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Applied Organometallic Chemistry

Improved stability and dispersity of ZnO@PANI nanocomposites aqueous suspension

Published: 18 May 2018

Author(s): Xin Jin, Guangrong Liu, Chongzhuo Bao, Mingxin Chen, Qiang Huang

The high dispersion and stability of a nanocomposites suspension are required as a crucial factor in many of their applications. In this study, ZnO nanosheets covered with polyaniline (PANI) thin layer (ZnO@PANI) were synthesized by a simple in‐situ polymerization. The as‐prepared ZnO@PANI powders were well characterized by XRD, Raman, FTIR, XPS and photoluminescence spectra, as well as SEM and TEM techniques. The effect of PANI...

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Applied Organometallic Chemistry

Synthesis, characterization, spectroscopic and theoretical studies of transition metal complexes of new nano Schiff base derived from l ‐histidine and 2‐acetylferrocene and evaluation of biological and anticancer activities

Published: 18 May 2018

Author(s): Walaa H. Mahmoud, M.M. Omar, Fatma N. Sayed, Gehad G. Mohamed

A new Schiff base derived from the condensation of 2‐acetylferrocene with l‐histidine was prepared and characterized using elemental analyses and spectroscopic methods. Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes of the Schiff base were prepared and characterized using various physicochemical methods such as elemental analysis, Fourier transform infrared and UV–visible spectroscopies, molar conductance, thermal...

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Molecular Nutrition & Food Research

Exosomal MicroRNAs in Milk from Mothers Delivering Preterm Infants Survive in Vitro Digestion and Are Taken up by Human Intestinal Cells

Published: 18 May 2018

Author(s): Sarah Kahn, Yalin Liao, Xiaogu Du, Wei Xu, Jie Li, Bo Lönnerdal

Scope This study investigates the ability of preterm milk exosomes to survive gastric/pancreatic digestion, internalization by intestinal epithelia, and the microRNAs (miRNAs) contents. Methods and results At average infant age 1 week and 6 days, milk is collected from mothers who delivered preterm and term infants (n = 10). Milk is exposed to...

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European Journal of Organic Chemistry

Organocatalytic Strategies to Stereoselectively Trap Photochemically Generated Hydroxy‐ o ‐quinodimethanes

Published: 18 May 2018

Author(s): Sara Cuadros, Paolo Melchiorre

Light excitation of ortho‐alkyl aromatic ketones and aldehydes gives access to hydroxy‐o‐quinodimethanes. These reactive electron‐rich intermediates are sufficiently long‐lived to productively engage in chemical processes, mainly acting as dienes in [4+2]‐cycloadditions with electron‐poor alkenes. Since the early discovery of this photoenolization mechanism in 1961, a variety of transformations has been developed, providing a photochemical...

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Applied Organometallic Chemistry

Synthesis and characterization of graphene oxide‐based hybrid ligand and its metal complexes: Highly efficient sensor and catalytic properties

Published: 18 May 2018

Author(s): Muharrem Karabörk, R. Maher Zubair, Serhan Uruş, Mehmet Tümer

A new graphene oxide‐based hybrid material (HL) and its Co(II), Cu(II) and Ni(II) metal complexes were prepared. Firstly, graphene oxide and (3‐aminopropyl)trimethoxysilane were reacted to give graphene oxide–3‐(aminopropyl)trimethoxysilane (GO‐APTMS) hybrid material. After that, hybrid material HL was synthesized from the reaction of GO‐APTMS and 2,6‐diformyl‐4‐methylphenol. Finally, Co(II), Cu(II) and Ni(II) complexes of HL were...

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Applied Organometallic Chemistry

Theoretical investigation into the coordination of R ‐/ S ‐asymmetric uranyl–salophens containing six‐membered ring lactam with cis −/ trans ‐cyclohexylamines

Published: 18 May 2018

Author(s): Liang‐Liang Yang, Xiang‐He Kong, Zhi‐Lin Wu, Ying‐Wu Lin, Li‐Fu Liao, Chang‐Ming Nie

