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Applied Organometallic Chemistry

Preparation of disk‐like Pt/CeO 2 ‐p‐TiO 2 catalyst derived from MIL‐125(Ti) for excellent catalytic performance

Published: 18 May 2018

Author(s): Shenhao Yuan, Yan Gao, Jiehua Bao, Yiwei Zhang, Wenxia Chen, Jiasheng Fang, Yuming Zhou, Yanyun Wang, Wenyu Zhu

A feasible strategy is reported for the synthesis of a disk‐like Pt/CeO2‐p‐TiO2 catalyst derived from the titanium‐based metal–organic framework (MOF) MIL‐125(Ti) through a few valid steps. To verify the successful synthesis and structural features of the Pt/CeO2‐p‐TiO2 catalyst, as‐prepared samples were characterized using several techniques. The characterizations demonstrated that MOF‐derived porous TiO2 was appropriate for application as a support...

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Applied Organometallic Chemistry

A robust UV–visible light‐driven SBA‐15‐PS/phthalhydrazide nanohybrid material with enhanced photocatalytic activity in the photodegradation of methyl orange

Published: 18 May 2018

Author(s): R. Tayebee, R. Mohammadzadeh Kakhki, P. Audebert, M. M. Amini, M. Salehi, N. Mahdizadeh Ghohe, V. Mandanipour, G.R. Karimipour

SBA‐15‐PS/phthalhydrazide (PHD) is presented as a new heterogeneous inorganic–organic nanohybrid photocatalyst with high stability, superior recyclability and remarkable performance in the degradation of methyl orange (MO). Distinctive parameters, including photocatalyst and dye concentrations, pH and degradation time, were assessed for MO degradation catalysed by SBA‐15‐PS/PHD. This new heterogeneous nanocatalyst was characterized using...

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European Journal of Inorganic Chemistry

Water Oxidation Reaction Mediated by an Octanuclear Iron‐Oxo Cluster

Published: 18 May 2018

Author(s): Jennifer Deutscher, Teresa Corona, Katrin Warm, Xenia Engelmann, Sebastian Sobottka, Beatrice Braun‐Cula, Biprajit Sarkar, Kallol Ray

A one‐pot synthetic procedure yields the octanuclear FeIII complex [Fe8(µ4‐O)4(µ‐4‐tBu‐pz)12Cl4] (2). The molecular structure of 2 resembles the building units of iron‐containing minerals like magnetite, ferrihydrite and maghemite. Based on mechanistic investigation we propose that in presence of Et3N, iron(III) pyrazolates are reduced to iron(II) pyrazolates, which then activate dioxygen to form 2. Complex 2 exhibits unique spectroscopic and electrochemical...

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Advanced Functional Materials

Smart Liquid Transport on Dual Biomimetic Surface via Temperature Fluctuation Control

Published: 18 May 2018

Author(s): Chuxin Li, Cunlong Yu, Dezhao Hao, Lei Wu, Zhichao Dong, Lei Jiang

Abstract Microdevices that manipulate fluids to transport in a predefined direction and to switch flow directions under temperature stimuli are fundamental to the intelligent control of biomedical devices, thermal managements, lab‐on‐a‐chip, etc. Despite current advances in controlling drop transport, the amplitude of liquid motion is still limited with a low speed, and the flow direction is not well controlled because of the...

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Advanced Materials

3D DNA Origami Crystals

Published: 18 May 2018

Author(s): Tao Zhang, Caroline Hartl, Kilian Frank, Amelie Heuer‐Jungemann, Stefan Fischer, Philipp C. Nickels, Bert Nickel, Tim Liedl

Abstract 3D crystals assembled entirely from DNA provide a route to design materials on a molecular level and to arrange guest particles in predefined lattices. This requires design schemes that provide high rigidity and sufficiently large open guest space. A DNA‐origami‐based “tensegrity triangle” structure that assembles into a 3D rhombohedral crystalline lattice with an open structure in which 90% of the volume is empty space is...

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Journal of Physical Organic Chemistry

Photoswitchable double bonds: Synthetic strategies for tunability and versatility

Published: 18 May 2018

Author(s): David Cameron, Sara Eisler

Abstract Isomerizations of azo, imine, and alkene groups using light are highly tunable. As such, photoswitches based on these functional groups have become critical components of many responsive molecules and materials. This mini‐review describes recent work focused on controlling various properties of double bond‐based molecular switches, including speed of switching, thermal stability, and wavelength required to initiate...

