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Enhancing Oxygen Storage Capability and Catalytic Activity of Lanthanum Oxysulfide (La 2 O 2 S) Nanocatalysts by Sodium and Iron/Sodium Doping

Published: 14 December 2017

Author(s): Shuai Tan, Dongmei Li

Abstract We report the enhanced oxygen storage capability (OSC) and activity of lanthanum oxysulfide (La2O2S) nanocatalysts, derived from the introduction of oxygen vacancies by sodium (Na) doping. Additionally, iron/sodium (Fe/Na) co‐doping further increased the OSC by three times, with an additional 15–20 % increase in CO conversion for the water‐gas shift (WGS) reaction, compared with the best CO conversion rate among Na‐doped La2O2S...

thumbnail image: ChemCatChem


Live‐Cell MicroRNA Imaging through MnO 2 Nanosheet‐Mediated DD‐A Hybridization Chain Reaction

Published: 14 December 2017

Author(s): Min Ou, Jin Huang, Xiaohai Yang, Xiaoxiao He, Ke Quan, Yanjing Yang, Nuli Xie, Jing Li, Kemin Wang

Abstract Innovative techniques to visualize native microRNAs (miRNAs) in live cells can dramatically impact current research on the roles of miRNA in biology and medicine. Here, we report a novel approach for live‐cell miRNA imaging using a biodegradable MnO2 nanosheet‐mediated DD‐A FRET hybridization chain reaction (HCR). The MnO2 nanosheets can adsorb DNA hairpin probes and deliver them into live cells. After entering cells, the MnO2...

thumbnail image: ChemBioChem

Chemistry - A European Journal

Tuning the Förster Resonance Energy Transfer through a Self‐Assembly Approach for Efficient White‐Light Emission in an Aqueous Medium

Published: 14 December 2017

Author(s): Pragyan Pallavi, Bahadur Sk, Palak Ahir, Abhijit Patra

Abstract A simple and cost‐effective methodology employing environmentally benign substances for the fabrication of white‐light emitting materials is important for practical applications in the field of lighting and display devices. Designing purely organic‐based white‐light‐emitting systems with high quantum efficiency in aqueous media is an unmet challenge. With this objective, a new class of pyridoindole‐based hydrophobic...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ring/Chain Morphology Control in Overall‐Neutral, Internally Ion‐Paired Supramolecular Polymers

Published: 14 December 2017

Author(s): Nadia Manganaro, Ilenia Pisagatti, Anna Notti, Andrea Pappalardo, Salvatore Patanè, Norberto Micali, Valentina Villari, Melchiorre F. Parisi, Giuseppe Gattuso

Abstract The self‐assembly of internally ion‐paired, neutral AA/BB‐type supramolecular polymers composed of complementary di‐ionizable homoditopic pairs of monomers is reported. Host‐to‐guest double‐proton transfer mediates the recognition between bis‐calix[5]arenedicarboxylic acids and α,ω‐diaminoalkanes to yield cyclic, doughnut‐shaped assemblies with morphologies (i.e., cyclic vs. linear) that can be controlled by means of...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ketenimines Generated from Ynamides: Versatile Building Blocks for Nitrogen‐Containing Scaffolds

Published: 14 December 2017

Author(s): Robert H. Dodd, Kevin Cariou

Abstract Using ynamides as readily available starting materials, a single step can generate highly reactive ketenimines, which can then undergo a variety of transformations. The choice of the method for generating the ketenimine dictates the outcome of the reaction that can, moreover, be precisely steered through minor variations of the starting material. This Concept gives an overview of the different existing methodologies for...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Nitrogen Reduction to Ammonia on a Biomimetic Mononuclear Iron Centre: Insights into the Nitrogenase Enzyme

Published: 14 December 2017

Author(s): Monika A. Kaczmarek, Abheek Malhotra, G. Alex Balan, Amy Timmins, Sam P. de Visser

Abstract Nitrogenases catalyse nitrogen fixation to ammonia on a multinuclear Fe‐Mo centre, but their mechanism and particularly the order of proton and electron transfer processes that happen during the catalytic cycle is still unresolved. Recently, a unique biomimetic mononuclear iron model was developed using tris(phosphine)borate (TPB) ligands that was shown to convert N2 into NH3. Herein, we present a computational study on the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Why the Flavin Adenine Dinucleotide (FAD) Cofactor Needs To Be Covalently Linked to Complex II of the Electron‐Transport Chain for the Conversion of FADH 2 into FAD

Published: 14 December 2017

Author(s): Daniel F. A. R. Dourado, Marcel Swart, Alexandra T. P. Carvalho

Abstract A covalently bound flavin cofactor is predominant in the succinate‐ubiquinone oxidoreductase (SQR; Complex II), an essential component of aerobic electron transport, and in the menaquinol‐fumarate oxidoreductase (QFR), the anaerobic counterpart, although it is only present in approximately 10 % of the known flavoenzymes. This work investigates the role of this 8α‐N3‐histidyl linkage between the flavin adenine dinucleotide...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Covalent Bonding and Charge Shift Bonds: Comment on “The Carbon–Nitrogen Bonds in Ammonium Compounds Are Charge Shift Bonds”

Published: 14 December 2017

Author(s): Gernot Frenking

Abstract The paper by Gershoni‐Poranne and Chen (R. Gershoni‐Poranne, P. Chen, Chem. Eur. J. 2017, 23, 4659) gives an incorrect definition of covalent bonding. Furthermore, the assignment of so‐called charge shift bonds in ammonium compounds has no physical foundation and is conceptually redundant.

