatorial Library Construction [Full Paper]
ChemBioChem 2018, vol. 19, p. 221

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Lukas Raddatz, Jonas Austerjost, Sascha Beutel
3D-Druck: Chancen, Möglichkeiten, Risiken [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 42

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Ping Zhang, Nopphon Weeranoppanant, Dale A. Thomas, Kohei Tahara, Torsten Stelzer, Mary Grace Russell, Marcus O'Mahony, Allan S. Myerson, Hongkun Lin, Liam P. Kelly, Klavs F. Jensen, Timothy F. Jamison, Chunhui Dai, Yuqing Cui, Naomi Briggs, Rachel L. Beingessner, Andrea Adamo
Advanced Continuous Flow Platform for On-Demand Pharmaceutical Manufacturing [Full Paper]
Chem. Eur. J. 2018, vol. 24, p. 2776

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Zhi-Xiang Yu, Biao Yu, Xiao-Bing Lu, Jian Pei
Organic Chemistry for the Future [Editorial]
Asian J. Org. Chem. 10.1002/ajoc.201800077

Chris de Graaf, Albert J. Kooistra, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Ross McGuire, Márton Vass
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 10.1002/cmdc.201700754

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Ferdi Karadas, Ekmel Ozbay, Amir Ghobadi, Turkan Gamze Ulusoy Ghobadi
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 10.1002/cptc.201700165

Jiwhan Kim, Hee-Eun Kim, Hyunjoo Lee
Single-Atom Catalysts of Precious Metals for Electrochemical Reactions [Minireview]
ChemSusChem 2018, vol. 11, p. 104

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai
Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper]
Eur. J. Org. Chem. 2016, p. 331

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 19

Die neue Macht des Forschers [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 103

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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