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ChemBioChem

Photochemical Mechanism of an Atypical Algal Phytochrome

Published: 20 April 2018

Author(s): Uzma Choudry, Derren J. Heyes, Samantha J. O. Hardman, Michiyo Sakuma, Igor V. Sazanovich, Joyce Woodhouse, Eugenio De La Mora, Martin N. Pedersen, Michael Wulff, Martin Weik, Giorgio Schirò, Nigel S. Scrutton

Abstract Phytochromes are bilin‐containing photoreceptors that are typically sensitive to the red/far‐red region of the visible spectrum. Recently, phytochromes from certain eukaryotic algae have become attractive targets for optogenetic applications because of their unique ability to respond to multiple wavelengths of light. Herein, a combination of time‐resolved spectroscopy and structural approaches across picosecond to second...

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Chemistry - A European Journal

3 D Porous CoS 2 Hexadecahedron Derived from MOC toward Ultrafast and Long‐Lifespan Lithium Storage

Published: 20 April 2018

Author(s): Han‐Chi Wang, Zheng Cui, Chao‐Ying Fan, Si‐Yu Liu, Yan‐Hong Shi, Xing‐Long Wu, Jing‐Ping Zhang

Abstract A new hexadecahedron assembled by core–shell CoS2 particles@N‐doped carbon (CoS2@NCH) is prepared successfully through the self‐templating method. The CoS2@NCH hybrid electrode delivers a high lithium‐storage capacity of 778 mA h g−1 after 1000 cycles at a high current density of 1 A g−1, which is the longest cycle lifespan among the reported CoS2 anode materials in lithium‐ion batteries. Furthermore, the CoS2@NCH hybrid electrode shows excellent rate...

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ChemPlusChem

Optimization of Hexadentate Bispidine Ligands as Chelators for 64 Cu II PET Imaging

Published: 20 April 2018

Author(s): Peter Comba, Miriam Starke, Hubert Wadepohl

Abstract The coordination chemistry of the hexadentate bispidine ligand L1 with three pyridine, one pyridazine, and two tertiary amine donors with CuII and ZnII is reported. The substitution of one of the two cis‐disposed pyridine donors in‐plane with the two tertiary amines of the bispidine backbone by a pyridazine group was predicted to substantially reduce distortion from planarity of the tetradentate subunit and therefore was assumed to lead to higher ...

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ChemPlusChem

Multivalent Dendrimers and their Differential Recognition of Short Single‐Stranded DNAs of Various Length and Sequence

Published: 20 April 2018

Author(s): Yan Zhang, Eddy Petit, Mihail Barboiu

Abstract Polycationic dendrimers were generated through simple and versatile reversible amine/aldehyde–imine chemistry. The inherent CD spectroscopic signal arising from the helical structures of single‐stranded DNA (ssDNA) undergoes a dramatic amplification in the presence of the synthesised polycationic dendrimers. Compared to the first‐generation core molecule, the second‐generation dendrimer shows high spectroscopic responses...

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ChemPlusChem

The Antimicrobial Activity of Mononuclear Ruthenium(II) Complexes Containing the dppz Ligand

Published: 20 April 2018

Author(s): Xuewen Liu, Biyun Sun, Ruby E. M. Kell, Hannah M. Southam, Jonathan A. Butler, Xin Li, Robert K. Poole, F. Richard Keene, J. Grant Collins

Abstract The cis‐α isomer of [Ru(bb7)(dppz)]2+ (dppz=dipyrido[3,2‐a:2′,3′‐c]phenazine; bb7=bis[4(4′‐methyl‐2,2′‐bipyridyl)]‐1,7‐alkane) has been synthesised. The minimum inhibitory concentrations and the minimum bactericidal concentrations of [Ru(bb7)(dppz)]2+ and its parent complex [Ru(phen)2(dppz)]2+ (phen=1,10‐phenanthroline) were determined against a range of bacteria. The results showed that both ruthenium complexes exhibited good activity...

