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Chemistry - A European Journal

Gold Redox Catalysis through Base‐Initiated Diazonium Decomposition toward Alkene, Alkyne, and Allene Activation

Published: 24 July 2017

Author(s): Boliang Dong, Haihui Peng, Stephen E. Motika, Xiaodong Shi

Abstract The discovery of photoassisted diazonium activation toward gold(I) oxidation greatly extended the scope of gold redox catalysis by avoiding the use of a strong oxidant. Some practical issues that limit the application of this new type of chemistry are the relative low efficiency (long reaction time and low conversion) and the strict reaction condition control that is necessary (degassing and inert reaction environment)....

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European Journal of Organic Chemistry

Design and Synthesis of Spirocycles

Published: 24 July 2017

Author(s): Sambasivarao Kotha, Nageswara Rao Panguluri, Rashid Ali

In this account we disclose a variety of simple strategies demonstrated in our laboratory in the last two decades for the assembly of diverse and intricate molecular frameworks containing spiro linkage(s) by using various metathesis protocols such as ring‐closing metathesis (RCM), ring‐opening cross‐metathesis (ROCM), ring‐closing enyne metathesis (RCEM) and ring‐rearrangement metathesis (RRM). Also, cycloaddition reactions ([2+2], [4+2]...

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Chemistry - A European Journal

α,β‐Unsaturated Amides as Dipolarophiles: Catalytic Asymmetric exo ‐Selective 1,3‐Dipolar Cycloaddition with Nitrones

Published: 24 July 2017

Author(s): Ming Zhang, Naoya Kumagai, Masakatsu Shibasaki

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Chemistry - A European Journal

Unearthing [3‐(Dimethylamino)propyl]aluminium(III) Complexes as Novel Atomic Layer Deposition (ALD) Precursors for Al 2 O 3 : Synthesis, Characterization and ALD Process Development

Published: 24 July 2017

Author(s): Lukas Mai, Maximilian Gebhard, Teresa de los Arcos, Ignacio Giner, Felix Mitschker, Manuela Winter, Harish Parala, Peter Awakowicz, Guido Grundmeier, Anjana Devi

Abstract Identification and synthesis of intramolecularly donor‐stabilized aluminium(III) complexes, which contain a 3‐(dimethylamino)propyl (DMP) ligand, as novel atomic layer deposition (ALD) precursors has enabled the development of new and promising ALD processes for Al2O3 thin films at low temperatures. Key for this promising outcome is the nature of the ligand combination that leads to heteroleptic Al complexes encompassing...

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Chemistry - A European Journal

Selectivity of C−H versus C−F Bond Oxygenation by Homo‐ and Heterometallic Fe 4 , Fe 3 Mn, and Mn 4 Clusters

Published: 24 July 2017

Author(s): Graham de Ruiter, Kurtis M. Carsch, Michael K. Takase, Theodor Agapie

Abstract A series of tetranuclear [LM3(HFArPz)3OM′][OTf]2 (M, M′=Fe or Mn) clusters that displays 3‐(2‐fluorophenyl)pyrazolate (HFArPz) as bridging ligand is reported. With these complexes, manganese was demonstrated to facilitate C(sp2)−F bond oxygenation via a putative terminal metal‐oxo species. Moreover, the presence of both ortho C(sp2)−H and C(sp2)−F bonds in proximity of the apical metal center provided an opportunity to investigate the selectivity...

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Chemistry - A European Journal

Decoding Nucleation and Growth of Zeolitic Imidazolate Framework Thin Films with Atomic Force Microscopy and Vibrational Spectroscopy

Published: 24 July 2017

Author(s): Zafer Öztürk, Matthias Filez, Bert M. Weckhuysen

Abstract The synthesis of metal‐organic framework (MOF) thin films has garnered significant attention during the past decade. By better understanding the parameters governing the nucleation and growth of such thin films, their properties can be rationally tuned, empowering their application as (reactive) membranes. Here, a combined AFM‐vibrational spectroscopy research strategy is employed to detail the chemistries governing the...

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Chemistry - A European Journal

Interactions between Ketones and Alcohols: Rotational Spectrum and Internal Dynamics of the Acetone–Ethanol Complex

Published: 24 July 2017

Author(s): Qian Gou, Laura B. Favero, Gang Feng, Luca Evangelisti, Cristóbal Pérez, Walther Caminati

Abstract The rotational spectra of two isotopologues of the 1:1 complex formed between acetone and ethanol have been recorded and analyzed by using Fourier‐transform microwave spectroscopy. One rotamer was detected, in which ethanol adopts the gauche form. The two subunits are linked by a conventional O−H⋅⋅⋅O and a weak C−H⋅⋅⋅O hydrogen bond, forming a six‐membered ring. Each rotational transition is split into five component lines due to the...

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Chemistry - A European Journal

A Flexible, Fused, Azomethine–Boron Complex: Thermochromic Luminescence and Thermosalient Behavior in Structural Transitions between Crystalline Polymorphs

Published: 24 July 2017

Author(s): Shunsuke Ohtani, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo

Abstract This manuscript reports the multi‐functional boron complex presenting aggregation‐induced emission (AIE), crystallization‐induced emission enhancement (CIEE), and thermosalient behavior accompanying thermochromic luminescence during crystal–crystal transitions by employing the fused azomethine ligand. In particular, we propose that these properties can be explained by molecular “flexibility” toward external stimuli,...

