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Journal of Chemical Technology & Biotechnology

Oxalate degradation by alkaliphilic biofilms acclimatised to nitrogen‐supplemented and nitrogen‐deficient conditions

Published: 20 October 2017

Author(s): Tharanga N Weerasinghe Mohottige, Ka Yu Cheng, Anna H Kaksonen, Ranjan Sarukkalige, Maneesha P Ginige

Abstract BACKGROUND Sodium oxalate is a key organic contaminant in alumina industry, which diminishes process yields and product quality. Given that Bayer process liquor is typically deficient in nitrogen (N), there is external supplementation of N in current full‐scale biological treatment processes. This study, for the first time, examines oxalate degradation under N deficient conditions using two...

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Journal of Chemical Technology & Biotechnology

Novel microbial and root mediated green synthesis of TiO 2 nanoparticles and its application in wastewater remediation

Published: 20 October 2017

Author(s): Jyoti Fulekar, Dimple P Dutta, Bhawana Pathak, Madhusudan H Fulekar

Abstract BACKGROUND Rhizosphere is a natural phenomenon which has been identified as plant assisted bioremediation and comprises of bacteria, fungi and actinomycetes along the root zone. Rhizosphere can be enhanced by providing the nutrients and favourable environmental condition and is considered an ecological remediation unit. In the present study, mycorrhizal sorghum roots and bacterial strains...

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Journal of Food Process Engineering

Structure evolution of pullulan–alginate edible films during drying studied by low‐field NMR

Published: 20 October 2017

Author(s): Qian Xiao, Zhengtao Zhao, Loong‐Tak Lim

Abstract The evolutions of spatial structure for pullulan, alginate, and pullulan–alginate blend aqueous solutions during drying were investigated by low‐field nuclear magnetic resonance. For pullulan solutions, during the first 1,320 min of drying, NMR signal intensity in profiles did not vary with position. Thereafter, the apparent shift of the air–pullulan interface began at 1,440 min, indicating...

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A Single‐Framework Synthetic Antibody Library Containing a Combination of Canonical and Variable Complementarity‐Determining Regions

Published: 20 October 2017

Author(s): Bharathikumar Vellalore Maruthachalam, Ayman El‐Sayed, Jianghai Liu, Ashley R. Sutherland, Wayne Hill, Md Kausar Alam, Landon Pastushok, Humphrey Fonge, Kris Barreto, C. Ronald Geyer

Abstract Synthetic antibody libraries have been used to generate antibodies with favorable biophysical and pharmacological properties. Here, we describe the design, construction, and validation of a phage‐displayed antigen‐binding fragment (Fab) library built on a modified trastuzumab framework with four fixed and two diversified complementarity‐determining regions (CDRs). CDRs L1, L2, H1, and H2 were fixed to preserve the most...

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Identification and Functional Analysis of Chitin Synthase A in Oriental Armyworm, Mythimna separata

Published: 20 October 2017

Author(s): Yifan Zhai, Xiaobin Fan, Zhenjuan Yin, Xiangzhao Yue, Xingyuan Men, Li Zheng, Wenqing Zhang

Abstract Chitin synthases are very important enzymes for chitin synthesis in various species, which makes them a specific target of insecticides. In the present study, the function of the chitin synthase A (CHSA) gene isolated from Mythimna separate is investigated. The majority of dsMysCHSA treated larvae (89.50%) exhibit lethal phenotypes, including three phenotypes with severe cuticle deformations. The dsMysCHSA treatment in adult females affects...

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Discovery of Antimicrobial Peptides in Cervical‐Vaginal Fluid from Healthy Nonpregnant Women via an Integrated Proteome and Peptidome Analysis

Published: 20 October 2017

Author(s): Carla M. J. Muytjens, Yijing Yu, Eleftherios P. Diamandis

Abstract Cervical‐vaginal fluid (CVF) covers the lower part of the female reproductive system and functions in the homeostasis and immunity of the surrounding tissues. In contrast to the CVF proteome of both nonpregnant and pregnant women, the CVF peptidome has not been reported to date. In the current study, we identified 1087 proteins in CVF, of which 801 proteins were not previously identified in CVF proteomes. The presence of...

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Effect of Silyl Ether‐functinoalized Dimethoxydimethylsilane on Electrochemical Performance of a Ni‐rich NCM Cathode

Published: 20 October 2017

Author(s): Seol Heui Jang, Taeeun Yim

Abstract Dimethoxydimethylsilane (DODSi) is used as an interface stabilizing additive through a selective HF scavenging reaction for layered Ni‐rich oxide cathodes. Ex situ NMR analyses demonstrated that DODSi effectively removes HF from the electrolyte based on the matched chemical reactivity of Si with F− and O with H+. The cells employing DODSi exhibit higher specific capacity with retention than those cycled with a DODSi‐free electrolyte ...

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Flow‐Pattern Characterization of Biphasic Electrochemical Cells by Magnetic Resonance Imaging under Forced Hydrodynamic Conditions

Published: 20 October 2017

Author(s): María R. Serial, Manuel I. Velasco, Emilia V. Silletta, Franco M. Zanotto, Sergio A. Dassie, Rodolfo H. Acosta

Abstract The fluid dynamics of a liquid|liquid system inside a four‐electrode electrochemical cell were studied by velocimetry magnetic resonance imaging (MRI) and flow propagator measurements. To characterize this system fully, three different cell configurations operating at two rotational frequencies were analyzed. Quantitative information about the stability of the liquid|liquid interface and the dynamics of the organic phase...

