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Chemistry - A European Journal

Robust Macroscopic 3D Sponges of Manganese Oxide Molecular Sieve

Published: 21 September 2017

Author(s): Zhenxin Liu, Depeng Wu, Xuehui Guo, Shaoming Fang, Lizhen Wang, Yu Xing, Steven L. Suib

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Dual Visible Light‐Triggered Photoswitch of a Diarylethene Supramolecular Assembly with Cucurbit[8]uril

Published: 21 September 2017

Author(s): Guoxing Liu, Ying‐Ming Zhang, Conghui Wang, Yu Liu

Abstract Research on photochromic molecules switched by visible light is of particular interest for their application in bioimaging and stimuli‐responsive materials. Here, a photoswitchable supramolecular assembly comprised of monocharged bispyridinium‐modified diarylethenes (DAEs) and cucurbit[8]uril (CB[8]) has been constructed, which exhibits reversible photochromic behaviour with visible light in both directions. The...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Photoswitchable Carbohydrate‐Based Macrocyclic Azobenzene: Synthesis, Chiroptical Switching, and Multistimuli‐Responsive Self‐Assembly

Published: 21 September 2017

Author(s): Chaoqi Lin, Stéphane Maisonneuve, Rémi Métivier, Juan Xie

Abstract A one‐pot O‐alkylation mediated macrocyclization approach has been used for the synthesis of carbohydrate‐based macrocyclic azobenzene. The synthesized macrocycle can be reversibly isomerized between E and Z isomers upon UV or visible irradiation with excellent photostability and thermal stability (t1/2=51 days at 20 °C for the Z isomer). A chirality transfer from the chiral sugar unit to azobenzene was observed by circular dichroism (CD). DFT and...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Chemical Potential of the Solvent: A Crucial Player for Rationalizing Host–Guest Affinities

Published: 21 September 2017

Author(s): Karine Baudet, Sebastiano Guerra, Claude Piguet

Abstract Access to reliable values of the thermodynamic constants β 1 , 1 H , G , which control simple host–guest ([HG])...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Transition Metal Catalyzed, Regioselective B (4)‐Halogenation and B (4,5)‐Diiodination of Cage B−H Bonds in o ‐Carboranes

Published: 21 September 2017

Author(s): Hairong Lyu, Yangjian Quan, Zuowei Xie

Abstract Transition metal catalyzed, regioselective carborane‐cage B(4)−H iodination, bromination, and chlorination as well as B(4,5)−H diiodination were achieved by using NXS (X=I, Br), FeCl3, or IOAc as the halogenating agent, respectively. A series of previously inaccessible B(4)‐halogenated o‐carboranes were synthesized in a simple one‐pot process, and proved to be valuable synthons for the functionalization of carboranes. Mono‐ and di‐selectivity can...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Helicity‐Dependent Regiodifferentiation in the Excited‐State Quenching and Chiroptical Properties of Inward/Outward Helical Coumarins

Published: 21 September 2017

Author(s): Arindam Mukhopadhyay, Tousif Hossen, Indrajit Ghosh, Apurba Lal Koner, Werner M. Nau, Kalyanasis Sahu, Jarugu Narasimha Moorthy

Abstract Influence of helicity on the excited‐state as well as chiroptical properties of two sets of regiohelical coumarins that are differentiated by “inward” and “outward” disposition of the pyran‐2‐one ring has been investigated. A subtle difference in the helicities manifests in divergent excited‐state properties and significant differences in the dipole moments. The latter permit heretofore unprecedented regiodifferentiation in...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

β‐Acrolein‐Substituted Corroles: A Route to the Preparation of Functionalized Polyacrolein Microspheres for Chemical Sensor Applications

Published: 21 September 2017

Author(s): Andrea Savoldelli, Gabriele Magna, Corrado Di Natale, Alexandro Catini, Sara Nardis, Frank R. Fronczek, Kevin M. Smith, Roberto Paolesse

Abstract An efficient β‐functionalization of [5,10,15‐tris‐(4‐methylphenyl)corrolato]cobalt derivatives through a Vilsmeier‐type reaction allows the introduction of an acrolein substituent, which is subsequently copolymerized with pure acrolein. The obtained hybrid microspheres are exploited as nanogravimetric chemical sensors. The sensing properties of the developed sensors are tested through exposure to different volatile organic...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Catalytic Asymmetric Formal [3+2] Cycloaddition of 2‐Isocyanatomalonate Esters and Unsaturated Imines: Synthesis of Highly Substituted Chiral γ‐Lactams

Published: 21 September 2017

Author(s): Miguel Espinosa, Gonzalo Blay, Luz Cardona, M. Carmen Muñoz, José R. Pedro

Abstract Unlike their isocyano and isothiocyanato analogues, isocyanato esters remain almost unexplored as formal 1,3‐dipoles in asymmetric catalytic reactions. The first asymmetric formal [3+2] cycloaddition involving isocyanato esters and electrophilic alkenes is reported. Diisopropyl 2‐isocyanatomalonate reacts with α,β‐unsaturated N‐(o‐anisidyl) imines in the presence of a Mg(OTf)2–BOX complex to give highly substituted chiral...

