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Angewandte Chemie

Functional Cellular Mimics for the Spatiotemporal Control of Multiple Enzymatic Cascade Reactions

Published: 22 November 2017

Author(s): Xiaoling Liu, Petr Formanek, Brigitte Voit, Dietmar Appelhans

Abstract Next‐generation therapeutic approaches are expected to rely on the engineering of biomimetic cellular systems that can mimic specific cellular functions. Herein, we demonstrate a highly effective route for constructing structural and functional eukaryotic cell mimics by loading pH‐sensitive polymersomes as membrane‐associated and free‐floating organelle mimics inside the multifunctional cell membrane. Metabolism mimicry has...

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Angewandte Chemie International Edition

Functional Cellular Mimics for the Spatiotemporal Control of Multiple Enzymatic Cascade Reactions

Published: 22 November 2017

Author(s): Xiaoling Liu, Petr Formanek, Brigitte Voit, Dietmar Appelhans

Abstract Next‐generation therapeutic approaches are expected to rely on the engineering of biomimetic cellular systems that can mimic specific cellular functions. Herein, we demonstrate a highly effective route for constructing structural and functional eukaryotic cell mimics by loading pH‐sensitive polymersomes as membrane‐associated and free‐floating organelle mimics inside the multifunctional cell membrane. Metabolism mimicry has...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Three‐Dimensional Anionic Cyclodextrin‐Based Covalent Organic Frameworks

Published: 22 November 2017

Author(s): Yuanyuan Zhang, Jiyun Duan, Dou Ma, Pengfei Li, Siwu Li, Haiwei Li, Junwen Zhou, Xiaojie Ma, Xiao Feng, Bo Wang

Abstract Three‐dimensional covalent organic frameworks (3D COFs) are promising crystalline materials with well‐defined structures, high porosity, and low density; however, the limited choice of building blocks and synthetic difficulties have hampered their development. Herein, we used a flexible and aliphatic macrocycle, namely γ‐cyclodextrin (γ‐CD), as the soft struts for the construction of a polymeric and periodic 3D extended...

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Clinical and Experimental Pharmacology and Physiology

Prorenin receptor mediates inflammation in renal ischemia

Published: 22 November 2017

Author(s): Syed S Quadri, Silas Culver, Helmy M Siragy

Summary We hypothesized that PRR contributes to renal inflammation in the 2‐kidney, 1‐clip (2K1C) renal ischaemia model. Male Sprague‐Dawley rats were fed normal sodium diet. Blood pressure (BP) was obtained on days 0 and 28 after left renal artery clipping that reduced renal blood flow by 40%. Renal expression of TNF‐α, COX‐2, NF‐κB, IL‐1β, MCP‐1 and collagen type I were assessed in sham and 2K1C rats with or without left renal...

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Angewandte Chemie International Edition

Room‐Temperature‐Phosphorescence‐Based Dissolved Oxygen Detection by Core‐Shell Polymer Nanoparticles Containing Metal‐Free Organic Phosphors

Published: 22 November 2017

Author(s): Youngchang Yu, Min Sang Kwon, Jaehun Jung, Yingying Zeng, Mounggon Kim, Kyeongwoon Chung, Johannes Gierschner, Ji Ho Youk, Sergey M. Borisov, Jinsang Kim

Abstract The highly sensitive optical detection of oxygen including dissolved oxygen (DO) is of great interest in various applications. We devised a novel room‐temperature‐phosphorescence (RTP)‐based oxygen detection platform by constructing core–shell nanoparticles with water‐soluble polymethyloxazoline shells and oxygen‐permeable polystyrene cores crosslinked with metal‐free purely organic phosphors. The resulting nanoparticles...

thumbnail image: Angewandte Chemie International Edition

Journal of Applied Polymer Science

Compatibilization of the poly(lactic acid)/poly(propylene carbonate) blends through in situ formation of poly(lactic acid)‐ b ‐poly(propylene carbonate) copolymer

Published: 22 November 2017

Author(s): Zhao Wang, Min Zhang, Zhengying Liu, Shuyang Zhang, Zhiqiang Cao, Wei Yang, Mingbo Yang

ABSTRACT The in situ formation of poly(lactic acid)‐b‐poly(propylene carbonate) (PLA‐b‐PPC) block copolymers were carried out by the reaction between PLA and PPC in the presence of tetrabutyl titanate via transesterification. Molecular weight measurements and 13C nuclear magnetic resonance spectroscopy revealed that PLA‐b‐PPC block copolymers with higher molecular weight were obtained by controlling the reactivity point ratio between PLA chains ...

