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A Lucifer‐Based Environment‐Sensitive Fluorescent PNA Probe for Imaging Poly(A) RNAs

Published: 13 March 2018

Author(s): Pramod M. Sabale, Uddhav B. Ambi, Seergazhi G. Srivatsan

Abstract Fluorescence‐based oligonucleotide (ON) hybridization probes greatly aid the detection and profiling of RNA sequences in cells. However, certain limitations such as target accessibility and hybridization efficiency in cellular environments hamper their broad application because RNAs can form complex and stable structures. In this context, we have developed a robust hybridization probe suitable for imaging RNA in cells by...

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POM & MOF‐based Electrocatalysts for Energy‐related Reactions

Published: 13 March 2018

Author(s): Cristina Freire, Diana M. Fernandes, Marta Nunes, Victor K. Abdelkader

Abstract Electrocatalysis plays a central role in clean energy conversion, enabling a number of sustainable processes for future technologies and the development of highly efficient and cost‐effective materials is one of the current major challenges. This results from the current global energy crisis, reflected in the depletion of fossil fuels and growth of the environmental pollution, which has stimulated the development of novel...

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Impact of Hydrophobic Organohybrid Silicas on the Stability of Ni 2 P Catalyst Phase in the Hydrodeoxygenation of Biophenols

Published: 13 March 2018

Author(s): Michael Dierks, Zhengwen Cao, Jinesh C. Manayil, Jeganathan Akilavasan, Karen Wilson, Ferdi Schüth, Roberto Rinaldi

Abstract Hydrodeoxygenation (HDO) of lignocellulose‐derived pyrolysis oils offers an option to produce fuel substitutes. However, catalyst deactivation and stability constitute a significant issue. Herein, the dependence of stability and activity of Ni2P/SiO2 HDO catalysts on the support surface polarity is addressed in detail. The support surface polarity was adjusted by copolymerizing tetraethyl orthosilicate (TEOS) with different types and...

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Bottom‐Up Design of Nitrogen‐Containing Carbon Catalysts for the Oxygen Reduction Reaction

Published: 13 March 2018

Author(s): Riku Shibuya, Takahiro Kondo, Junji Nakamura

Abstract Pyridinic nitrogen species on nitrogen‐doped carbon catalysts were recently found to create active sites for the oxygen reduction reaction (ORR). Bottom‐up assembly of pyridinic‐nitrogen‐containing aromatic molecules on graphitic carbon electrodes is a promising synthesis method to design ORR carbon catalysts with a high density of active sites. Herein, we report the preparation of a model catalyst by dropping a solution of...

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Iron‐Doped Nickel Phosphide Nanosheets In Situ Grown on Nickel Submicrowires as Efficient Electrocatalysts for Oxygen Evolution Reaction

Published: 13 March 2018

Author(s): Jiahui Chen, Yunming Li, Guoqing Sheng, Lu Xu, Huangqing Ye, Xian‐Zhu Fu, Rong Sun, Ching‐Ping Wong

Abstract Tens of micrometers long metallic Ni submicrowires with a diameter of approximately 200 nm are prepared by a chemical reduction method under a magnetic field. Fe‐doped Ni2P nanosheets are then in situ grown on Ni submicrowires by a simple wet‐chemical reaction followed by a low‐temperature phosphorization process. The (Ni0.87Fe0.13)2P–Ni composite exhibits the highest catalytic activity toward oxygen evolution reaction in alkaline...

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Opposite Enantioselectivity by Nanotubes and Nanospheres Self‐Assembled from Dirhodium(II) and an l ‐Glutamic Acid Terminated Bolaamphiphile

Published: 13 March 2018

Author(s): Chenhuan Yuan, Jian Jiang, Hui Sun, Decai Wang, Yonghong Hu, Minghua Liu

Abstract Coordination is an important factor that can be used to modulate the structure and function of self‐assembly systems. Herein, we report the coordination‐regulated self‐assembly of chiral nanostructures and their enantioselective catalytic performances. We found that if a rhodium complex and an l‐glutamic acid terminated bolaamphiphile were self‐assembled by coordination, single‐walled nanotubes and nanospheres could be...