thumbnail image: Chemistry - A European Journal

ChemSusChem

Diphenyl‐2‐pyridylamine‐Substituted Porphyrins as Hole‐Transporting Materials for Perovskite Solar Cells

Published: 21 September 2017

Author(s): Un‐Hak Lee, Randi Azmi, Septy Sinaga, Sunbin Hwang, Seung Hun Eom, Tae‐Wook Kim, Sung Cheol Yoon, Sung‐Yeon Jang, In Hwan Jung

Abstract The susceptibility of porphyrin derivatives to light‐harvesting and charge‐transport operations have enabled these materials to be employed in solar cell applications. The potential of porphyrin derivatives as hole‐transporting materials (HTMs) for perovskite solar cells (PSCs) has recently been demonstrated, but knowledge of the relationships between the porphyrin structure and device performance remains insufficient. In...

thumbnail image: ChemSusChem

Chemistry - A European Journal

Prediction of Reduction Potentials of Copper Proteins with Continuum Electrostatics and Density Functional Theory

Published: 21 September 2017

Author(s): Nicholas J. Fowler, Christopher F. Blanford, Jim Warwicker, Sam P. de Visser

Abstract Blue copper proteins, such as azurin, show dramatic changes in Cu2+/Cu+ reduction potential upon mutation over the full physiological range. Hence, they have important functions in electron transfer and oxidation chemistry and have applications in industrial biotechnology. The details of what determines these reduction potential changes upon mutation are still unclear. Moreover, it has been difficult to model and predict the reduction...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

July 2017

 


Xinxing Zhang, Gaoxiang Liu, Sandra Ciborowski, Kit Bowen
Stabilizing Otherwise Unstable Anions with Halogen Bonding [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 9897

Jonathan Okerblom, Ajit Varki
Biochemical, Cellular, Physiological, and Pathological Consequences of Human Loss of N-Glycolylneuraminic Acid [Review]
ChemBioChem 2017, vol. 18, p. 1155

Hélène Olivier-Bourbigou, Céline Chizallet, Franck Dumeignil, Pascal Fongarland, Christophe Geantet, Pascal Granger, Franck Launay, Axel Löfberg, Pascale Massiani, Françoise Maugé, Armelle Ouali, Anne-Cécile Roger, Yves Schuurman, Nathalie Tanchoux, Denis Uzio, François Jérôme, Daniel Duprez, Catherine Pinel
The Pivotal Role of Catalysis in France: Selected Examples of Recent Advances and Future Prospects. [Review]
ChemCatChem 2017, vol. 9, p. 2029

Klaus Roth, Elisabeth Vaupel
Von Insekten, Chrysanthemen und Menschen [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 162

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Marc T. M. Koper, Hasan Yılmaz, Ruud Kortlever, Recep Kas, Guido Mul
Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO2 Electroreduction by Process Conditions [Communication]
ChemElectroChem 2015, vol. 2, p. 354

Liming Dai, Xinliang Feng, Zhongfan Liu, Hua Zhang
Two-Dimensional Materials: A Powerful Platform for Energy Applications [Editorial]
ChemNanoMat 2017, vol. 3, p. 338

Ralf Haiges, Piyush Deokar, Monica Vasiliu, Trent H. Stein, David A. Dixon, Karl O. Christe
Cover Picture: Preparation and Characterization of Group 13 Cyanides (Chem. Eur. J. 38/2017) [Cover Picture]
Chem. Eur. J. 2017, vol. 23, p. 8989

Yilong Yang, Songcan Wang, Yongli Li, Jinshu Wang, Lianzhou Wang
Strategies for Efficient Solar Water Splitting Using Carbon Nitride [Focus Review]
Chem. Asian J. 2017, vol. 12, p. 1421

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Edmond Differding
The Drug Discovery and Development Industry in India-Two Decades of Proprietary Small-Molecule R&D [Review]
ChemMedChem 2017, vol. 12, p. 786

Sergey Akbulatov, Roman Boulatov
Experimental Polymer Mechanochemistry and its Interpretational Frameworks [Review]
ChemPhysChem 2017, vol. 18, p. 1422

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, p. 148

Hirotaka Koga, Naoko Namba, Tsukasa Takahashi, Masaya Nogi, Yuta Nishina
Renewable Wood Pulp Paper Reactor with Hierarchical Micro/Nanopores for Continuous-Flow Nanocatalysis [Communication]
ChemSusChem 2017, vol. 10, p. 2560

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

MATLAB für Dummies von Jim Sizemore und John Paul Mueller [Buchbesprechung]
Lebensmittelchemie 2017, vol. 71, p. 32

Reinhard Zellner
Die Fakten und ihre Wahrnehmung [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 662

Jana Thomas, Sabine Struckmeier, Bernhard F. Sieve
„Molekulares Sieben 2.0“ - vom Kontinuum zum Diskontinuum mit molekularer Küche [Das Experiment]
CHEMKON 2017, vol. 24, p. 142

Sarah Millar
Tips and Tricks for the Lab: Column Choices
ChemViews Magazine 2012.

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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