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Construction of Large‐Area Uniform Graphdiyne Film for High‐Performance Lithium‐Ion Batteries

Published: 14 December 2017

Author(s): Jianjiang He, Kaijing Bao, Weiwei Cui, Jiaojiao Yu, Changshui Huang, Xiangyan Shen, Zili Cui, Ning Wang

Abstract Large‐area graphdiyne film is constructed by heat treatment, including thermally induced evaporation and a cross‐coupling reaction process. The growth mechanism is proposed based on the observation and characterization that the heating temperature plays an important role in the evaporation of oligomers and in triggering the thermal cross‐coupling reaction, whereas the heating duration mainly determines the execution of the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Unveiling the Role of Macrodipolar Interactions in the Properties of Self‐Assembled Supramolecular Materials

Published: 14 December 2017

Author(s): Marina Pereira Oliveira, Hans‐Werner Schmidt, Rodrigo Queiroz Albuquerque

Abstract Invited for the cover of this issue is the group of Rodrigo Queiroz Albuquerque at Liverpool John Moores University. The image depicts an antiparallel interaction among macrodipoles inside the supramolecular material, each arrow representing the macrodipole of a 1D supramolecular column self‐assembled from tricarboxamide derivatives. Read the full text of the article at 10.1002/chem.201704548.

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

November 2017


Pingyu Zhang, Cookson K. C. Chiu, Huaiyi Huang, Yuko P. Y. Lam, Abraha Habtemariam, Thomas Malcomson, Martin J. Paterson, Guy J. Clarkson, Peter B. O'Connor, Hui Chao, Peter J. Sadler
Organoiridium Photosensitizers Induce Specific Oxidative Attack on Proteins within Cancer Cells [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 14898

Mariam Iftikhar, Tivoli J. Olsen, Kaitlin M. Pugliese, William A. Brown, Joshua N. Smith, Sameeran Kunche, Stephan T. Kudlacek, Callum F. G. Ormonde, Tom Z. Yuan, Colin L. Raston, Gregory A. Weiss
Shear‐Stress‐Mediated Refolding of Proteins from Aggregates and Inclusion Bodies [Communication]
ChemBioChem 2015, vol. 16, p. 393

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Andreas Schaate, Pascal Roy, Adelheid Godt, Jann Lippke, Florian Waltz, Michael Wiebcke, Peter Behrens
Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals [Full Paper]
Chem. Eur. J. 2011, vol. 17, p. 6643

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Ulrich Lücking, Arne Scholz, Philip Lienau, Gerhard Siemeister, Dirk Kosemund, Rolf Bohlmann, Hans Briem, Ildiko Terebesi, Kirstin Meyer, Katja Prelle, Karsten Denner, Ulf Bömer, Martina Schäfer, Knut Eis, Ray Valencia, Stuart Ince, Franz von Nussbaum, Dominik Mumberg, Karl Ziegelbauer, Bert Klebl, Axel Choidas, Peter Nussbaumer, Matthias Baumann, Carsten Schultz-Fademrecht, Gerd Rühter, Jan Eickhoff, Michael Brands
Identification of Atuveciclib (BAY 1143572), the First Highly Selective, Clinical PTEFb/CDK9 Inhibitor for the Treatment of Cancer [Full Paper]
ChemMedChem 2017, vol. 12, p. 1776

Paul J. A. Kenis, Angela Dibenedetto, Tierui Zhang
Carbon Dioxide Utilization Coming of Age [Editorial]
ChemPhysChem 2017, vol. 18, p. 3091

Rebecca Clarke, Kin Lok Ho, Abdulrahman Abdullah Alsimaree, Owen J. Woodford, Paul G. Waddell, Jonathan Bogaerts, Wouter Herrebout, Julian G. Knight, Robert Pal, Thomas J. Penfold, Michael J. Hall
Circularly Polarised Luminescence from Helically Chiral “Confused” N,N,O,C-Boron-Chelated Dipyrromethenes (BODIPYs) [Article]
ChemPhotoChem 2017, vol. 1, p. 513

Holger Dau, Etsuko Fujita, Licheng Sun
Artificial Photosynthesis: Beyond Mimicking Nature [Editorial]
ChemSusChem 2017, vol. 10, p. 4228

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Salia Tangara, Alice Kanazawa, Sandrine Py
The Baldwin Rearrangement: Synthesis of 2-Acylaziridines [Microreview]
Eur. J. Org. Chem. 2017, p. 6357

Deutscher Lebensmittelchemikertag 2015 in Karlsruhe [Poster]
Lebensmittelchemie 2016, vol. 70, p. 71

Norbert Heeb
Der lange Weg zu sauberem Diesel [Leitartikel]
Nachr. Chem. 2017, vol. 65, p. 1079

Katrin Sommer, Christina Toschka, Laura Schröder, Thomas Philipp Schröder, Henning Steff, Roland A. Fischer
Modellexperimente im Chemieunterricht. [Artikel]
CHEMKON 2017, vol. 24, p. 13

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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