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Chemie Ingenieur Technik - CIT

Direktkontakt‐Latentwärmespeicher zur Effizienzsteigerung von WärmepumpenDirect Contact Latent Heat Storage for Efficiency Enhancement of Heat Pumps

Published: 20 November 2017

Author(s): Sven Kunkel, Felix Kübel‐Heising, Patrick Dörnhofer, Isabel Medina, Jürgen Weis, Rainer Stabler, Jens‐Uwe Repke, Matthias Rädle

Abstract Mit einem neuen Konzept zur Speicherung thermischer Energie auf niedrigem und konstantem Temperaturniveau soll solarthermische Energie auch in der Übergangs‐ und Winterzeit effektiv genutzt und zur Steigerung des Wirkungsgrades von Wärmepumpen gespeichert werden. Es wird ein Latentwärmespeicher auf Basis von Salzhydraten vorgestellt, wobei das Salzhydrat einen Schmelzpunkt von 15 °C aufweist und durch Direktkontakt mit...

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Chemie Ingenieur Technik - CIT

Rheinische Braunkohle – Energieträger und vielseitiger Rohstoff im Wandel der ZeitRhenish Lignite – Energy Carrier and Versatile Raw Material Through the Ages

Published: 20 November 2017

Author(s): Urs Overhoff, Peter Moser, Reinhold Elsen, Gero Vinzelberg, Michael Eyll‐Vetter, Markus Neuroth

Abstract Als bedeutsamster, heimischer fossiler Energieträger spielt die Braunkohle in Deutschland eine wichtige Rolle in der Strom‐ und Wärmeversorgung. Auch wenn ihr Anteil an der Stromerzeugung durch die zunehmende Einspeisung erneuerbarer Energien rückläufig ist, werden die fossilen Energieträger auch zukünftig die zuverlässige Grundlast‐ und Back‐Up‐Versorgung in Zeiten stellen, in denen die erneuerbaren Energien kaum Strom...

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Chemistry - A European Journal

Reversible Oxidative Se−Se Coupling of Phosphine Selenides by Ph 3 Sb(OTf) 2

Published: 20 November 2017

Author(s): Maximilian J. Poller, Neil Burford, Konstantin Karaghiosoff

Abstract Salts of diphosphoniumdiselenide dications ([R3PSeSePR3][OTf]2) have been isolated from reactions of trialkylphosphine selenides with triphenylantimony bistriflate. The redox process is speculated to proceed via a cationic coordination complex [Ph3SbL2][OTf]2 (L=Me3PSe, iPr3PSe), which is also formed in the reaction of [R3PSeSePR3][OTf]2 with Ph3Sb. The observations indicate that the reductive elimination of [R3PSeSePR3]2+ from [Ph3Sb(SePR3)2]2+...

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Chemistry - A European Journal

Braking of a Light‐Driven Molecular Rotary Motor by Chemical Stimuli

Published: 20 November 2017

Author(s): Thomas van Leeuwen, Wojciech Danowski, Stefano F. Pizzolato, Peter Štacko, Sander J. Wezenberg, Ben L. Feringa

Abstract Artificial molecular motors hold great promise for application in responsive functional materials as well as to control the properties of biohybrid systems. Herein a strategy is reported to modulate the rotation of light‐driven molecular motors. That is, the rotary speed of a molecular motor, functionalized with a biphenol moiety, could be decreased in situ by non‐covalent substrate binding, as was established by 1H NMR and...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

α,α‐Alkylation‐Halogenation and Dihalogenation of Sulfoxonium Ylides. A Direct Preparation of Geminal Difunctionalized Ketones

Published: 20 November 2017

Author(s): Rafael D. C. Gallo, Anees Ahmad, Gustavo Metzker, Antonio C. B. Burtoloso

Abstract A one‐pot alkylation–halogenation of ketosulfoxonium ylides in the presence of alkyl halides is described. The method furnishes several gem‐difunctionalized haloketones (an alkyl and F, Cl, Br, or I) in good yields. Replacing alkyl halides with a mixture of electrophilic halogen species and various halide anions led to gem‐dihalogenated ketones containing a combination of the same or two different halogens. Kinetic isotopic effects as...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

A Facile and Green Method for the Synthesis of SFE Borosilicate Zeolite and Its Heteroatom‐Substituted Analogues with Promising Catalytic Performances

Published: 20 November 2017

Author(s): Yi Luo, Zhendong Wang, Junliang Sun, Yingying Wang, Shaoqing Jin, Bin Zhang, Hongmin Sun, Weimin Yang

Abstract Synthesis of SFE‐type borosilcate zeolite was successfully carried out using a commercially available low‐cost organic structure directing agent (OSDA) with ultra‐low OSDA and water contents within a short crystallization time. Heteroatom (Al, Ti, V, or Fe)‐substituted SFE‐type zeolite analogues were also directly synthesized for the first time. The obtained Al containing zeolites exhibited promising catalytic performances...

