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European Journal of Inorganic Chemistry

A Comparative Study of Structurally Related Homogeneous Ruthenium and Iron Catalysts for the Hydrogenation of Levulinic Acid to γ‐Valerolactone

Published: 15 December 2017

Author(s): Christian A. M. R. van Slagmaat, Stefaan M. A. De Wildeman

Abstract Invited for the cover of this issue is the group of Stefaan DeàWildeman from Maastricht University, Geleen, The Netherlands. The cover image shows a chemical chessboard having white pieces filled with “green” biobased chemicals and black ones soiled with unsustainable petrochemicals.

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Origin of Concentration Quenching in Ytterbium Coordination Polymers: Phonon‐Assisted Energy Transfer

Published: 15 December 2017

Author(s): Shun Omagari, Takayuki Nakanishi, Yuichi Hirai, Yuichi Kitagawa, Tomohiro Seki, Koji Fushimi, Hajime Ito, Yasuchika Hasegawa

Abstract Invited for the cover of this issue are Takayuki Nakanishi from Hokkaido University, Sapporo, Japan, and co‐workers. The cover image shows the YbIII coordination polymer used for the investigation of the concentration quenching mechanism.

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Front Cover: Origin of Concentration Quenching in Ytterbium Coordination Polymers: Phonon‐Assisted Energy Transfer (Eur. J. Inorg. Chem. /2018)

Published: 15 December 2017

Author(s): Shun Omagari, Takayuki Nakanishi, Yuichi Hirai, Yuichi Kitagawa, Tomohiro Seki, Koji Fushimi, Hajime Ito, Yasuchika Hasegawa

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Direct Evidence of a Photoinduced Electron Transfer in Diluted “Molybdenum‐Copper” Molecular Compounds

Published: 15 December 2017

Author(s): Nathalie Bridonneau, Pierre Quatremare, Hans Jurgen von Bardeleben, Jean‐Louis Cantin, Sébastien Pillet, El‐Eulmi Bendeif, Valérie Marvaud

For the first time, direct evidence of a photoinduced intramolecular electron transfer has been found in the “molybdenum‐copper“ family of cyanide complexes that corresponds to a [MoIV–CuII]→[MoV–CuI] transition. The design and synthesis of a diluted molecular system, [Mo(Zn(1–x)Cux)2‐tren] (x = 0, ε, 1, 5 and 10 %, , with ε corresponding to ppm ratio), viewed as new model compounds, have allowed good characterization of the metastable states involved ...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Crystal Structure and Magnetic Properties of an Oxamato‐Bridged Heterobimetallic Tetranuclear [Ni II Cu II ] 2 Complex of the Rack Type

Published: 15 December 2017

Author(s): Natalia V. Reis, Wdeson P. Barros, Willian X. C. Oliveira, Cynthia L. M. Pereira, Willian R. Rocha, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Humberto O. Stumpf

This work discusses a new heterobimetallic nickel(II)–copper(II) complex of the formula [Ni(tpa)Cu(opba)]2·6H2O (1) {H4opba = N,N′‐1,2‐phenylenebis(oxamic acid) and tpa = tris(2‐pyridylmethyl)amine}. The molecular structure of 1 consists of neutral tetranuclear species with a 4R rack‐type architecture featuring two NiIICuII dinuclear units connected through two out‐of‐plane oxo(carboxylate‐oxamate) atoms from the opba ligands. The crystal packing of 1 exhibits a...

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Chemistry - A European Journal

Directing a Non‐Heme Iron(III)‐Hydroperoxide Species on a Trifurcated Reactivity Pathway

Published: 15 December 2017

Author(s): Christina Wegeberg, Frants R. Lauritsen, Cathrine Frandsen, Steen Mørup, Wesley R. Browne, Christine J. McKenzie

Abstract The reactivity of [FeIII(tpena)]2+ (tpena=N,N,N′‐tris(2‐pyridylmethyl)ethylenediamine‐N′‐acetate) as a catalyst for oxidation reactions depends on its ratio to the terminal oxidant H2O2 and presence or absence of sacrificial substrates. The outcome can be switched between: 1) catalysed H2O2 disproportionation, 2) selective catalytic oxidation of methanol or benzyl alcohol to the corresponding aldehyde, or 3) oxidative decomposition of the tpena...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Programming Recognition Arrays through Double Chalcogen‐Bonding Interactions

Published: 15 December 2017

Author(s): Nicolas Biot, Davide Bonifazi

Abstract In this work, we have programmed and synthesized a recognition motif constructed around a chalcogenazolo‐pyridine scaffold (CGP) that, through the formation of frontal double chalcogen‐bonding interactions, associates into dimeric EX‐type complexes. The reliability of the double chalcogen‐bonding interaction has been shown at the solid‐state by X‐ray analysis, depicting the strongest recognition persistence for a...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Humidity‐Responsive ON/OFF Switching of Gas Inclusion by Using Cooperative Opening/Closing of Heterogeneous Crystalline Cavities in a Peptide Ni II Macrocycle

Published: 15 December 2017

Author(s): Ryosuke Miyake, Chika Kuwata, Manami Ueno, Teppei Yamada

Abstract Humidity‐responsive ON/OFF switching of CO2 inclusion, associated with cooperative structural changes of heterogeneous cavities in crystalline peptide NiII macrocycles, 1⋅NO3, is demonstrated. The structural transformation between an “open form” and a “closed form” was caused by reversible water uptake into one of the cavities. The adsorption behavior of CO2 was studied with and without water vapor, combined with gas‐composition analysis by using...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Organocatalyzed Decarboxylative Trichloromethylation of Morita–Baylis–Hillman Adducts in Batch and Continuous Flow

