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Chemistry - A European Journal

The Dynamic Equilibrium of Hexakispentafluoroethyldistannane Adducts XSnC 2 F 5 3 SnC 2 F 5 3 XCl Br I SnC 2 F 5 3

Published: 21 February 2018

Author(s): Markus Wiesemann, Johannes Klösener, Beate Neumann, Hans‐Georg Stammler, Berthold Hoge

Abstract The tin–tin bond cleavage of hexaorganodistannanes by nucleophiles is a long‐known reaction and widely used for stannate formation or stannyl group transfer. Herein, we detail our experiments to provide analytical evidence for the existence of the reasonably stable anionic complexes [XSn(C2F5)3{Sn(C2F5)3}]− (X=Cl, Br, I, Sn(C2F5)3) derived from hexakis(pentafluoroethyl)distannane. NMR investigations at low temperature lend further...

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Chemistry - A European Journal

New WaterSoluble Cluster Compound Znen 3 3 V 15 Sb 6 O 42 H 2 O Ethylenediamine 3 10H 2 O as a Synthon for the Generation of Two New Antimonato Polyoxovanadates

Published: 21 February 2018

Author(s): Lisa K. Mahnke, Ulrike Warzok, Mengxi Lin, Christian Näther, Christoph A. Schalley, Wolfgang Bensch

Abstract A new antimonato polyoxovanadate {Zn(en)3}3[V15Sb6O42(H2O)]⋅3 en⋅10 H2O (en=ethylenediamine) synthesized under hydrothermal conditions exhibits remarkable solubility in water. Electrospray ionization mass spectrometry (ESI‐MS) investigations on an aqueous solution demonstrate that the cluster core remains fully intact for 72 h. At longer times, slow transformation into a {V14Sb8O42} cluster is observed. The conversion reaches 50 %...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Cyclodextrin‐Sandwiched Hexaphyrin Hybrids: Side‐to‐Side Cavity Coupling Switched by a Temperature‐ and Redox‐Responsive Central Device

Published: 21 February 2018

Author(s): Mickaël Ménand, Matthieu Sollogoub, Bernard Boitrel, Stéphane Le Gac

Abstract Access to allosteric enzyme mimics that ideally associate communicating compartments for catalysis and regulation is still challenging. Whereas a sandwich “cavity–catalyst–cavity” approach, developed mainly with cyclodextrins and porphyrins, appears promising, its counterpart with hexaphyrins featuring rich conformation, aromaticity, and coordination behavior has not been prospected at all. We thus developed sandwich...

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Structural Change of a Single Ag Nanoparticle Observed by Dark‐field Microspectroscopy

Published: 21 February 2018

Author(s): Jie Pang, Hai‐Ling Liu, Jian Li, Ting‐Ting Zhai, Kang Wang, Xing‐Hua Xia

Abstract Silver nanoparticles (AgNPs) have been widely used as photocatalysts and nanosensors. Observation of the spectroscopy of a single AgNP greatly helps us understand the catalytic characteristics and morphology change of the AgNP during reactions. In the present study, AgNPs physically adsorbed on indium tin oxide (ITO) conductive glass were electrochemically reduced and oxidized, and the plasmonic resonance Rayleigh...

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Chemistry - A European Journal

Circularly Polarized Luminescence from Inorganic Materials: Encapsulating Guest Lanthanide Oxides in Chiral Silica Hosts

Published: 21 February 2018

Author(s): Masumi Sugimoto, Xin‐Ling Liu, Seiji Tsunega, Erika Nakajima, Shunsuke Abe, Takuya Nakashima, Tsuyoshi Kawai, Ren‐Hua Jin

Abstract Invited for the cover of this issue is the group of Ren‐Hua Jin at the Kanagawa University and co‐workers at Nara Institute of Science and Technology. The image depicts lanthanide metals encapsulated within temperature‐resistant chiral silica emitting polarized light. Read the full text of the article at 10.1002/chem.201705862.

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Programming Recognition Arrays through Double Chalcogen‐Bonding Interactions

Published: 21 February 2018

Author(s): Nicolas Biot, Davide Bonifazi

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Computational Study of the Aza‐Michael Addition of the Flavonoid (+)‐Taxifolin in the Inhibition of β‐Amyloid Fibril Aggregation

Published: 21 February 2018

Author(s): Tiziana Ginex, Marta Trius, F. Javier Luque

thumbnail image: Chemistry - A European Journal


Spectroscopic and Hydrodynamic Characterisation of DNA‐Linked Gold Nanoparticle Dimers in Solution using Two‐Photon Photoluminescence

Published: 21 February 2018

Author(s): Johanna Midelet, Afaf H. El‐Sagheer, Tom Brown, Antonios G. Kanaras, Anne Débarre, Martinus H. V. Werts

Abstract Two‐photon photoluminescence (TPPL) emission spectra of DNA–gold nanoparticle (AuNP) monoconjugates and the corresponding DNA‐linked AuNP dimers are obtained by photon time‐of‐flight spectroscopy. This technique is combined with two‐photon photoluminescence fluctuation correlation spectroscopy (TPPL–FCS) to simultaneously monitor the optical and hydrodynamic behaviour of these nano‐assemblies in solution, with...

