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European Journal of Inorganic Chemistry

Basicity of N ‐(Tetramesityltetraphosphacyclopentylidene)cyclohexylamine: An Unusual Diphospha(III)guanidine Derivative

Published: 22 September 2017

Author(s): Anup Kumar Adhikari, Toni Grell, Peter Lönnecke, Evamarie Hey‐Hawkins

The nitrogen atom in cyclic hetero‐oligophosphane cyclo‐P4Mes4C(NCy) (1) can be protonated with HCl or HBF4. The resulting cation was isolated as the BF4–, AlCl4– and GaCl4– salts and characterised by NMR spectroscopy, mass spectrometry and X‐ray crystallography. According to quantum mechanical calculations, the basicity of compound 1 is comparable to that of methyl‐substituted monophospha(III)guanidine. The pKα value of 1 was also determined experimentally with...

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European Journal of Organic Chemistry

Online Monitoring of Polymerizations: Current Status

Published: 22 September 2017

Author(s): Joris J. Haven, Tanja Junkers

Polymerizations are challenging to monitor online. Next to spectrometric information, which indicates the composition, progress, and identity of polymers, other characterization methods also need to be employed for paramount monitoring. Information on molecular weight distributions and end group patterns are often indispensable for accurate process (and product) control. An overview of existing characterization methods, which can be used...

thumbnail image: European Journal of Organic Chemistry


Effect of Formamidinium/Cesium Substitution and PbI 2 on the Long‐Term Stability of Triple‐Cation Perovskites

Published: 22 September 2017

Author(s): Shashwat Shukla, Sudhanshu Shukla, Lew Jia Haur, Sai S. H. Dintakurti, Guifang Han, Anish Priyadarshi, Tom Baikie, Subodh G. Mhaisalkar, Nripan Mathews

Abstract Altering cation and anion ratios in perovskites has proven an excellent means of tuning the perovskite properties and enhancing the performance. Recently, methylammonium/formamidinium/cesium triple‐cation mixed‐halide perovskites have demonstrated efficiencies up to 22 %. Similar to the widely explored methylammonium lead halide, excess PbI2 is added to these perovskite films to enhance their performances. The excess PbI2 is known to...

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Chemistry - A European Journal

C−H Cyanation of 6‐Ring N‐Containing Heteroaromatics

Published: 22 September 2017

Author(s): Bryony L. Elbert, Alistair J. M. Farley, Timothy W. Gorman, Tarn C. Johnson, Christophe Genicot, Bénédicte Lallemand, Patrick Pasau, Jakub Flasz, José L. Castro, Malcolm MacCoss, Robert S. Paton, Christopher J. Schofield, Martin D. Smith, Michael C. Willis, Darren J. Dixon

Abstract Heteroaromatic nitriles are important compounds in drug discovery, both for their prevalence in the clinic and due to the diverse range of transformations they can undergo. As such, efficient and reliable methods to access them have the potential for far‐reaching impact across synthetic chemistry and the biomedical sciences. Herein, we report an approach to heteroaromatic C−H cyanation through triflic anhydride activation,...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Synthesis and Reactivity of a Scandium Terminal Hydride: H 2  Activation by a Scandium Terminal Imido Complex

Published: 22 September 2017

Author(s): Xianghao Han, Li Xiang, Carlos A. Lamsfus, Weiqing Mao, Erli Lu, Laurent Maron, Xuebing Leng, Yaofeng Chen

Abstract Dihydrogen is easily activated by a scandium terminal imido complex containing the weakly coordinated THF. The reaction proceeds through a 1,2‐addition mechanism, which is distinct from the σ‐bond metathesis mechanism reported to date for rare‐earth metal‐mediated H2 activation. This reaction yields a scandium terminal hydride, which is structurally well‐characterized, being the first one to date. The reactivity of this...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

In‐Situ Fabrication of MOF‐Derived Co−Co Layered Double Hydroxide Hollow Nanocages/Graphene Composite: A Novel Electrode Material with Superior Electrochemical Performance

Published: 22 September 2017

Author(s): Xue Bai, Jingyuan Liu, Qi Liu, Rongrong Chen, Xiaoyan Jing, Bin Li, Jun Wang

Abstract Rational design of a transition metal layered double hydroxide (LDH) and graphene composite is vitally important for designing high‐performance supercapacitor electrodes. Although various methods are performed, the realization of high‐performance is still impeded by the agglomeration of graphene and layered double hydroxide. Here, metal–organic framework derived cobalt–cobalt layered double hydroxide (Co−Co LDH) hollow...

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Ribbon‐like Foldamers for Cellular Uptake and Drug Delivery

Published: 22 September 2017

Author(s): Lubomir L. Vezenkov, Vincent Martin, Nadir Bettache, Matthieu Simon, Alexandre Messerschmitt, Baptiste Legrand, Jean‐Louis Bantignies, Gilles Subra, Marie Maynadier, Virginie Bellet, Marcel Garcia, Jean Martinez, Muriel Amblard

Abstract Different intracellular delivery systems of bioactive compounds have been developed, including cell‐penetrating peptides. Although usually nontoxic and biocompatible, these vectors share some of the general drawbacks of peptides, notably low bioavailability and susceptibility to protease degradation, that limit their use. Herein, the conversion of short peptide sequences into poly‐α‐amino‐γ‐lactam foldamers that adopt a...