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Microwave Reaction: A Facile Economic and Green Method to Synthesize Oxygen‐Decorated Graphene from Carbon Cloth for Oxygen Electrocatalysis

Published: 13 March 2018

Author(s): Weifeng Zhang, Yaguang Li, Yingqi Xu, Zisheng Zhang, Shufang Wang, Guangsheng Fu

Abstract Oxygen‐functionalized graphene is active for oxygen evolution reaction (OER). However, the high costs, complex instruments and pollution risks in the synthesis process make oxygen‐functionalized graphene difficult to be industrialized. The microwave reaction has originally been used to remove the oxygen groups on graphene structures. In this work, the microwave reaction is reversed to decorate oxygen groups on graphene from...

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Electronic Rearrangement in Molecular Plasmons: An Electron Density and Electrostatic Potential‐Based Study

Published: 13 March 2018

Author(s): Mishu Paul, P. Balanarayan

Abstract Plasmonic modes in single‐molecule systems have been previously identified by scaling two‐electron interactions in calculating excitation energies. Analysis of transition dipole moments for states of polyacenes based on configuration interaction is another method for characterising molecular plasmons. The principal features in the electronic absorption spectra of polyacenes are a low‐intensity, lower‐in‐energy peak and a...

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Chemistry - A European Journal

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl‐Containing Molecules

Published: 13 March 2018

Author(s): Kamil Hofman, Nai‐Wei Liu, Georg Manolikakes

Abstract Molecules containing a sulfonyl functionality, such as sulfones, sulfonyl chlorides or sulfonamides play an important role in organic chemistry and have found widespread application, especially in the construction of biologically active compounds. Recently, methods for the synthesis of the sulfonyl moiety utilizing sulfur dioxide as a key building block have received considerable attention. In this context, radical‐based...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

A Neutral Ru II Hydride Complex for the Regio‐ and Chemoselective Reduction of N ‐Silylpyridinium Ions

Published: 13 March 2018

Author(s): Susanne Bähr, Martin Oestreich

Abstract A detailed experimental analysis of the 1,4‐selective reduction of pyridine with hydrosilanes catalyzed by a coordinatively unsaturated RuII thiolate complex is reported. The previously suggested intermediates, N‐silylpyridinium ions and a neutral RuII hydride, have been independently synthesized and do indeed participate in the catalytic cycle. The resting state is not the cationic RuII complex initially used as the catalyst but its...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2018


Nan Zhao, Shuqiang Yin, Shengling Xie, Hao Yan, Pan Ren, Gui Chen, Fang Chen, Jing Xu
Total Synthesis of Astellatol [Communication]
Angew. Chem. Int. Ed. 10.1002/anie.201800167

Aitao Li, Carlos G. Acevedo-Rocha, Zhoutong Sun, Tony Cox, Jia Lucy Xu, Manfred T. Reetz
Beating Bias in the Directed Evolution of Proteins: Combining High-Fidelity on-Chip Solid-Phase Gene Synthesis with Efficient Gene Assembly for Combinatorial Library Construction [Full Paper]
ChemBioChem 2018, vol. 19, p. 221

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Lukas Raddatz, Jonas Austerjost, Sascha Beutel
3D-Druck: Chancen, Möglichkeiten, Risiken [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 42

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Ping Zhang, Nopphon Weeranoppanant, Dale A. Thomas, Kohei Tahara, Torsten Stelzer, Mary Grace Russell, Marcus O'Mahony, Allan S. Myerson, Hongkun Lin, Liam P. Kelly, Klavs F. Jensen, Timothy F. Jamison, Chunhui Dai, Yuqing Cui, Naomi Briggs, Rachel L. Beingessner, Andrea Adamo
Advanced Continuous Flow Platform for On-Demand Pharmaceutical Manufacturing [Full Paper]
Chem. Eur. J. 2018, vol. 24, p. 2776

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Zhi-Xiang Yu, Biao Yu, Xiao-Bing Lu, Jian Pei
Organic Chemistry for the Future [Editorial]
Asian J. Org. Chem. 10.1002/ajoc.201800077

Chris de Graaf, Albert J. Kooistra, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Ross McGuire, Márton Vass
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 10.1002/cmdc.201700754

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Ferdi Karadas, Ekmel Ozbay, Amir Ghobadi, Turkan Gamze Ulusoy Ghobadi
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 10.1002/cptc.201700165

Jiwhan Kim, Hee-Eun Kim, Hyunjoo Lee
Single-Atom Catalysts of Precious Metals for Electrochemical Reactions [Minireview]
ChemSusChem 2018, vol. 11, p. 104

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai
Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper]
Eur. J. Org. Chem. 2016, p. 331

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 19

Die neue Macht des Forschers [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 103

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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