Published: 15 December 2017

Author(s): Martin V. Enevoldsen, Jacob Overgaard, Maja S. Pedersen, Anders T. Lindhardt

Abstract Two protocols for the organocatalyzed decarboxylative trichloromethylation of Morita–Baylis–Hillman (MBH) substrates have been developed. Applying sodium trichloroacetate, as the trichloromethyl anion precursor, in combination with an organocatalyst and acetylated MBH‐alcohols, the desired trichloromethylated products were obtained in good yields at room temperature in batch. The method was next extrapolated into a two‐step...

thumbnail image: Chemistry - A European Journal


Preliminary Evaluation of Artemisinin–Cholesterol Conjugates as Potential Drugs for the Treatment of Intractable Forms of Malaria and Tuberculosis

Published: 15 December 2017

Author(s): Mokhitli Morake, Dina Coertzen, Andile Ngwane, Johannes F. Wentzel, Ho Ning Wong, Frans J. Smit, Lyn‐Marie Birkholtz, Ray‐Dean Pietersen, Bienyameen Baker, Ian Wiid, David D. N'Da, Richard K. Haynes

Abstract To evaluate the feasibility of developing drugs that may be active against both malaria and tuberculosis (TB) by using in part putative cholesterol transporters in the causative pathogens and through enhancement of passive diffusion in granulomatous TB, artemisinin–cholesterol conjugates were synthesized by connecting the component molecules through various linkers. The compounds were screened in vitro against Plasmodium...

thumbnail image: ChemMedChem

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

November 2017


Pingyu Zhang, Cookson K. C. Chiu, Huaiyi Huang, Yuko P. Y. Lam, Abraha Habtemariam, Thomas Malcomson, Martin J. Paterson, Guy J. Clarkson, Peter B. O'Connor, Hui Chao, Peter J. Sadler
Organoiridium Photosensitizers Induce Specific Oxidative Attack on Proteins within Cancer Cells [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 14898

Mariam Iftikhar, Tivoli J. Olsen, Kaitlin M. Pugliese, William A. Brown, Joshua N. Smith, Sameeran Kunche, Stephan T. Kudlacek, Callum F. G. Ormonde, Tom Z. Yuan, Colin L. Raston, Gregory A. Weiss
Shear‐Stress‐Mediated Refolding of Proteins from Aggregates and Inclusion Bodies [Communication]
ChemBioChem 2015, vol. 16, p. 393

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Andreas Schaate, Pascal Roy, Adelheid Godt, Jann Lippke, Florian Waltz, Michael Wiebcke, Peter Behrens
Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals [Full Paper]
Chem. Eur. J. 2011, vol. 17, p. 6643

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Ulrich Lücking, Arne Scholz, Philip Lienau, Gerhard Siemeister, Dirk Kosemund, Rolf Bohlmann, Hans Briem, Ildiko Terebesi, Kirstin Meyer, Katja Prelle, Karsten Denner, Ulf Bömer, Martina Schäfer, Knut Eis, Ray Valencia, Stuart Ince, Franz von Nussbaum, Dominik Mumberg, Karl Ziegelbauer, Bert Klebl, Axel Choidas, Peter Nussbaumer, Matthias Baumann, Carsten Schultz-Fademrecht, Gerd Rühter, Jan Eickhoff, Michael Brands
Identification of Atuveciclib (BAY 1143572), the First Highly Selective, Clinical PTEFb/CDK9 Inhibitor for the Treatment of Cancer [Full Paper]
ChemMedChem 2017, vol. 12, p. 1776

Paul J. A. Kenis, Angela Dibenedetto, Tierui Zhang
Carbon Dioxide Utilization Coming of Age [Editorial]
ChemPhysChem 2017, vol. 18, p. 3091

Rebecca Clarke, Kin Lok Ho, Abdulrahman Abdullah Alsimaree, Owen J. Woodford, Paul G. Waddell, Jonathan Bogaerts, Wouter Herrebout, Julian G. Knight, Robert Pal, Thomas J. Penfold, Michael J. Hall
Circularly Polarised Luminescence from Helically Chiral “Confused” N,N,O,C-Boron-Chelated Dipyrromethenes (BODIPYs) [Article]
ChemPhotoChem 2017, vol. 1, p. 513

Holger Dau, Etsuko Fujita, Licheng Sun
Artificial Photosynthesis: Beyond Mimicking Nature [Editorial]
ChemSusChem 2017, vol. 10, p. 4228

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Salia Tangara, Alice Kanazawa, Sandrine Py
The Baldwin Rearrangement: Synthesis of 2-Acylaziridines [Microreview]
Eur. J. Org. Chem. 2017, p. 6357

Deutscher Lebensmittelchemikertag 2015 in Karlsruhe [Poster]
Lebensmittelchemie 2016, vol. 70, p. 71

Norbert Heeb
Der lange Weg zu sauberem Diesel [Leitartikel]
Nachr. Chem. 2017, vol. 65, p. 1079

Katrin Sommer, Christina Toschka, Laura Schröder, Thomas Philipp Schröder, Henning Steff, Roland A. Fischer
Modellexperimente im Chemieunterricht. [Artikel]
CHEMKON 2017, vol. 24, p. 13

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

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Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
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ChemistryOpen 2013, vol. 2, pp. 115–124

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ChemElectroChem 2014, vol. 1, pp. 83–86

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Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

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Eur. J. Inorg. Chem. 2013, pp. 653–661

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