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Chemistry - A European Journal

Ultrathin Anionic Tungstophosphite Molecular Wire with Tunable Hydrophilicity and Catalytic Activity for Selective Epoxidation in Organic Media

Published: 19 October 2017

Author(s): Zhenxin Zhang, Masahiro Sadakane, Michikazu Hara, Wataru Ueda

Abstract Invited for the cover of this issue are the groups of Zhenxin Zhang and Wataru Ueda at Kanagawa University, Tokyo Institute of Technology, and Hiroshima University. The image depicts the development of a tungstophosphite molecular wire through the growth of a tree, in which the roots represent the triangular PIIIO3 units with tungstate that assemble into the trunk of building blocks and the final wire grows on the branches. Read...

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Chemistry - A European Journal

Mild Decarboxylative C−H Alkylation: Computational Insights for Solvent‐Robust Ruthenium(II) Domino Manifold

Published: 18 October 2017

Author(s): N. Y. Phani Kumar, Torben Rogge, Santhivardhana Reddy Yetra, Alexander Bechtoldt, Eric Clot, Lutz Ackermann

Abstract Computational studies on decarboxylative C−H alkenylations provided key insights into the solvent‐robust nature of C−H activation/decarboxylation domino reactions. These properties were exploited for ruthenium(II)‐catalyzed C−H alkylations by a decarboxylative process with ample scope under copper‐free and silver‐free reaction conditions.

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Chemistry - A European Journal

Terminal Alkyne Coupling on a Corrugated Noble Metal Surface: From Controlled Precursor Alignment to Selective Reactions

Published: 18 October 2017

Author(s): Tao Lin, Liding Zhang, Jonas Björk, Zhi Chen, Mario Ruben, Johannes V. Barth, Florian Klappenberger

Abstract Surface‐templated covalent coupling of organic precursors currently emerges as a promising route to the atom‐precise fabrication of low‐dimensional carbon materials. Here, we investigate the adsorption and the coupling reactions of 4,4′′‐diethynyl‐1,1′:4′,1′′‐terphenyl on Au(110) under ultra‐high vacuum conditions by using scanning tunneling microscopy combined with density functional theory and kinetic Monte Carlo calculations....

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ChemCatChem

Manganese Copper Sulfide Nanocomposites: Structure Tailoring and Photo/Electrocatalytic Hydrogen Generation

Published: 18 October 2017

Author(s): Jing Wang, Yee‐Fun Lim, Ghim Wei Ho

Abstract In this paper, we present an l‐cysteine‐mediated hydrothermal synthesis of manganese copper sulfide (MCS) nanocomposites with versatile nanostructures and demonstrate their applications in photocatalytic and electrocatalytic hydrogen generation from water splitting. Variation of the Mn/Cu molar ratios in the precursors facilely tailors the MCS nanocomposites into one‐dimensional nanowires or two‐dimensional nanosheets,...

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ChemPhysChem

pH‐Driven Wetting Switchability of Electrodeposited Superhydrophobic Copolymers of Pyrene Bearing Acid Functions and Fluorinated Chains

Published: 18 October 2017

Author(s): Gabriela Ramos Chagas, Denis Kiryanenko, Guilhem Godeau, Frédéric Guittard, Thierry Darmanin

Abstract A smart stimuli‐responsive surface was fabricated by the electro‐copolymerization of pyrene monomers followed by base and acid treatment. Copolymers of pyrenes bearing fluorinated chains (Py‐nF6) and acid functions (Py‐COOH) were produced with different molar concentrations of each monomer (0, 25, 50, 75, and 100 % of Py‐nF6 vs. Py‐COOH) by an electrochemical process. Two different perfluorinated pyrenes containing ester and amide...

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ChemistryOpen

Towards Fingermark Dating: A Raman Spectroscopy Proof‐of‐Concept Study

Published: 18 October 2017

Author(s): Per Ola Andersson, Christian Lejon, Therese Mikaelsson, Lars Landström

Abstract Fingermarks have, for a long time, been vital in the forensic community for the identification of individuals, and a possibility to non‐destructively date the fingermarks would of course be beneficial. Raman spectroscopy is, herein, evaluated for the purpose of estimating the age of fingermarks deposits. Well‐resolved spectra were non‐destructively acquired to reveal spectral uniqueness, resembling those of epidermis, and...