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Potent Pyrimidine and Pyrrolopyrimidine Inhibitors of Testis‐Specific Serine/Threonine Kinase 2 (TSSK2)

Published: 20 October 2017

Author(s): Jon E. Hawkinson, Rondedrick Sinville, Deepti Mudaliar, Jagathpala Shetty, Timothy Ward, John C. Herr, Gunda I. Georg

Abstract Testis‐specific serine/threonine kinase 2 (TSSK2) is an important target for reversible male contraception. A high‐throughput screen of ≈17 000 compounds using a mobility shift assay identified two potent series of inhibitors having a pyrrolopyrimidine or pyrimidine core. The pyrrolopyrimidine 10 (IC50 22 nm; GSK2163632A) and the pyrimidine 17 (IC50 31 nm; ALK inhibitor 1) are the most potent TSSK2 inhibitors in these series, which...

thumbnail image: ChemMedChem


Aminocarbonylation of Aryl Halides to Produce Primary Amides by Using NH 4 HCO 3 Dually as Ammonia Surrogate and Base

Published: 20 October 2017

Author(s): Dong‐Liang Wang, Huan Liu, Da Yang, Peng Wang, Yong Lu, Ye Liu

Abstract An efficient and clean protocol was developed for rapid production of primary aromatic amides by aminocarbonylation with NH4HCO3. Without addition of auxiliary base, the use of solid and cheap NH4HCO3 dually as ammonia surrogate and base not only promoted aminocarbonylation over subsequent dehydration and hydrolysis of amides owing to its weak basicity, and it also made the reaction manipulation clean and simplified without the presence of stinky ...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

September 2017


Beau P. Pritchett, Etienne J. Donckele, Brian M. Stoltz
Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, p. 12624

Joseph Cowell, Matthew Buck, Ali H. Essa, Rebecca Clarke, Waldemar Vollmer, Daniela Vollmer, Catharien M. Hilkens, John D. Isaacs, Michael J. Hall, Joe Gray
Traceless Cleavage of Protein-Biotin Conjugates under Biologically Compatible Conditions [Communication]
ChemBioChem 2017, vol. 18, p. 1688

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Sigma Hashimoto, Takahiro Iwamoto, Daisuke Kurachi, Eiichi Kayahara, Shigeru Yamago
Shortest Double-Walled Carbon Nanotubes Composed of Cycloparaphenylenes [Communication]
ChemPlusChem 2017, vol. 82, p. 1015

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Andrzej Kapturkiewicz
Electrochemical Generation of Excited Intramolecular Charge-Transfer States [Review]
ChemElectroChem 2017, vol. 4, p. 1604

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Reto M. Witzig, Dominik Lotter, Vincent C. Fäseke, Christof Sparr
Stereoselective Arene-Forming Aldol Condensation: Catalyst-Controlled Synthesis of Axially Chiral Compounds [Concept]
Chem. Eur. J. 2017, vol. 23, p. 12960

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Jieun Choi, Nagendra Nath Yadav, Hyun-Joon Ha
Front Cover: Preparation of a Stable Bicyclic Aziridinium Ion and Its Ring Expansion toward Piperidines and Azepanes (Asian J. Org. Chem. 9/2017) [Cover Picture]
Asian J. Org. Chem. 2017, vol. 6, p. 1110

Munia F. Sowaileh, Robert A. Hazlitt, David A. Colby
Application of the Pentafluorosulfanyl Group as a Bioisosteric Replacement [Minireview]
ChemMedChem 2017, vol. 12, p. 1481

Thomas J. Penfold, Andrew P. Monkman, Jamie Gibson
The Importance of Vibronic Coupling for Efficient Reverse Intersystem Crossing in Thermally Activated Delayed Fluorescence Molecules [Communication]
ChemPhysChem 2016, vol. 17, p. 2956

Tugba Ozdemir, Yu-Chen Lu, Safacan Kolemen, Esra Tanriverdi-Ecik, Engin U. Akkaya
Generation of Singlet Oxygen by Persistent Luminescent Nanoparticle-Photosensitizer Conjugates: A Proof of Principle for Photodynamic Therapy without Light [Communication]
ChemPhotoChem 2017, vol. 1, p. 183

Junfei Luo, Igor Larrosa
C−H Carboxylation of Aromatic Compounds through CO2 Fixation [Minireview]
ChemSusChem 2017, vol. 10, p. 3317

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Gregory J. P. Perry, Igor Larrosa
Recent Progress in Decarboxylative Oxidative Cross-Coupling for Biaryl Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 3517

Biochemische und molekularbiologische Analytik [Bericht]
Lebensmittelchemie 2017, vol. 71, p. 13

Maren Bulmahn
Parteien zur Wahl [Bildung & Gesellschaft]
Nachr. Chem. 2017, vol. 65, p. 911

Dominique Rosenberg, Svenja Pansegrau, Mirco Wachholz, Alexander Rehling, Maike Busker, Walter Jansen
Redox-Flow-Batterien - Organische Batterien mit Zukunftsperspektiven [Artikel]
CHEMKON 2017, vol. 24, p. 325

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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