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Advanced Materials

Biomimetic Supramolecular Fibers Exhibit Water‐Induced Supercontraction

Published: 18 May 2018

Author(s): Yuchao Wu, Darshil U. Shah, Baoyuan Wang, Ji Liu, Xiaohe Ren, Michael H. Ramage, Oren A. Scherman

Abstract Spider silk is a fascinating material, combining high strength and elasticity that outperforms most synthetic fibers. Another intriguing feature of spider silk is its ability to “supercontract,” shrinking up to 50% when exposed to water. This is likely on account of the entropy‐driven recoiling of secondary structured proteins when water penetrates the spider silk. In contrast, humidity‐driven contraction in synthetic...

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Chemical Biology & Drug Design

Improving metabolic stability with deuterium: The discovery of HWL ‐066, a potent and long‐acting free fatty acid receptor 1 agonists

Published: 18 May 2018

Author(s): Chunxia Liu, Zheng Li, Wei Shi, Huilan Li, Nasi Wang, Yuxuan Dai, Chen Liao, Wenlong Huang, Hai Qian

The free fatty acid receptor 1 (FFA1) is a potential target due to its function in enhancing of glucose‐stimulated insulin secretion. The FFA1 agonist GW9508 has great potential for the treatment of type 2 diabetes mellitus, but it has been suffering from high plasma clearance probably because the phenylpropanoic acid is vulnerable to β‐oxidation. To identify orally available analog without influence on the unique pharmacological...

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Journal of Basic Microbiology

Haererehalobacter sp. JS1, a bioemulsifier producing halophilic bacterium isolated from Indian solar salt works

Published: 18 May 2018

Author(s): Mariathason Birdilla Selva Donio, Subbiahanadar Chelladurai Karthikeyan, Mariavincent Michaelbabu, Ganapathi Uma, Ramaiyan Raja Jeya Sekar, Thavasimuthu Citarasu

Bioemulsifier (BE)‐producing Haererehalobacter sp. JS1 was isolated and identified from the solar salt works in India. The BE was extracted, purified, and characterized by Gas Chromatography‐Mass Spectrometry (GC‐MS) analysis. Emulsification activity was performed against different oils and dye degradation potential against different dyes. The production of BE was optimized using different carbon sources (C), nitrogen ...

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Chemistry - An Asian Journal

Hierarchical MoS 2 @TiO 2 Heterojunctions for Enhanced Photocatalytic Performance and Electrocatalytic Hydrogen Evolution

Published: 18 May 2018

Author(s): Yu Dong, Sheng‐You Chen, Yi Lu, Yu‐Xuan Xiao, Jie Hu, Si‐Ming Wu, Zhao Deng, Ge Tian, Gang‐Gang Chang, Jing Li, Silvia Lenaerts, Christoph Janiak, Xiao‐Yu Yang, Bao‐Lian Su

Abstract Hierarchical MoS2@TiO2 heterojunctions were synthesized through a one‐step hydrothermal method by using protonic titanate nanosheets as the precursor. The TiO2 nanosheets prevent the aggregation of MoS2 and promote the carrier transfer efficiency, and thus enhance the photocatalytic and electrocatalytic activity of the nanostructured MoS2. The obtained MoS2@TiO2 has significantly enhanced photocatalytic activity in the degradation of...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018


Zhang Luo, Bing Liu
Shape‐Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture]
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Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens
MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication]
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Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber
Analytik mit Licht - Das Smartphone-Photometer [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 52

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication]
Chem. Eur. J. 2018, vol. 24, p. 4552

Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo
Aromatic Aminocatalysis [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 740

Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki
Abstract [Focus Review]
Asian J. Org. Chem. 10.1002/ajoc.201800013

Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 2018, vol. 13, p. 614

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 2018, vol. 2, p. 161

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson
The Use of Halide‐Substituted Anilines for the Formation of Magnesium Imides [Full Paper]
Eur. J. Inorg. Chem. 2008, p. 3935

D. B. Ramachary [Author Profile]
Eur. J. Org. Chem. 10.1002/ejoc.201800182

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Peter Chen
Chemistry 4.0 [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 203

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
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Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
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