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Chemistry - A European Journal

The Trifluoromethyl Sulfinyl and Oxathiyl Radicals

Published: 07 December 2017

Author(s): Zhuang Wu, Jian Xu, Guohai Deng, Xianxu Chu, Liubov Sokolenko, Tarek Trabelsi, Joseph S. Francisco, André K. Eckhardt, Peter R. Schreiner, Xiaoqing Zeng

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ChemPlusChem

Synthesis of Nontoxic Protoflavone Derivatives through Selective Continuous‐Flow Hydrogenation of the Flavonoid B‐Ring

Published: 07 December 2017

Author(s): Sándor B. Ötvös, Máté Vágvölgyi, Gábor Girst, Ching‐Ying Kuo, Hui‐Chun Wang, Ferenc Fülöp, Attila Hunyadi

Abstract Protoflavones are unique natural flavonoids with a non‐aromatic B‐ring, known for their potent antitumor properties. However, their cytotoxicity represents a strong limitation in the further exploration of their pharmacological potential. In the current study, we sought to selectively saturate the p‐quinol B‐ring of protoapigenone and that of its 1′‐O‐butyl ether, in order to obtain non‐toxic protoflavone analogues expressing the...

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ChemCatChem

Sandwich‐Like Silica@Ni@Silica Multicore–Shell Catalyst for the Low‐Temperature Dry Reforming of Methane: Confinement Effect Against Carbon Formation

Published: 07 December 2017

Author(s): Zhoufeng Bian, Sibudjing Kawi

Abstract We synthesize a new sandwich‐like silica@Ni@silica multicore–shell catalyst. Firstly, Ni phyllosilicate (NiPS) is supported on silica nanospheres by a simple ammonia evaporation method. Then NiPS is coated with a layer of mesoporous silica to obtain a core–shell NiPS@silica structure by the hydrolysis of tetraethylorthosilicate (TEOS). The thickness of the shell can be tuned by varying the amount of TEOS. After calcination...

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ChemistryOpen

N‐Type Doped Silicon Thin Film on a Porous Cu Current Collector as the Negative Electrode for Li‐Ion Batteries

Published: 07 December 2017

Author(s): Aliya Mukanova, Arailym Nurpeissova, Sung‐Soo Kim, Maksym Myronov, Zhumabay Bakenov

Abstract This work reports the preparation of a three‐dimensional Si thin film negative electrode employing a porous Cu current collector. A previously reported copper etching procedure was modified to develop the porous structures inside a 9 μm thick copper foil. Magnetron sputtering was used for the deposition of an n‐type doped 400 nm thick amorphous Si thin film. Electrochemical cycling of the prepared anode confirmed the...

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ChemistryOpen

A Small Molecule Impedes Insulin Fibrillation: Another New Role of Phenothiazine Derivatives

Published: 07 December 2017

Author(s): Meghomukta Mukherjee, Jagannath Jana, Subhrangsu Chatterjee

Abstract Protein misfolding is interrelated to several diseases, including neurodegenerative diseases and type II diabetes. Misfolded/unfolded proteins produce soluble oligomers that accumulate into “amyloid plaques”. Inhibition of amyloid‐plaque formation by those misfolded/unfolded proteins will lead to the invention of new therapeutic approaches for amyloid‐related diseases. Herein, methylene blue (MB), a well‐defined drug...

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European Journal of Inorganic Chemistry

Florence–Orsay: A Joint Laboratory with Olivier

Published: 07 December 2017

Author(s): Dante Gatteschi, Michel Verdaguer

The present essay gathers a few anecdotes and slices of the authors' scientific lives, trying to show how Olivier Kahn occupied a pivotal position in molecular magnetism and why it is possible today to speak of his scientific legacy.

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ChemCatChem

Molybdenum Sulfide Nanosheet‐Based Hollow Porous Flat Boxes and Nanotubes for Efficient Electrochemical Hydrogen Evolution

Published: 07 December 2017

Author(s): Liao Chen, Hongli Zhu

Abstract Intriguing amorphous/quasiamorphous molybdenum sulfide (MoSx) materials with active terminal disulfide S22− units have been recognized recently as prominent catalysts for the hydrogen evolution reaction (HER). Here, we diversify the MoSx morphologies and structures by a facile template‐free solvothermal method to prepare fascinating MoSx nanosheet‐based hollow porous flat boxes and nanotubes. As we increase the ethanol concentration in the mixed...

