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Chemistry - A European Journal

Potential Therapeutic Applications of MnSODs and SOD‐Mimetics

Published: 12 December 2017

Author(s): Rosalin Bonetta

Abstract Natural as well as synthetic antioxidants are constantly being investigated for their efficiency in combatting the effects of oxidative stress, which appears to be the responsible cause of several diseases, including cancer, central nervous system disorders, ischaemia‐reperfusion disorders, cardiovascular conditions, and diabetes. Superoxide dismutases (SODs) constitute the ubiquitous antioxidant defences against oxidative...

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Laccase‐Mediated Grafting on Biopolymers and Synthetic Polymers: A Critical Review

Published: 12 December 2017

Author(s): Sjoerd Slagman, Han Zuilhof, Maurice C. R. Franssen

Abstract Laccase‐mediated grafting on lignocelluloses has gained considerable attention as an environmentally benign method to covalently modify wood, paper and cork. In recent decades this technique has also been employed to modify fibres with a polysaccharide backbone, such as cellulose or chitosan, to infer colouration, antimicrobial activity or antioxidant activity to the material. The scope of this approach has been further...

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Chemistry - A European Journal

Porphyrin‐Based Air‐Stable Helical Radicals

Published: 12 December 2017

Author(s): Kenichi Kato, Ko Furukawa, Tadashi Mori, Atsuhiro Osuka

Abstract Stable helical radicals are promising multi‐functional molecules in light of intriguing magnetic and chiroptical properties. Attempts were made to extend diphenylmethyl‐fused NiII porphyrin radical to helical system as the first air‐stable organic neutral helical radicals. Intramolecular Pd‐catalyzed twofold C−H arylation of methyl‐ or methoxy‐introduced meso‐diphenylmethyl NiII porphyrins gave a mixture of the target and rearranged...

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Chemistry - A European Journal

In Situ Generated Ruthenium–Arene Catalyst for Photoactivated Ring‐Opening Metathesis Polymerization through Photolatent N‐Heterocyclic Carbene Ligand

Published: 12 December 2017

Author(s): Julien Pinaud, Thi Kim Hoang Trinh, David Sauvanier, Emeline Placet, Sriprapai Songsee, Patrick Lacroix‐Desmazes, Jean‐Michel Becht, Bassam Tarablsi, Jacques Lalevée, Loïc Pichavant, Valérie Héroguez, Abraham Chemtob

Abstract 1,3‐Bis(mesityl)imidazolium tetraphenylborate (IMesH+ BPh4−) can be synthesized in one step by anion metathesis between the corresponding imidazolium chloride and sodium tetraphenylborate. In the presence of 2‐isopropylthioxanthone (sensitizer), an IMes N‐heterocyclic carbene (NHC) ligand can be photogenerated under irradiation at 365 nm through coupled electron/proton transfer reactions. By combining this tandem NHC photogenerator ...

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Chemistry - A European Journal

Valence Localization at a Bio‐inspired Mixed‐Valent {Cu 2 S} 2+ Motif upon Solvation in Acetonitrile: Effect on Nitrous Oxide Reductase (N 2 Or) Activity

Published: 12 December 2017

Author(s): Charlène Esmieu, Maylis Orio, Jordan Mangue, Jacques Pécaut, Stéphane Ménage, Stéphane Torelli

Abstract We demonstrate, based on experimental and theoretical evidence, that the isolated [2(CH3CN)2]2+ complex prepared in CH3CN and containing a mixed‐valent {Cu2II,IS} core evolves towards a new [2(CH3CN)3]2+ species upon solvation in CH3CN. Unlike its type III structural analogue [2(H2O)(OTf)]+ active toward N2O reduction, this new type I compound is inactive. This outcome opens new perspectives for a rational for N2O activation using bio‐inspired Cu/S complexes,...

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Flavin‐N5 Covalent Intermediate in a Nonredox Dehalogenation Reaction Catalyzed by an Atypical Flavoenzyme

Published: 12 December 2017

Author(s): Yumin Dai, Karina Kizjakina, Ashley C. Campbell, David A. Korasick, John J. Tanner, Pablo Sobrado

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Flavin‐N5 Covalent Intermediate in a Nonredox Dehalogenation Reaction Catalyzed by an Atypical Flavoenzyme

Published: 12 December 2017

Author(s): Yumin Dai, Karina Kizjakina, Ashley C. Campbell, David A. Korasick, John J. Tanner, Pablo Sobrado

Abstract The flavin‐dependent enzyme 2‐haloacrylate hydratase (2‐HAH) catalyzes the conversion of 2‐chloroacrylate, a major component in the manufacture of acrylic polymers, to pyruvate. The enzyme was expressed in Escherichia coli, purified, and characterized. 2‐HAH was shown to be monomeric in solution and contained a non‐covalent, yet tightly bound, flavin adenine dinucleotide (FAD). Although the catalyzed reaction was redox‐neutral, 2‐HAH...

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Catalytic Upgrading of Ethanol to n ‐Butanol: Progress in Catalyst Development

Published: 12 December 2017

Author(s): Xianyuan Wu, Geqian Fang, Yuqin Tong, Dahao Jiang, Zhe Liang, Wenhua Leng, Liu Liu, Pengxiang Tu, Hongjing Wang, Jun Ni, Xiaonian Li

Abstract Because n‐butanol as a fuel additive has more advantageous physicochemical properties than those of ethanol, ethanol valorization to n‐butanol through homo‐ or heterogeneous catalysis has received much attention in recent decades in both scientific and industrial fields. Recent progress in catalyst development for upgrading ethanol to n‐butanol, which involves homogeneous catalysts, such as iridium and ruthenium complexes, and...