ChemPlusChem

Influence of the Anion on the Oxidation of 5‐Hydroxymethylfurfural by Using Ionic‐Polymer‐Supported Platinum Nanoparticle Catalysts

Published: 22 November 2017

Author(s): Sviatlana Siankevich, Simone Mozzettini, Felix Bobbink, Shipeng Ding, Zhaofu Fei, Ning Yan, Paul J. Dyson

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ChemPlusChem

Influence of the Anion on the Oxidation of 5‐Hydroxymethylfurfural by Using Ionic‐Polymer‐Supported Platinum Nanoparticle Catalysts

Published: 22 November 2017

Author(s): Sviatlana Siankevich, Simone Mozzettini, Felix Bobbink, Shipeng Ding, Zhaofu Fei, Ning Yan, Paul J. Dyson

Abstract Invited for this month's cover are the groups of Prof. Paul J. Dyson at Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland and Prof. Ning Yan at National University of Singapore, Singapore. The cover shows the catalytic conversion of 5‐hydroxymethylfurfural (5‐HMF) into 2,5‐furandicarboxylic acid catalyzed by platinum nanoparticles stabilized by polymeric imidazolium salts. The catalyst is represented by...

thumbnail image: ChemPlusChem

Journal of Applied Polymer Science

Fabrication of composite films with poly(methyl methacrylate) and incompletely condensed cage‐silsesquioxane fillers

Published: 22 November 2017

Author(s): Sota Yuasa, Yuri Sato, Hiroaki Imoto, Kensuke Naka

ABSTRACT Polyhedral oligomeric silsesquioxane (POSS) is a promising nanofiller for tuning properties of optically transparent polymer materials. On the other hand, traditional completely condensed POSS (CC‐POSS) has a fundamental problem for fabricating optically transparent composite films; CC‐POSS has high crystallinity due to its symmetrical structure, resulting in aggregation in the polymer matrices. In this work, we have...

Journal of Applied Polymer Science

Epoxy composite foams with excellent electromagnetic interference shielding and heat‐resistance performance

Published: 22 November 2017

Author(s): Jingkai Pan, Yu Xu, Jianjun Bao

ABSTRACT Epoxy composite foams with improved heat‐resistant property and efficient electromagnetic interference shielding effectiveness (EMI SE) were fabricated through a two‐step foaming technique. A sort of novel and untraditional expandable microspheres was adopted to reduce the density of prepared materials. A multiscale conductive network system composed of multiwalled carbon nanotubes (MWCNTs) and nickel‐plated carbon fibers...

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

October 2017

 


Bryan D. Ellis, Christopher D. Vanderwal
Hughes and Gleason's Virosaine A-Appreciating the Art in Synthesis [Highlight]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 13940

Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz
How We Make DNA Origami [Concept]
ChemBioChem 2017, vol. 18, p. 1873

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, p. 1523

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Flavia Izzo, Martina Schäfer, Robert Stockman, Ulrich Lücking
A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides [Full Paper]
Chem. Eur. J. 2017, vol. 23, p. 15189

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Paramita Mukherjee, Martin Pettersson, Jason K. Dutra, Longfei Xie, Christopher W. am Ende
Trifluoromethyl Oxetanes: Synthesis and Evaluation as a tert-Butyl Isostere [Communication]
ChemMedChem 2017, vol. 12, p. 1574

David D. Evanoff, George Chumanov
Synthesis and Optical Properties of Silver Nanoparticles and Arrays [Minireview]
ChemPhysChem 2005, vol. 6, p. 1221

Jonathan E. Barnsley, Bethany A. Lomax, James R. W. McLay, Christopher B. Larsen, Nigel T. Lucas, Keith C. Gordon
Flicking the Switch on Donor-Acceptor Interactions in Hexaazatrinaphthalene Dyes: A Spectroscopic and Computational Study [Article]
ChemPhotoChem 2017, vol. 1, p. 432

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Francesca Leonelli, Marinella Capuzzi, Vincenzo Calcagno, Pietro Passacantilli, Giovanni Piancatelli
Stereoselective Michael‐Type Addition of Organocopper Reagents to Enones Derived from Glycals in the Synthesis of 2‐Phosphono‐α‐C‐Glycosides [Short Communication]
Eur. J. Org. Chem. 2005, p. 2671

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Titandioxid: schön oder schädlich [Industrie & Technik]
Nachr. Chem. 2017, vol. 65, p. 1008

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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