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European Journal of Inorganic Chemistry

Platinum Intercalators of DNA as Anticancer Agents

Published: 20 January 2017

Author(s): Benjamin J. Pages, K. Benjamin Garbutcheon‐Singh, Janice R. Aldrich‐Wright

The drawbacks of the platinum chemotherapy agents cisplatin, carboplatin and oxaliplatin have inspired the development of compounds with different mechanisms of action. Polyaromatic platinum complexes (PPCs) are a promising anticancer alternative; these bind reversibly with DNA through the insertion of a planar aromatic moiety between nucleobases in a process known as intercalation. PPCs have demonstrated in vitro behaviour remarkably...

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ChemistryOpen

Relationship between Side‐Chain Polarity and the Self‐Assembly Characteristics of Perylene Diimide Derivatives in Aqueous Solution

Published: 20 January 2017

Author(s): Jurgen Schill, Lech‐Gustav Milroy, Jody A. M. Lugger, Albertus P. H. J. Schenning, Luc Brunsveld

Abstract Perylene‐3,4,9,10‐tetracarboxylic acid diimides (PDIs) have recently gained considerable interest for water‐based biosensing applications. PDIs have been studied intensively in the bulk state, but their physical properties in aqueous solution in interplay with side‐chain polarity are, however, poorly understood. Therefore, three perylene diimide based derivatives were synthesized to study the relationship between side‐chain...

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ChemPhysChem

Photoinduced Charge Separation Catalyzed by Manganese Oxides onto a Y‐Shaped Branching Acceptor Efficiently Preventing Charge Recombination

Published: 20 January 2017

Author(s): Kentaro Yamamoto, Kazuo Takatsuka

Abstract A full‐dimensional nonadiabatic electron wavepacket study is performed on Mn oxide catalytic charge separation to be created on an accepting molecular system, which is of Y‐shaped structure and has a track‐branching function for protons and electrons. This branching is necessary in cases in which the transferred electrons and protons are to be eventually carried to mutually different destinations without quick annihilation...

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ChemSusChem

Synthesis and Characterisation of Reduced Graphene Oxide/Bismuth Composite for Electrodes in Electrochemical Energy Storage Devices

Published: 20 January 2017

Author(s): Jiabin Wang, Han Zhang, Michael R. C. Hunt, Alasdair Charles, Jie Tang, Oana Bretcanu, David Walker, Khalil T. Hassan, Yige Sun, Lidija Šiller

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ChemCatChem

Nitrogen‐Doped Hierarchical Porous Carbons Derived from Sodium Alginate as Efficient Oxygen Reduction Reaction Electrocatalysts

Published: 20 January 2017

Author(s): Cuijuan Xuan, Zexing Wu, Wen Lei, Jie Wang, Junpo Guo, Deli Wang

Abstract The exploration of earth‐abundant and low‐cost eco‐friendly materials with an excellent electrocatalytic performance is crucial for sustainable energy development. In this work, 3 D N‐doped hierarchical porous carbon (NC) materials with an interconnected mesoporous/macroporous structure have been synthesized by the simple single‐step pyrolysis of naturally available sodium alginate in the presence of urea. The systematic...

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ChemPlusChem

Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands

Published: 20 January 2017

Author(s): Bastien Michelet, David Lebœuf, Christophe Bour, Karel Škoch, Filip Horký, Petr Štěpnička, Vincent Gandon

Abstract Two new cationic dinuclear gold(I) complexes, [Au2{μ(P,N)‐5}2]X2—in which X=NTf2 (7; Tf=trifluoromethanesulfonate) or SbF6 (8) and 2‐(diphenylphosphanyl)benzonitrile (5) is a P,N‐bridging donor—have been synthesized and structurally characterized. These air‐stable species and their dimeric and polymeric analogues possessing 1′‐(diphenylphosphanyl)‐1‐cyanoferrocene (1) as the bridging ligand, [Au2{μ(P,N)‐1}2](NTf2)2 and [Au{μ(P,N)‐1}]n[SbF6]n, were...