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Molybdenum Doping Augments Platinum–Copper Oxygen Reduction Electrocatalyst

Published: 12 December 2017

Author(s): Yun Luo, Björn Kirchhoff, Donato Fantauzzi, Laura Calvillo, Luis Alberto Estudillo‐Wong, Gaetano Granozzi, Timo Jacob, Nicolas Alonso‐Vante

Abstract Improving the efficiency of Pt‐based oxygen reduction reaction (ORR) catalysts while also reducing costs remains an important challenge in energy research. To this end, we synthesized highly stable and active carbon‐supported Mo‐doped PtCu (Mo‐PtCu/C) nanoparticles (NPs) from readily available precursors in a facile one‐pot reaction. Mo‐PtCu/C displays two‐to‐fourfold‐higher ORR half‐cell kinetics than reference PtCu/C and...

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Inhibitors against Fungal Cell Wall Remodeling Enzymes

Published: 12 December 2017

Author(s): Ignacio Delso, Jessika Valero‐Gonzalez, Fernando Gomollón‐Bel, Jorge Castro‐López, Wenxia Fang, Iva Navratilova, Daan M. F. van Aalten, Tomás Tejero, Pedro Merino, Ramon Hurtado‐Guerrero

Abstract Fungal β‐1,3‐glucan glucanosyltransferases are glucan‐remodeling enzymes that play important roles in cell wall integrity, and are essential for the viability of pathogenic fungi and yeasts. As such, they are considered possible drug targets, although inhibitors of this class of enzymes have not yet been reported. Herein we report a multidisciplinary approach based on a structure‐guided design using a highly conserved...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

November 2017


Pingyu Zhang, Cookson K. C. Chiu, Huaiyi Huang, Yuko P. Y. Lam, Abraha Habtemariam, Thomas Malcomson, Martin J. Paterson, Guy J. Clarkson, Peter B. O'Connor, Hui Chao, Peter J. Sadler
Organoiridium Photosensitizers Induce Specific Oxidative Attack on Proteins within Cancer Cells [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 14898

Mariam Iftikhar, Tivoli J. Olsen, Kaitlin M. Pugliese, William A. Brown, Joshua N. Smith, Sameeran Kunche, Stephan T. Kudlacek, Callum F. G. Ormonde, Tom Z. Yuan, Colin L. Raston, Gregory A. Weiss
Shear‐Stress‐Mediated Refolding of Proteins from Aggregates and Inclusion Bodies [Communication]
ChemBioChem 2015, vol. 16, p. 393

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Andreas Schaate, Pascal Roy, Adelheid Godt, Jann Lippke, Florian Waltz, Michael Wiebcke, Peter Behrens
Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals [Full Paper]
Chem. Eur. J. 2011, vol. 17, p. 6643

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Andrea Gualandi, Luca Mengozzi, Pier Giorgio Cozzi
Iron-Promoted Radical Reactions: Current Status and Perspectives [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 1160

Ulrich Lücking, Arne Scholz, Philip Lienau, Gerhard Siemeister, Dirk Kosemund, Rolf Bohlmann, Hans Briem, Ildiko Terebesi, Kirstin Meyer, Katja Prelle, Karsten Denner, Ulf Bömer, Martina Schäfer, Knut Eis, Ray Valencia, Stuart Ince, Franz von Nussbaum, Dominik Mumberg, Karl Ziegelbauer, Bert Klebl, Axel Choidas, Peter Nussbaumer, Matthias Baumann, Carsten Schultz-Fademrecht, Gerd Rühter, Jan Eickhoff, Michael Brands
Identification of Atuveciclib (BAY 1143572), the First Highly Selective, Clinical PTEFb/CDK9 Inhibitor for the Treatment of Cancer [Full Paper]
ChemMedChem 2017, vol. 12, p. 1776

Paul J. A. Kenis, Angela Dibenedetto, Tierui Zhang
Carbon Dioxide Utilization Coming of Age [Editorial]
ChemPhysChem 2017, vol. 18, p. 3091

Rebecca Clarke, Kin Lok Ho, Abdulrahman Abdullah Alsimaree, Owen J. Woodford, Paul G. Waddell, Jonathan Bogaerts, Wouter Herrebout, Julian G. Knight, Robert Pal, Thomas J. Penfold, Michael J. Hall
Circularly Polarised Luminescence from Helically Chiral “Confused” N,N,O,C-Boron-Chelated Dipyrromethenes (BODIPYs) [Article]
ChemPhotoChem 2017, vol. 1, p. 513

Holger Dau, Etsuko Fujita, Licheng Sun
Artificial Photosynthesis: Beyond Mimicking Nature [Editorial]
ChemSusChem 2017, vol. 10, p. 4228

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Salia Tangara, Alice Kanazawa, Sandrine Py
The Baldwin Rearrangement: Synthesis of 2-Acylaziridines [Microreview]
Eur. J. Org. Chem. 2017, p. 6357

Deutscher Lebensmittelchemikertag 2015 in Karlsruhe [Poster]
Lebensmittelchemie 2016, vol. 70, p. 71

Norbert Heeb
Der lange Weg zu sauberem Diesel [Leitartikel]
Nachr. Chem. 2017, vol. 65, p. 1079

Katrin Sommer, Christina Toschka, Laura Schröder, Thomas Philipp Schröder, Henning Steff, Roland A. Fischer
Modellexperimente im Chemieunterricht. [Artikel]
CHEMKON 2017, vol. 24, p. 13

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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