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Chemistry - A European Journal

Interfacial Generation of a Carbanion: The Key Step of PTC Reaction Directly Observed by Second Harmonic Generation

Published: 21 February 2018

Author(s): Michal Hamkalo, Piotr Fita, Michal Fedorynski, Mieczyslaw Makosza

Abstract We present the first unambiguous evidence of the interfacial mechanism of phase‐transfer catalysis (PTC) by direct observation of the formation of carbanions in the interfacial region between the aqueous and the organic phase by using a surface‐sensitive spectroscopic method known as second harmonic generation (SHG). Ion exchange of carbanions adsorbed at the surface after addition of lipophilic tetraalkylammonium salts...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Self‐Assembled Cofacial Zinc–Porphyrin Supramolecular Nanocapsules as Tuneable 1 O 2 Photosensitizers

Published: 21 February 2018

Author(s): Cédric Colomban, Carles Fuertes‐Espinosa, Sébastien Goeb, Marc Sallé, Miquel Costas, Lluís Blancafort, Xavi Ribas

Abstract We demonstrate the benefits of using cofacial Zn–porphyrins as structural synthons in coordination‐driven self‐assembled prisms to produce cage‐like singlet oxygen (1O2) photosensitizers with tunable properties. In particular, we describe the photosensitizing and emission properties of palladium‐ and copper‐based supramolecular capsules, and demonstrate that the nature of the bridging metal nodes in these discrete self‐assembled ...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

January 2018


New Academicians and Foreign Members of the Chinese Academy of Sciences [News]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 1445

Michael Dirkmann, Javier Iglesias-Fernández, Victor Muñoz, Pandian Sokkar, Christoph Rumancev, Andreas von Gundlach, Oktavian Krenczyk, Tobias Vöpel, Julia Nowack, Martin A. Schroer, Simon Ebbinghaus, Christian Herrmann, Axel Rosenhahn, Elsa Sanchez-Garcia, Frank Schulz
A Multiperspective Approach to Solvent Regulation of Enzymatic Activity: HMG-CoA Reductase [Communication]
ChemBioChem 2018, vol. 19, p. 153

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Haymo Ross
We are Family (Chemistry Smash Hits) [Editorial]
Chem. Eur. J. 2018, vol. 24, p. 6

Xinzhe Shi, Arpan Sasmal, Jean-François Soulé, Henri Doucet
Metal-Catalyzed C−H Bond Activation of 5-Membered Carbocyclic Rings: A Powerful Access to Azulene, Acenaphthylene and Fulvene Derivatives [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 143

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Truong-Thanh Tung, Trong T. Dao, Marta G. Junyent, Michael Palmgren, Thomas Günther-Pomorski, Anja T. Fuglsang, Søren B. Christensen, John Nielsen
Cover Feature: LEGO-Inspired Drug Design: Unveiling a Class of Benzo[d]thiazoles Containing a 3,4-Dihydroxyphenyl Moiety as Plasma Membrane H+-ATPase Inhibitors (ChemMedChem 1/2018) [Cover Picture]
ChemMedChem 2018, vol. 13, p. 2

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Dogukan Hazar Apaydin, Dong Ryeol Whang
Artificial Photosynthesis: Learning from Nature [Review]
ChemPhotoChem 10.1002/cptc.201700163

Jiwhan Kim, Hee-Eun Kim, Hyunjoo Lee
Single-Atom Catalysts of Precious Metals for Electrochemical Reactions [Minireview]
ChemSusChem 2018, vol. 11, p. 104

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, p. 18

Deutscher Lebensmittelchemikertag 2016 in Freising-Weihenstephan [Vorträge]
Lebensmittelchemie 2017, vol. 71, p. 2

Meilensteine der Chemie 2018 [Bildung & Gesellschaft]
Nachr. Chem. 2018, vol. 66, p. 38

Katrin Sommer, Christina Toschka, Laura Schröder, Thomas Philipp Schröder, Henning Steff, Roland A. Fischer
Modellexperimente im Chemieunterricht. [Artikel]
CHEMKON 2017, vol. 24, p. 13

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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