A six‐membered ring lactam derivative was introduced in a parallel manner into uranyl–salophens with R/S configuration (R‐/S‐AUSRLs), which were used as receptors to coordinate with guests of cis−/trans‐methylcyclohexylamines (cis−/trans‐MCHAs). Using density functional theory calculations at the B3LYP/6‐311G** level and RECP, an insight into the coordination complexes of the R‐/S‐AUSRLs with cis−/trans‐MCHAs was obtained. The results showed that the U atoms of...

thumbnail image: Applied Organometallic Chemistry

Applied Organometallic Chemistry

Transition metal complexes of a hydrazone–oxime ligand containing the isonicotinoyl moiety: Synthesis, characterization and microbicide activities

Published: 18 May 2018

Author(s): Mohamad M.E. Shakdofa, Fathy A. El‐Saied, Anas J. Rasras, Ahmed N. Al‐Hakimi

Complexes of VO2+, Mn2+, Co2+, Ni2+, Cu2+, Zn2+, Ru3+ and UO22+ with (3‐(hydroxyimino)butan‐2‐ylidene)isonicotinohydrazide were synthesized and characterized using physical and spectral methods. Analytical data revealed that the complexes formed in 1:1 or 1:2 metal–ligand ratios. Spectral studies showed that the ligand bonded to the metal ion in neutral tridentate, monobasic tridentate or monobasic bidentate fashion through azomethine ...

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Journal of Polymer Science Part B: Polymer Physics

Unveiling of polymer/fullerene blend films morphology by ellipsometrically determined optical order within polymer and fullerene phases

Published: 18 May 2018

Author(s): Henryk Bednarski, Barbara Hajduk, Marian Domański, Bożena Jarząbek, Paweł Nitschke, Katarzyna Łaba, Andrzej Wanic, Mieczysław Łapkowski

ABSTRACT Optical properties of polymer/fullerene blend films upon thermal annealing are investigated by spectroscopic ellipsometry and described consistently within an optical model of the blend film. The optical model developed in this work treats both components, polymer and fullerene, as mixtures of reference materials, that is, their optically ordered and disordered phase. Then, the polymer/fullerene blend layer is also...

Applied Organometallic Chemistry

Diisopropyl fluorophosphate (DFP) degradation activity using transition metal–dipicolylamine complexes

Published: 18 May 2018

Author(s): Keunhong Jeong, Joongmoo Shim, Woo Young Chung, Young Sik Kye, Dongwook Kim

Transition metal complexes have been extensively used as catalysts for organophosphorus agent decomposition to reduce their toxicity with their performance being strongly dependent on the nature of the metal ion. To investigate this dependence, we prepared dipicolylamine (DPA)‐containing complexes of Cu(II), Zn(II), Ni(II), Co(II), and Fe(II) and analyzed their activities for the degradation of diisopropyl fluorophosphate (DFP), a nerve...

thumbnail image: Applied Organometallic Chemistry

Applied Organometallic Chemistry

Highly efficient CO 2 capture with a metal–organic framework‐derived porous carbon impregnated with polyethyleneimine

Published: 18 May 2018

Author(s): Samira Salehi, Mansoor Anbia

Global warming is considered as one of the great challenges of the twenty‐first century. Application of CO2 capture and storage technologies to flue gas is considered to be a useful method of lessening global warning. Highly porous carbon has played an important role in tackling energy and environmental problems. We attempted to synthesize a highly porous carbon adsorbent by carbonizing a highly crystalline metal–organic framework (MOF) without any...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018

 


Zhang Luo, Bing Liu
Shape‐Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture]
Angew. Chem. Int. Ed. 10.1002/anie.201802726

Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens
MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication]
ChemBioChem 2018, vol. 19, p. 434

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber
Analytik mit Licht - Das Smartphone-Photometer [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 52

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication]
Chem. Eur. J. 2018, vol. 24, p. 4552

Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo
Aromatic Aminocatalysis [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 740

Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki
Abstract [Focus Review]
Asian J. Org. Chem. 10.1002/ajoc.201800013

Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 2018, vol. 13, p. 614

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 2018, vol. 2, p. 161

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson
The Use of Halide‐Substituted Anilines for the Formation of Magnesium Imides [Full Paper]
Eur. J. Inorg. Chem. 2008, p. 3935

D. B. Ramachary [Author Profile]
Eur. J. Org. Chem. 10.1002/ejoc.201800182

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Peter Chen
Chemistry 4.0 [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 203

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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