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ChemBioChem

Enzyme from an Uncultivated Sponge Bacterium Catalyzes S‐Methylation in a Ribosomal Peptide

Published: 20 January 2017

Author(s): Maximilian J. Helf, Aurelia Jud, Jörn Piel

Abstract Amino acid modifications are essential for the structural diversity and bioactivity of ribosomally synthesized and post‐translationally modified peptide natural products (RiPPs). A particularly large and virtually untapped pool of unusual RiPPs and associated modifying enzymes is provided by uncultivated bacteria. An example is the chemically rich sponge symbiont “Candidatus Entotheonella factor”, which produces the hypermodified...

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ChemBioChem

An Engineered Tryptophan Synthase Opens New Enzymatic Pathways to β‐Methyltryptophan and Derivatives

Published: 20 January 2017

Author(s): Daniel Francis, Michael Winn, Jonathan Latham, Michael F. Greaney, Jason Micklefield

Abstract β‐Methyltryptophans (β‐mTrp) are precursors in the biosynthesis of bioactive natural products and are used in the synthesis of peptidomimetic‐based therapeutics. Currently β‐mTrp is produced by inefficient multistep synthetic methods. Here we demonstrate how an engineered variant of tryptophan synthase from Salmonella (StTrpS) can catalyse the efficient condensation of l‐threonine and various indoles to generate β‐mTrp and derivatives...

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Chemistry - A European Journal

Silicone‐Based Organic–Inorganic Hybrid Aerogels and Xerogels

Published: 20 January 2017

Author(s): Taiyo Shimizu, Kazuyoshi Kanamori, Kazuki Nakanishi

Abstract Aerogels are attracting increasing attention due to their high thermal insulation ability as well as unique properties such as high porosity, surface area, and transparency. However, low mechanical strengths, originating from their unique porous structure, impede handling, formability, mass production, and extended applications. This minireview focuses on the strengthening of aerogels by several organic–inorganic...

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Chemistry - A European Journal

How Do Phosphinates React with Unactivated Alkenes Under Organic Photocatalyzed Conditions? Substrate Scope and Mechanistic Insights

Published: 20 January 2017

Author(s): Giovanni Fausti, Fabrice Morlet‐Savary, Jacques Lalevée, Annie‐Claude Gaumont, Sami Lakhdar

Abstract The first visible‐light‐mediated, metal‐free hydrophosphinylation of unactivated alkenes with ethyl and butyl phosphinates is described. The reaction works with a low catalyst loading of 9‐mesityl‐10‐methylacridinium perchlorate (Fukuzumi photocatalyst, 0.5 mol %) in the presence of diphenyliodonium triflate as oxidant. The reaction proceeds smoothly and covers a broad scope of substrates. Detailed mechanistic...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

December 2016

 


Thomas Scattolin, Kristina Deckers, Franziska Schoenebeck
Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench‐Stable Precursor (Me4N)SCF3 [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 221

Alex R. Maolanon, Helle M. E. Kristensen, Luke J. Leman, M. Reza Ghadiri, Christian A. Olsen
Natural and Synthetic Macrocyclic Inhibitors of the Histone Deacetylase Enzymes [Review]
ChemBioChem 2017, vol. 18, p. 5

Isabela C. Man, Hai‐Yan Su, Federico Calle‐Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Dieter Wöhrle
Kampf‐ und Explosivstoffe [Treffpunkt Forschung]
Chem. Unserer Zeit 2016, vol. 50, p. 369

Thammadihalli Nanjundaiah Ravishankar, Thippeswamy Ramakrishnappa, Ganganagappa Nagaraju, Hanumanaika Rajanaika
Synthesis and Characterization of CeO2 Nanoparticles via Solution Combustion Method for Photocatalytic and Antibacterial Activity Studies [Full Paper]
ChemistryOpen 2015, vol. 4, p. 146

Andrea Liscio, Konstantinos Kouroupis‐Agalou, Alessandro Kovtun, Elias Gebremedhn, Mohamed El Garah, Wassima Rekab, Emanuele Orgiu, Loris Giorgini, Paolo Samorì, David Beljonne, Vincenzo Palermo
Exfoliation of Few‐Layer Graphene in Volatile Solvents Using Aromatic Perylene Diimide Derivatives as Surfactants [Full Paper]
ChemPlusChem 2016, 10.1002/cplu.201600503

Yang Song, Rui Peng, Dale K. Hensley, Peter V. Bonnesen, Liangbo Liang, Zili Wu, Harry M. Meyer, Miaofang Chi, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High‐Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N‐Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, 10.1002/slct.201601169

