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Chemistry - A European Journal

Usefulness of the σ‐Aromaticity and σ‐Antiaromaticity Concepts for Clusters and Solid‐State Compounds

Published: 17 October 2017

Author(s): Ivan A. Popov, Alyona A. Starikova, Dmitry V. Steglenko, Alexander I. Boldyrev

Abstract In this Review we present examples of clusters, molecules, and solid‐state compounds, for which the use of σ‐aromaticity and σ‐antiaromaticity concepts is essential for understanding of chemical bonding. We show that the bonding patterns in these σ‐aromatic and σ‐antiaromatic compounds are similar to those of the corresponding π‐aromatic and π‐antiaromatic chemical systems, respectively. Undoubtedly, σ‐aromaticity helps us...

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Chemistry - A European Journal

Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides

Published: 17 October 2017

Author(s): Eric A. Marro, Eric M. Press, Tapas K. Purkait, Daniel Jimenez, Maxime A. Siegler, Rebekka S. Klausen

Abstract This crystallographic and computational study describes an unusual potassium silanide structure. A contact ion pair is expected in the solid state between potassium and silicon, yet the potassium cation binds an aromatic ring and the anionic silanide interacts with CH bonds on neighboring crown ether molecules. These structure‐bonding phenomena are attributed to strong soft–soft interactions.

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ultrathin Anionic Tungstophosphite Molecular Wire with Tunable Hydrophilicity and Catalytic Activity for Selective Epoxidation in Organic Media

Published: 17 October 2017

Author(s): Zhenxin Zhang, Masahiro Sadakane, Michikazu Hara, Wataru Ueda

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ultrathin Anionic Tungstophosphite Molecular Wire with Tunable Hydrophilicity and Catalytic Activity for Selective Epoxidation in Organic Media

Published: 17 October 2017

Author(s): Zhenxin Zhang, Masahiro Sadakane, Michikazu Hara, Wataru Ueda

Abstract The extended 1D tungstophosphite molecular wire is obtained by connection of polyoxometalates. Self‐assembly of a triangular PIIIO3 unit with tungstate produces a hexagonal [HPIIIW6O21]2− building block, which then connects linearly to form the molecular wire. The surface property of the molecular wire is tuned to hydrophobic using organoammonium cations, and the surface‐modified material disperses easily in organic media. The...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Supramolecular Synthon Approach in Developing Anti‐Inflammatory Topical Gels for In Vivo Self‐Delivery

Published: 17 October 2017

Author(s): Rajdip Roy, Parthasarathi Dastidar

Abstract A new series of tertiary‐butyl ammonium (TBA) salts of various nonsteroidal anti‐inflammatory drugs (NSAIDs) have been synthesized and characterized. Nearly 90 % of the NSAID‐derived primary ammonium monocarboxylate (PAM) salts displayed remarkable gelation ability with various solvents including methyl salicylate. Single crystal X‐ray diffraction data (SXRD) revealed the existence of 1D PAM synthon in the gelator salts. ...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Size‐Dependent Reactivity of Nano‐Sized Neutral Manganese Oxide Clusters toward Ethylene

Published: 17 October 2017

Author(s): Jiao‐Jiao Chen, Ting Zhang, Mei‐Qi Zhang, Qing‐Yu Liu, Xiao‐Na Li, Sheng‐Gui He

Abstract Neutral manganese oxide clusters with the general composition Mn2 NO3 N+x (N=2–22; x=−1, 0, 1) with dimensions up to a nanosize were prepared by laser ablation and reacted with C2H4 in a fast flow reactor. The size‐dependent reactivity of C2H4 adsorption on these clusters was experimentally identified and the adsorption reactivity decreases generally with an increase of the cluster size. Density functional theory calculations were performed to...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Single Oxidative Collision Events of Silver Nanoparticles: Understanding the Rate‐Determining Chemistry

Published: 17 October 2017

Author(s): Kamonwad Ngamchuea, Richard O. D. Clark, Stanislav V. Sokolov, Neil P. Young, Christopher Batchelor‐McAuley, Richard G. Compton

Abstract The oxidative dissolution of citrate‐capped silver nanoparticles (AgNPs, ∼50 nm diameter) is investigated herein by two electrochemical techniques: nano‐impacts and anodic stripping voltammetry. Nano‐impacts or single nanoparticle‐electrode collisions allow the detection of individual nanoparticles. The technique offers an advantage over surface‐immobilized methods such as anodic stripping voltammetry as it eliminates the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ultrathin Cobalt‐Based Metal–Organic Framework Nanosheets with Both Metal and Ligand Redox Activities for Superior Lithium Storage

Published: 17 October 2017

Author(s): Yanqun Ning, Xiaobing Lou, Chao Li, Xiaoshi Hu, Bingwen Hu

Abstract The controllable synthesis and structural tailoring of nanostructured metal–organic frameworks (MOFs) is of huge significance in boosting their potential for rechargeable batteries. We herein present the facile synthesis of cobalt‐based ultrathin metal–organic framework nanosheets (referred to as “u‐CoTDA”) by using 2,5‐thiophenedicarboxylic (H2TDA) as the organic building block through a one‐pot ultrasonic method for the first time....