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Chemistry - A European Journal

Silylene‐Functionalized N‐Heterocyclic Carbene (Si−NHC)

Published: 18 October 2017

Author(s): Dennis Rottschäfer, Sebastian Blomeyer, Beate Neumann, Hans‐Georg Stammler, Rajendra S. Ghadwal

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Di(hydroperoxy)alkane Adducts of Phosphine Oxides: Safe, Solid, Stoichiometric, and Soluble Oxidizing Agents

Published: 18 October 2017

Author(s): Shin Hye Ahn, Nattamai Bhuvanesh, Janet Blümel

Abstract Invited for the cover of this issue is the group of Janet Blümel at Texas A&M University. The image depicts the crystals and crystal structures of novel oxidizing agents: di(hydroperoxy)alkane adducts of phosphine oxides. Read the full text of the article at 10.1002/chem.201703676.

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ChemBioChem

Bioluminescence Resonance Energy Transfer (BRET)‐coupled Annexin V‐functionalized Quantum Dots for Near‐Infrared Optical Detection of Apoptotic Cells

Published: 18 October 2017

Author(s): Setsuko Tsuboi, Takashi Jin

Abstract Deregulation in apoptosis induces numerous diseases such as cancer, cardiovascular, and neurodegenerative diseases. Detection of apoptotic cells is crucial for understanding the mechanism of these diseases and for therapy development. Although optical imaging using visible‐emitting fluorescent probes, such as FITC‐labeled annexin V, is widely used for the detection of apoptotic cells, there are very limited probes that can...

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Chemistry - A European Journal

Structure, Electronics and Reactivity of Ce(PNP) Complexes

Published: 18 October 2017

Author(s): Alexander V. Zabula, Yusen Qiao, Alex J. Kosanovich, Thibault Cheisson, Brian C. Manor, Patrick J. Carroll, Oleg V. Ozerov, Eric J. Schelter

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

September 2017

 


Beau P. Pritchett, Etienne J. Donckele, Brian M. Stoltz
Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 12624

Joseph Cowell, Matthew Buck, Ali H. Essa, Rebecca Clarke, Waldemar Vollmer, Daniela Vollmer, Catharien M. Hilkens, John D. Isaacs, Michael J. Hall, Joe Gray
Traceless Cleavage of Protein-Biotin Conjugates under Biologically Compatible Conditions [Communication]
ChemBioChem 2017, vol. 18, p. 1688

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Andrzej Kapturkiewicz
Electrochemical Generation of Excited Intramolecular Charge-Transfer States [Review]
ChemElectroChem 2017, vol. 4, p. 1604

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Reto M. Witzig, Dominik Lotter, Vincent C. Fäseke, Christof Sparr
Stereoselective Arene-Forming Aldol Condensation: Catalyst-Controlled Synthesis of Axially Chiral Compounds [Concept]
Chem. Eur. J. 2017, vol. 23, p. 12960

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Jieun Choi, Nagendra Nath Yadav, Hyun-Joon Ha
Front Cover: Preparation of a Stable Bicyclic Aziridinium Ion and Its Ring Expansion toward Piperidines and Azepanes (Asian J. Org. Chem. 9/2017) [Cover Picture]
Asian J. Org. Chem. 2017, vol. 6, p. 1110

Munia F. Sowaileh, Robert A. Hazlitt, David A. Colby
Application of the Pentafluorosulfanyl Group as a Bioisosteric Replacement [Minireview]
ChemMedChem 2017, vol. 12, p. 1481

Thomas J. Penfold, Andrew P. Monkman, Jamie Gibson
The Importance of Vibronic Coupling for Efficient Reverse Intersystem Crossing in Thermally Activated Delayed Fluorescence Molecules [Communication]
ChemPhysChem 2016, vol. 17, p. 2956

Tugba Ozdemir, Yu-Chen Lu, Safacan Kolemen, Esra Tanriverdi-Ecik, Engin U. Akkaya
Generation of Singlet Oxygen by Persistent Luminescent Nanoparticle-Photosensitizer Conjugates: A Proof of Principle for Photodynamic Therapy without Light [Communication]
ChemPhotoChem 2017, vol. 1, p. 183

Junfei Luo, Igor Larrosa
C−H Carboxylation of Aromatic Compounds through CO2 Fixation [Minireview]
ChemSusChem 2017, vol. 10, p. 3317

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Parteien zur Wahl [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 911

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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