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Chemistry - A European Journal

Xenon Recovery at Room Temperature using Metal–Organic Frameworks

Published: 24 July 2017

Author(s): Sameh K. Elsaidi, Daniele Ongari, Wenqian Xu, Mona H. Mohamed, Maciej Haranczyk, Praveen K. Thallapally

Abstract Xenon is known to be a very efficient anesthetic gas, but its cost prohibits the wider use in medical industry and other potential applications. It has been shown that Xe recovery and recycling from anesthetic gas mixtures can significantly reduce its cost as anesthetic. The current technology uses series of adsorbent columns followed by low‐temperature distillation to recover Xe; this method is expensive to use in medical...

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Chemistry - A European Journal

Densification of Silica Spheres: A New Pathway to Nano‐Dimensioned Zeolite‐Based Catalysts

Published: 24 July 2017

Author(s): Albert Gonche Fortunatus Machoke, Benjamin Apeleo Zubiri, Rainer Leonhardt, Venkata Ramana Reddy Marthala, Martin Schmiele, Tobias Unruh, Martin Hartmann, Erdman Spiecker, Wilhelm Schwieger

Abstract Nanosized materials are expected to play a unique role in the development of future catalytic processes. Herein, pre‐prepared and geometrically well‐defined amorphous silica spheres are densified into silica‐rich zeolites with nanosized dimensions. After the densification, the obtained nanosized zeolites exhibit the same spherical morphology like the starting precursor but characterized by a drastically reduced size, higher...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2017


Yifeng Chen, David Huang, Yizhou Zhao, Timothy R. Newhouse
Allyl-Palladium-Catalyzed Ketone Dehydrogenation Enables Telescoping with Enone α,β-Vicinal Difunctionalization [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 8258

Stephan Hinderlich, Rudolf Tauber, Carolyn R. Bertozzi, Christian P. R. Hackenberger
Werner Reutter: A Visionary Pioneer in Molecular Glycobiology [Editorial]
ChemBioChem 2017, vol. 18, p. 1141

Hélène Olivier-Bourbigou, Céline Chizallet, Franck Dumeignil, Pascal Fongarland, Christophe Geantet, Pascal Granger, Franck Launay, Axel Löfberg, Pascale Massiani, Françoise Maugé, Armelle Ouali, Anne-Cécile Roger, Yves Schuurman, Nathalie Tanchoux, Denis Uzio, François Jérôme, Daniel Duprez, Catherine Pinel
The Pivotal Role of Catalysis in France: Selected Examples of Recent Advances and Future Prospects. [Review]
ChemCatChem 2017, vol. 9, p. 2029

Klaus Roth, Elisabeth Vaupel
Von Insekten, Chrysanthemen und Menschen [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 162

Rituparna Das, Balaram Mukhopadhyay
Chemical O‐Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Daniele Cortecchia, Cesare Soci, Massimo Cametti, Annamaria Petrozza, Javier Martí-Rujas
Crystal Engineering of a Two-Dimensional Lead-Free Perovskite with Functional Organic Cations by Second-Sphere Coordination [Communication]
ChemPlusChem 2017, vol. 82, p. 681

Yang Song, Rui Peng, Dale K. Hensley, Peter V. Bonnesen, Liangbo Liang, Zili Wu, Harry M. Meyer, Miaofang Chi, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Ligang Feng, Huaiguo Xue
Advances in Transition-Metal Phosphide Applications in Electrochemical Energy Storage and Catalysis [Minireview]
ChemElectroChem 2017, vol. 4, p. 20

Amal Kumar Mandal, Javeed Mahmood, Jong-Beom Baek
Two-Dimensional Covalent Organic Frameworks for Optoelectronics and Energy Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 373

Tuhin Patra, Debabrata Maiti
Decarboxylation as the Key Step in C−C Bond-Forming Reactions [Review]
Chem. Eur. J. 2017, vol. 23, p. 7382

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Edmond Differding
The Drug Discovery and Development Industry in India-Two Decades of Proprietary Small-Molecule R&D [Review]
ChemMedChem 2017, vol. 12, p. 786

Gianfranco Pacchioni
Oxygen Vacancy: The Invisible Agent on Oxide Surfaces [Minireview]
ChemPhysChem 2003, vol. 4, p. 1041

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, p. 148

Sammy W. Verbruggen, Myrthe Van Hal, Tom Bosserez, Jan Rongé, Birger Hauchecorne, Johan A. Martens, Silvia Lenaerts
Inside Back Cover: Harvesting Hydrogen Gas from Air Pollutants with an Unbiased Gas Phase Photoelectrochemical Cell (ChemSusChem 7/2017) [Cover Picture]
ChemSusChem 2017, vol. 10, p. 1640

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal‐Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Lakshmana K. Kinthada, K. Naresh Babu, Dikshaa Padhi, Alakesh Bisai
Lewis-Acid-Catalysed Reaction of 3-Hydroxy-2-oxindoles with Terminal Alkynes: Synthetic Approaches to the Pyrroloindoline Alkaloids [Full Paper]
Eur. J. Org. Chem. 2017, p. 3078

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Reinhard Zellner
Die Fakten und ihre Wahrnehmung [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 662

Holger Fleischer
Fehlinterpretation der Fehling-Probe auf reduzierende Zucker - Von der Beobachtung im Chemieunterricht zur Evidenz gegen die Oxidation der Aldehydgruppe [Artikel]
CHEMKON 2017, vol. 24, p. 27

Sarah Millar
Tips and Tricks for the Lab: Column Choices
ChemViews Magazine 2012.

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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