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Anion‐Directed Metallocages: A Study on the Tendency of Anion Templation

Published: 17 October 2017

Author(s): Jing‐Yun Wu, Ming‐Shiou Zhong, Ming‐Hsi Chiang

Abstract Self‐assembly of Cu(NO3)2⋅3 H2O and di(3‐pyridylmethyl)amine (dpma) with addition of different acids (HNO3, HOAc, HCl, HClO4, HOTf, HPF6, HBF4, and H2SO4) afforded a family of anion‐templated tetragonal metallocages with a cationic prismatic structure of [(Gn−)⊂{Cu2(Hdpma)4}](8−n)+ (Gn−=NO3−, PF6−, SiF62−) with different ligating anions/solvents (NO3−, Cl−, ClO4−, OTf−, H2O) outside the cage. Systematic competitive experiments have rationalized the tendency...

thumbnail image: Chemistry - A European Journal


Catalyst Stability Benchmarking for the Oxygen Evolution Reaction: The Importance of Backing Electrode Material and Dissolution in Accelerated Aging Studies

Published: 17 October 2017

Author(s): Simon Geiger, Olga Kasian, Andrea M. Mingers, Shannon S. Nicley, Ken Haenen, Karl J. J. Mayrhofer, Serhiy Cherevko

Abstract In searching for alternative oxygen evolution reaction (OER) catalysts for acidic water splitting, fast screening of the material intrinsic activity and stability in half‐cell tests is of vital importance. The screening process significantly accelerates the discovery of new promising materials without the need of time‐consuming real‐cell analysis. In commonly employed tests, a conclusion on the catalyst stability is drawn...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

September 2017


Beau P. Pritchett, Etienne J. Donckele, Brian M. Stoltz
Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 12624

Joseph Cowell, Matthew Buck, Ali H. Essa, Rebecca Clarke, Waldemar Vollmer, Daniela Vollmer, Catharien M. Hilkens, John D. Isaacs, Michael J. Hall, Joe Gray
Traceless Cleavage of Protein-Biotin Conjugates under Biologically Compatible Conditions [Communication]
ChemBioChem 2017, vol. 18, p. 1688

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Andrzej Kapturkiewicz
Electrochemical Generation of Excited Intramolecular Charge-Transfer States [Review]
ChemElectroChem 2017, vol. 4, p. 1604

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Reto M. Witzig, Dominik Lotter, Vincent C. Fäseke, Christof Sparr
Stereoselective Arene-Forming Aldol Condensation: Catalyst-Controlled Synthesis of Axially Chiral Compounds [Concept]
Chem. Eur. J. 2017, vol. 23, p. 12960

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Jieun Choi, Nagendra Nath Yadav, Hyun-Joon Ha
Front Cover: Preparation of a Stable Bicyclic Aziridinium Ion and Its Ring Expansion toward Piperidines and Azepanes (Asian J. Org. Chem. 9/2017) [Cover Picture]
Asian J. Org. Chem. 2017, vol. 6, p. 1110

Munia F. Sowaileh, Robert A. Hazlitt, David A. Colby
Application of the Pentafluorosulfanyl Group as a Bioisosteric Replacement [Minireview]
ChemMedChem 2017, vol. 12, p. 1481

Thomas J. Penfold, Andrew P. Monkman, Jamie Gibson
The Importance of Vibronic Coupling for Efficient Reverse Intersystem Crossing in Thermally Activated Delayed Fluorescence Molecules [Communication]
ChemPhysChem 2016, vol. 17, p. 2956

Tugba Ozdemir, Yu-Chen Lu, Safacan Kolemen, Esra Tanriverdi-Ecik, Engin U. Akkaya
Generation of Singlet Oxygen by Persistent Luminescent Nanoparticle-Photosensitizer Conjugates: A Proof of Principle for Photodynamic Therapy without Light [Communication]
ChemPhotoChem 2017, vol. 1, p. 183

Junfei Luo, Igor Larrosa
C−H Carboxylation of Aromatic Compounds through CO2 Fixation [Minireview]
ChemSusChem 2017, vol. 10, p. 3317

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Parteien zur Wahl [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 911

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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