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Process Safety Progress

Elongated VCE blast waves and structural response

Published: 20 November 2017

Author(s): Jihui Geng, Thomas Mander, J. Kelly Thomas, Quentin Baker

Elongated congested volumes are common at chemical processing and petroleum refining facilities due to the arrangement of processing units, but there have been relatively few evaluations reported for the blast loads produced by elongated vapor cloud explosions (VCEs). The accidental VCE that occurred at the Buncefield, UK facility in 2005 involved an elongated congested volume formed by the trees and undergrowth along a portion of the...

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Process Safety Progress

And now for something completely different

Published: 20 November 2017

Author(s): Michael P. Broadribb

Process safety management systems are generally credited with reducing major accident risk in the process industries. While those systems have been around for many years—the EU introduced the Seveso Directive in 1982, and US OSHA promulgated the PSM regulation 10 years later— many companies today are challenged by inadequate and/or stagnant process safety management system performance. Several companies have experienced major incidents,...

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Israel Journal of Chemistry

Iron Dihydride Complexes: Synthesis, Reactivity, and Catalytic Applications

Published: 20 November 2017

Author(s): Huiguang Dai, Hairong Guan

Abstract Iron dihydride complexes often play important roles in catalytic reactions that employ reducing agents such as H2, boranes, and silanes. Development of more efficient and selective iron‐based catalysts for these processes requires effective synthetic strategies and a deeper understanding of the reactivity of the dihydride complexes. The purpose of this review is to provide the readers with an overview of different ligand systems that...

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Particle & Particle Systems Characterization

Silica Nanoparticles as Adhesives for Biological Tissues? Re‐Examining the Effect of Particles Size, Particle Shape, and the Unexpected Role of Base

Published: 20 November 2017

Author(s): Hui Liu, Yanfen Peng, Cangjie Yang, Mingfeng Wang

Abstract Development of new, effective, and patient‐friendly adhesives for biological tissues is important for medical and surgical practices such as bleeding control and organ repairing. While some commercially available silica nanoparticles such as LUDOX SM‐30 have shown adhesive properties for biological tissues, the role of inorganic base present in the adhesive properties of the silica nanoparticles has not been examined....

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

October 2017


Bryan D. Ellis, Christopher D. Vanderwal
Hughes and Gleason's Virosaine A-Appreciating the Art in Synthesis [Highlight]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 13940

Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz
How We Make DNA Origami [Concept]
ChemBioChem 2017, vol. 18, p. 1873

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, p. 1523

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Flavia Izzo, Martina Schäfer, Robert Stockman, Ulrich Lücking
A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides [Full Paper]
Chem. Eur. J. 2017, vol. 23, p. 15189

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Paramita Mukherjee, Martin Pettersson, Jason K. Dutra, Longfei Xie, Christopher W. am Ende
Trifluoromethyl Oxetanes: Synthesis and Evaluation as a tert-Butyl Isostere [Communication]
ChemMedChem 2017, vol. 12, p. 1574

David D. Evanoff, George Chumanov
Synthesis and Optical Properties of Silver Nanoparticles and Arrays [Minireview]
ChemPhysChem 2005, vol. 6, p. 1221

Jonathan E. Barnsley, Bethany A. Lomax, James R. W. McLay, Christopher B. Larsen, Nigel T. Lucas, Keith C. Gordon
Flicking the Switch on Donor-Acceptor Interactions in Hexaazatrinaphthalene Dyes: A Spectroscopic and Computational Study [Article]
ChemPhotoChem 2017, vol. 1, p. 432

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Francesca Leonelli, Marinella Capuzzi, Vincenzo Calcagno, Pietro Passacantilli, Giovanni Piancatelli
Stereoselective Michael‐Type Addition of Organocopper Reagents to Enones Derived from Glycals in the Synthesis of 2‐Phosphono‐α‐C‐Glycosides [Short Communication]
Eur. J. Org. Chem. 2005, p. 2671

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Titandioxid: schön oder schädlich [Industrie & Technik]
Nachr. Chem. 2017, vol. 65, p. 1008

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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