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Chemistry - A European Journal

Electrochemical C−O Bond Formation: Facile Access to Aromatic Lactones

Published: 20 April 2018

Author(s): Xiang‐Zhang Tao, Jian‐Jun Dai, Jie Zhou, Jun Xu, Hua‐Jian Xu

Abstract An efficient and robust methodology based on electrochemical techniques for the direct synthesis of aromatic lactones through dehydrogenative C−O cyclization is described. This new and useful electrochemical reaction can tolerate a variety of functional groups, and is scalable to 100 g under mild conditions. Remarkably, heterocycle‐containing substrates can be employed, thus expanding the scope of radical C−O cyclization...

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ChemSusChem

Hydrodehalogenation of Polyhalogenated Aromatics Catalyzed by NiPd Nanoparticles Supported on Nitrogen‐Doped Graphene

Published: 20 April 2018

Author(s): Xuefeng Guo, Chao Yu, Zhouyang Yin, Shouheng Sun, Christopher T. Seto

Abstract Ni30Pd70 nanoparticles supported on nitrogen‐doped graphene (NG) acts as a catalyst for the hydrodehalogenation of halogenated aromatics under mild reaction conditions. It reduces mono‐ or dichloroarenes to the corresponding dehalogenated arenes in >90 % yield in 10 % aqueous isopropanol solvent at or below 50 °C within 5 h. Tests on a variety of substrates containing various functional groups show that the catalyst is...

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ChemSusChem

Biowaste‐Derived Hierarchical Porous Carbon Nanosheets for Ultrahigh Power Density Supercapacitors

Published: 20 April 2018

Author(s): Dengfeng Yu, Chong Chen, Gongyuan Zhao, Lei Sun, Baosheng Du, Hong Zhang, Zhuo Li, Ye Sun, Flemming Besenbacher, Miao Yu

Abstract Low‐cost activated carbons with high capacitive properties remain desirable for supercapacitor applications. Herein, a three‐dimensional scaffolding framework of porous carbon nanosheets (PCNSs) has been produced from a typical biowaste, namely, ground cherry calyces, the specific composition and natural structures of which have contributed to the PCNSs having a very large specific surface area of 1612 m2 g−1, a...

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ChemBioChem

Chimeric Terpene Synthases Possessing both Terpene Cyclization and Prenyltransfer Activities

Published: 20 April 2018

Author(s): Takaaki Mitsuhashi, Ikuro Abe

Abstract Prenyltransferase (PT) and terpene synthase (TPS) are key enzymes in the formation of the basic carbon skeletons of terpenoids. The PTs determine the prenyl carbon chain length, whereas TPSs generate the structural complexity of the molecular scaffolds, forming various ring structures. Normally, PTs and TPSs are separate, independent enzymes. However, in 2007, a chimeric enzyme, in which the PT was fused with the TPS, was...

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Chemistry - A European Journal

Template‐Directed Synthesis of Titania Nanocages with Four Tetrahedrally Arranged Open Windows

Published: 20 April 2018

Author(s): Jiaji Cheng, Nicolas Mallet, Walid Baaziz, Ovidiu Ersen, Emilie Gombart, Valérie Alard, Jérôme Majimel, Marie‐Hélène Delville, Mona Tréguer‐Delapierre, Etienne Duguet

Abstract Original titania nanocages are fabricated from sacrificial silica/polystyrene tetrapod‐like templates. Here the template synthesis, titania deposition and nanocage development through polystyrene dissolution and subsequent silica etching are described. Discussion about the competitive deposition of titania on the biphasic templates is particularly emphasized. The morphology of the nanocages is investigated by TEM, STEM, EDX...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018

 


Zhang Luo, Bing Liu
Shape‐Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture]
Angew. Chem. Int. Ed. 10.1002/anie.201802726

Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens
MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication]
ChemBioChem 2018, vol. 19, p. 434

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber
Analytik mit Licht - Das Smartphone-Photometer [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 52

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication]
Chem. Eur. J. 2018, vol. 24, p. 4552

Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo
Aromatic Aminocatalysis [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 740

Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki
Abstract [Focus Review]
Asian J. Org. Chem. 10.1002/ajoc.201800013

Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 2018, vol. 13, p. 614

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 2018, vol. 2, p. 161

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson
The Use of Halide‐Substituted Anilines for the Formation of Magnesium Imides [Full Paper]
Eur. J. Inorg. Chem. 2008, p. 3935

D. B. Ramachary [Author Profile]
Eur. J. Org. Chem. 10.1002/ejoc.201800182

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Peter Chen
Chemistry 4.0 [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 203

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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