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Aromatic Halogenation by Using Bifunctional Flavin Reductase–Halogenase Fusion Enzymes

Published: 22 September 2017

Author(s): Mary C. Andorfer, Ketaki D. Belsare, Anna M. Girlich, Jared C. Lewis

Abstract The remarkable site selectivity and broad substrate scope of flavin‐dependent halogenases (FDHs) has led to much interest in their potential as biocatalysts. Multiple engineering efforts have demonstrated that FDHs can be tuned for non‐native substrate scope and site selectivity. FDHs have also proven useful as in vivo biocatalysts and have been successfully incorporated into biosynthetic pathways to build new chlorinated...

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Organocatalytic Synthesis of Lactones by the Oxidation of Alkenoic Acids

Published: 22 September 2017

Author(s): Ierasia Triandafillidi, Marianna Raftopoulou, Anatoli Savvidou, Christoforos G. Kokotos

Abstract Along the lines of modern sustainable oxidation, a green and mild organocatalytic synthetic procedure for the synthesis of hydroxylactones from alkenoic acids is described. The reaction includes the activation of H2O2 by an organocatalyst (2,2,2‐trifluoromethylacetophenone), the oxidation of an olefinic group to the corresponding epoxide, and intramolecular lactonization to afford a variety of substituted γ‐ or δ‐lactones with multiple...

thumbnail image: ChemCatChem


Isomerizing Hydroformylation of Cashew Nut Shell Liquid

Published: 22 September 2017

Author(s): Swechchha Pandey, Dinesh R. Shinde, Samir H. Chikkali

Abstract A small library of bisphosphorus ligands was evaluated in the rhodium‐catalyzed isomerizing hydroformylation (I‐HF) of cashew nut shell liquid (CNSL). The rhodium complex of 1,2‐bis((di‐tert‐butylphosphanyl)methyl)benzene (BDTBPMB; L4) outperformed the other bisphosphite and bisphosphine ligands and unveiled a moderate selectivity of 28 % and 50 % in the I‐HF of CNSL monoene and methoxy‐protected monoene, respectively. The resultant...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

July 2017


Xinxing Zhang, Gaoxiang Liu, Sandra Ciborowski, Kit Bowen
Stabilizing Otherwise Unstable Anions with Halogen Bonding [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 9897

Jonathan Okerblom, Ajit Varki
Biochemical, Cellular, Physiological, and Pathological Consequences of Human Loss of N-Glycolylneuraminic Acid [Review]
ChemBioChem 2017, vol. 18, p. 1155

Hélène Olivier-Bourbigou, Céline Chizallet, Franck Dumeignil, Pascal Fongarland, Christophe Geantet, Pascal Granger, Franck Launay, Axel Löfberg, Pascale Massiani, Françoise Maugé, Armelle Ouali, Anne-Cécile Roger, Yves Schuurman, Nathalie Tanchoux, Denis Uzio, François Jérôme, Daniel Duprez, Catherine Pinel
The Pivotal Role of Catalysis in France: Selected Examples of Recent Advances and Future Prospects. [Review]
ChemCatChem 2017, vol. 9, p. 2029

Klaus Roth, Elisabeth Vaupel
Von Insekten, Chrysanthemen und Menschen [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 162

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Marc T. M. Koper, Hasan Yılmaz, Ruud Kortlever, Recep Kas, Guido Mul
Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO2 Electroreduction by Process Conditions [Communication]
ChemElectroChem 2015, vol. 2, p. 354

Liming Dai, Xinliang Feng, Zhongfan Liu, Hua Zhang
Two-Dimensional Materials: A Powerful Platform for Energy Applications [Editorial]
ChemNanoMat 2017, vol. 3, p. 338

Ralf Haiges, Piyush Deokar, Monica Vasiliu, Trent H. Stein, David A. Dixon, Karl O. Christe
Cover Picture: Preparation and Characterization of Group 13 Cyanides (Chem. Eur. J. 38/2017) [Cover Picture]
Chem. Eur. J. 2017, vol. 23, p. 8989

Yilong Yang, Songcan Wang, Yongli Li, Jinshu Wang, Lianzhou Wang
Strategies for Efficient Solar Water Splitting Using Carbon Nitride [Focus Review]
Chem. Asian J. 2017, vol. 12, p. 1421

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Edmond Differding
The Drug Discovery and Development Industry in India-Two Decades of Proprietary Small-Molecule R&D [Review]
ChemMedChem 2017, vol. 12, p. 786

Sergey Akbulatov, Roman Boulatov
Experimental Polymer Mechanochemistry and its Interpretational Frameworks [Review]
ChemPhysChem 2017, vol. 18, p. 1422

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, p. 148

Hirotaka Koga, Naoko Namba, Tsukasa Takahashi, Masaya Nogi, Yuta Nishina
Renewable Wood Pulp Paper Reactor with Hierarchical Micro/Nanopores for Continuous-Flow Nanocatalysis [Communication]
ChemSusChem 2017, vol. 10, p. 2560

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

MATLAB für Dummies von Jim Sizemore und John Paul Mueller [Buchbesprechung]
Lebensmittelchemie 2017, vol. 71, p. 32

Reinhard Zellner
Die Fakten und ihre Wahrnehmung [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 662

Jana Thomas, Sabine Struckmeier, Bernhard F. Sieve
„Molekulares Sieben 2.0“ - vom Kontinuum zum Diskontinuum mit molekularer Küche [Das Experiment]
CHEMKON 2017, vol. 24, p. 142

Sarah Millar
Tips and Tricks for the Lab: Column Choices
ChemViews Magazine 2012.

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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