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ChemCatChem

First‐Principles Computational Screening of Dopants to Improve the Deacon Process over RuO 2

Published: 07 December 2017

Author(s): Zhen Yao, Karsten Reuter

Abstract Doping of metal oxides is a promising route to further optimize their catalytic performance. To guide corresponding experimental endeavors, we performed a DFT‐based computational screening study for a wide range of metal dopant atoms in rutile RuO2. With a focus on the Deacon process, that is, the catalytic oxidation of HCl to chlorine and water, we used the rate‐controlling Cl desorption energy as a reactivity descriptor. As stability...

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Chemistry - A European Journal

Reversible Polymerization of Adamantane‐type [P 4 N 10 ] 10− Anions to Honeycomb‐type [P 2 N 5 ] 5− Layers under High‐Pressure

Published: 07 December 2017

Author(s): Eva‐Maria Bertschler, Robin Niklaus, Wolfgang Schnick

Abstract The high‐pressure polymorph Li5P2N5 of Li10P4N10 (=“2 Li5P2N5”) was synthesized by high‐pressure/high‐temperature reaction of LiPN2 and Li7PN4 or β‐Li10P4N10 at 9 GPa, using the Li3N self‐flux method in a Walker‐type multianvil assembly. Li5P2N5 is the first lithium nitridophosphate with a layered structure and is made up of corner sharing PN4 tetrahedra forming a corrugated honeycomb‐type layer of linked sechser‐rings in chair conformation. The arrangement...

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Chemistry - A European Journal

Quantitative Analysis of Self‐Assembly Process of a Pd 2 L 4 Cage Consisting of Rigid Ditopic Ligands

Published: 07 December 2017

Author(s): Shumpei Kai, Vicente Martí‐Centelles, Yui Sakuma, Takako Mashiko, Tatsuo Kojima, Umpei Nagashima, Masanori Tachikawa, Paul J. Lusby, Shuichi Hiraoka

Abstract The self‐assembly process of a Pd2L4 cage complex consisting of rigid ditopic ligands, in which two 3‐pyridyl groups are connected to a benzene ring through acetylene bonds and PdII ions was revealed by a recently developed quantitative analysis of self‐assembly process (QASAP), with which the self‐assembly process of coordination assemblies can be investigated by monitoring the evolution with time of the average composition of ...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

October 2017

 


Bryan D. Ellis, Christopher D. Vanderwal
Hughes and Gleason's Virosaine A-Appreciating the Art in Synthesis [Highlight]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 13940

Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz
How We Make DNA Origami [Concept]
ChemBioChem 2017, vol. 18, p. 1873

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, p. 1523

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Flavia Izzo, Martina Schäfer, Robert Stockman, Ulrich Lücking
A New, Practical One-Pot Synthesis of Unprotected Sulfonimidamides by Transfer of Electrophilic NH to Sulfinamides [Full Paper]
Chem. Eur. J. 2017, vol. 23, p. 15189

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Paramita Mukherjee, Martin Pettersson, Jason K. Dutra, Longfei Xie, Christopher W. am Ende
Trifluoromethyl Oxetanes: Synthesis and Evaluation as a tert-Butyl Isostere [Communication]
ChemMedChem 2017, vol. 12, p. 1574

David D. Evanoff, George Chumanov
Synthesis and Optical Properties of Silver Nanoparticles and Arrays [Minireview]
ChemPhysChem 2005, vol. 6, p. 1221

Jonathan E. Barnsley, Bethany A. Lomax, James R. W. McLay, Christopher B. Larsen, Nigel T. Lucas, Keith C. Gordon
Flicking the Switch on Donor-Acceptor Interactions in Hexaazatrinaphthalene Dyes: A Spectroscopic and Computational Study [Article]
ChemPhotoChem 2017, vol. 1, p. 432

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Francesca Leonelli, Marinella Capuzzi, Vincenzo Calcagno, Pietro Passacantilli, Giovanni Piancatelli
Stereoselective Michael‐Type Addition of Organocopper Reagents to Enones Derived from Glycals in the Synthesis of 2‐Phosphono‐α‐C‐Glycosides [Short Communication]
Eur. J. Org. Chem. 2005, p. 2671

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Titandioxid: schön oder schädlich [Industrie & Technik]
Nachr. Chem. 2017, vol. 65, p. 1008

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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