Florian Ausfelder, Christian Beilmann, Martin Bertau, Sigmar Bräuninger, Angelika Heinzel, Renate Hoer, Wolfram Koch, Falko Mahlendorf, Anja Metzelthin, Marcell Peuckert, Ludolf Plass, Konstantin Räuchle, Martin Reuter, Georg Schaub, Sebastian Schiebahn, Ekkehard Schwab, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl‐Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Vida Zargar, Morteza Asghari, Amir Dashti
A Review on Chitin and Chitosan Polymers: Structure, Chemistry, Solubility, Derivatives, and Applications [Review]
ChemBioEng Rev. 2015, vol. 2, p. 204

Hanan Al‐Kutubi, Jorge Gascon, Ernst J. R. Sudhölter, Liza Rassaei
Electrosynthesis of Metal–Organic Frameworks: Challenges and Opportunities [Review]
ChemElectroChem 2015, vol. 2, p. 462

Changsoon Choi, Moon Kee Choi, Taeghwan Hyeon, Dae‐Hyeong Kim
Nanomaterial‐Based Soft Electronics for Healthcare Applications [Focus Review]
ChemNanoMat 2016, 10.1002/cnma.201600191

Marco Simonetti, Diego M. Cannas, Adyasha Panigrahi, Szymon Kujawa, Michal Kryjewski, Pan Xie, Igor Larrosa
Ruthenium‐Catalyzed C−H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides [Communication]
Chem. Eur. J. 2016, 10.1002/chem.201605068

Yasuhide Inokuma, Kazuki Matsumura, Shota Yoshioka, Makoto Fujita
Finding a New Crystalline Sponge from a Crystallographic Database [Communication]
Chem. Asian J. 2016, 10.1002/asia.201601551

Naoki Asari, Yusuke Takemoto, Yukino Shinomoto, Takuma Yagyu, Akira Yoshimura, Viktor V. Zhdankin, Akio Saito
Cover Picture: Catalytic Cycloisomerization–Fluorination Sequence of N‐Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems (Asian J. Org. Chem. 11/2016) [Cover Picture]
Asian J. Org. Chem. 2016, vol. 5, p. 1295

Hilmar Weinmann
Cancer Immunotherapy: Selected Targets and Small‐Molecule Modulators [Review]
ChemMedChem 2016, vol. 11, p. 450

Chuyang Cheng, J. Fraser Stoddart
Wholly Synthetic Molecular Machines [Minireview]
ChemPhysChem 2016, vol. 17, p. 1780

Jahangir Masud, Polydoros‐Chrysovalantis Ioannou, Nikolaos Levesanos, Panayotis Kyritsis, Manashi Nath
A Molecular Ni‐complex Containing Tetrahedral Nickel Selenide Core as Highly Efficient Electrocatalyst for Water Oxidation [Cover Profile]
ChemSusChem 2016, vol. 9, p. 3123

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal‐Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, 10.1002/ejic.201600394

Subhadip Maiti, Laxminarayana Burgula, Jyotirmayee Dash
Palladium Catalyzed Pyridine Group Directed RegioselectiveOxidative C‐H Acylation of Carbazoles Using Aldehydes as theAcyl Source [Full Paper]
Eur. J. Org. Chem. 2016, 10.1002/ejoc.201601322

45. Deutscher Lebensmittelchemikertag 2016 in Freising [Tagungen]
Lebensmittelchemie 2016, vol. 70, p. 157

Rainer Herges
Molekulare Maschinen [Wissenschaft & Forschung]
Nachr. Chem. 2016, vol. 64, p. 1045

Stefan Schwarzer, Ramzy Abdelaziz, Mady Elbahri, Timm Wilke
Wenn ein Wassertropfen zum Nanolabor wird [Das Experiment]
CHEMKON 2016, vol. 23, p. 188

Sarah Millar
Tips and Tricks for the Lab: Column Choices
ChemViews Magazine 2012.

Most Cited articles from ChemPubSoc Europe, ACES, and GDCh journals


2015

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Ashish Kumar Singh, Qiang Xu
Synergistic Catalysis over Bimetallic Alloy Nanoparticles [Review]
ChemCatChem 2013, vol. 5, pp. 652–676

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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