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Journal of Polymer Science Part A: Polymer Chemistry

Polyimides as cathodic materials in lithium batteries: Effect of the chemical structure of the diamine monomer

Published: 19 January 2018

Author(s): Guiomar Hernández, Maitane Salsamendi, Sofia M. Morozova, Elena I. Lozinskaya, Shanmukaraj Devaraj, Yakov S. Vygodskii, Alexander S. Shaplov, David Mecerreyes

ABSTRACT Polyimides are being investigated as alternative, environmentally friendly and safe organic electrode materials for lithium and sodium batteries. However, further improvements need the proper chemical design of these polymers. In this paper, the effect of chemical structure of polyimides on their performance as cathodic materials in lithium batteries was investigated in detail. More in particular, we studied polyimides...

Journal of Polymer Science Part A: Polymer Chemistry

One‐pot synthesis of block copolymers by ring‐opening polymerization and ultraviolet light‐induced ATRP at ambient temperature

Published: 19 January 2018

Author(s): Lin Lei, Feifei Li, Haixiu Zhao, Yuntao Wang

ABSTRACT We successfully synthesized poly(l‐lactide)‐b‐poly (methyl methacrylate) diblock copolymers at ambient temperature by combining ultraviolet light‐induced copper‐catalyzed ATRP and organo‐catalyzed ring‐opening polymerization (ROP) in one‐pot. The polymerization processes were carried out by three routes: one‐pot simultaneous ATRP and ROP, one‐pot sequential ATRP followed by ROP, and one‐pot sequential ROP followed by ATRP....

Journal of Polymer Science Part A: Polymer Chemistry

Radical polyaddition of difunctional vinyloxirane with thiols for synthesis of linear and networked polysulfides

Published: 19 January 2018

Author(s): Shinya Maeda, Atsushi Sudo, Takeshi Endo

ABSTRACT Radical ring‐opening polyaddition of bifunctional vinyloxirane with multifunctional thiols was investigated. The polyaddition proceeded smoothly via the ring‐opening reaction of the oxirane moiety to afford the corresponding networked polymers bearing vinyl ether and sulfide moieties in the main chain. The thermal properties of the networked polymers and volume changes upon the polyaddition were investigated. © 2018 Wiley...

Angewandte Chemie

Cobalt(II)‐based Metalloradical Activation of 2‐(Diazomethyl)pyridines for Radical Transannulation and Cyclopropanation

Published: 19 January 2018

Author(s): Satyajit Roy, Sandip Kumar Das, Buddhadeb Chattopadhyay

Abstract A new catalytic method for the denitrogenative transannulation/cyclopropanation of in‐situ‐generated 2‐(diazomethyl)pyridines is described using a cobalt‐catalyzed radical‐activation mechanism. The method takes advantage of the inherent properties of a CoIII‐carbene radical intermediate and is the first report of denitrogenative transannulation/cyclopropanation by a radical‐activation mechanism, which is supported by...

thumbnail image: Angewandte Chemie

Angewandte Chemie International Edition

An Efficient Method for the Conjugation of Hydrophilic and Hydrophobic Components by Solid‐Phase‐Assisted Disulfide Ligation

Published: 19 January 2018

Author(s): Kyohei Muguruma, Takuya Shirasaka, Daichi Akiyama, Kentarou Fukumoto, Akihiro Taguchi, Kentaro Takayama, Atsuhiko Taniguchi, Yoshio Hayashi

Abstract Chemical conjugation between hydrophilic and hydrophobic components is difficult because of their extremely different solubility. Herein, we report a new versatile method with a solid‐phase‐assisted disulfide ligation to overcome the difficulty of conjugation attributed to solubility. The method involves two steps in a one‐pot process: 1) loading of a hydrophobic molecule onto a resin in an organic solvent, and 2) release...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie

Palladium/Copper Dual Catalysis for the Cross‐Coupling of Aryl(trialkyl)silanes with Aryl Bromides

Published: 19 January 2018

Author(s): Takeshi Komiyama, Yasunori Minami, Yuki Furuya, Tamejiro Hiyama

Abstract Whereas aryl(trialkyl)silanes are considered to be ideal organometallic reagents for cross‐coupling reactions owing to their stability, low toxicity, solubility, and easy accessibility, they are generally inert under typical cross‐coupling conditions. Disclosed herein is a palladium/copper catalytic system that enables the cross‐coupling of trimethyl, triethyl, tert‐butyldimethyl, and triisopropyl aryl silanes with aryl...

thumbnail image: Angewandte Chemie

Angewandte Chemie International Edition

Surface‐Confined Dynamic Covalent System Driven by Olefin Metathesis

Published: 19 January 2018

Author(s): Chunhua Liu, Eunsol Park, Yinghua Jin, Jie Liu, Yanxia Yu, Wei Zhang, Shengbin Lei, Wenping Hu

Abstract Understanding how the constitutional dynamics of a dynamic combinatorial library (DCL) adapts to surfaces (compared to bulk solution) is of fundamental importance to the design of adaptive materials. Submolecular resolved scanning tunneling microscopy (STM) can provide detailed insights into olefin metathesis at the interface. Analysis of the distribution of products has revealed the important role of environmental...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie

Surface‐Confined Dynamic Covalent System Driven by Olefin Metathesis

Published: 19 January 2018

Author(s): Chunhua Liu, Eunsol Park, Yinghua Jin, Jie Liu, Yanxia Yu, Wei Zhang, Shengbin Lei, Wenping Hu

Abstract Understanding how the constitutional dynamics of a dynamic combinatorial library (DCL) adapts to surfaces (compared to bulk solution) is of fundamental importance to the design of adaptive materials. Submolecular resolved scanning tunneling microscopy (STM) can provide detailed insights into olefin metathesis at the interface. Analysis of the distribution of products has revealed the important role of environmental...

thumbnail image: Angewandte Chemie

Angewandte Chemie International Edition

Cobalt(II)‐based Metalloradical Activation of 2‐(Diazomethyl)pyridines for Radical Transannulation and Cyclopropanation

Published: 19 January 2018

Author(s): Satyajit Roy, Sandip Kumar Das, Buddhadeb Chattopadhyay

Abstract A new catalytic method for the denitrogenative transannulation/cyclopropanation of in‐situ‐generated 2‐(diazomethyl)pyridines is described using a cobalt‐catalyzed radical‐activation mechanism. The method takes advantage of the inherent properties of a CoIII‐carbene radical intermediate and is the first report of denitrogenative transannulation/cyclopropanation by a radical‐activation mechanism, which is supported by...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Palladium/Copper Dual Catalysis for the Cross‐Coupling of Aryl(trialkyl)silanes with Aryl Bromides

Published: 19 January 2018

Author(s): Takeshi Komiyama, Yasunori Minami, Yuki Furuya, Tamejiro Hiyama

Abstract Whereas aryl(trialkyl)silanes are considered to be ideal organometallic reagents for cross‐coupling reactions owing to their stability, low toxicity, solubility, and easy accessibility, they are generally inert under typical cross‐coupling conditions. Disclosed herein is a palladium/copper catalytic system that enables the cross‐coupling of trimethyl, triethyl, tert‐butyldimethyl, and triisopropyl aryl silanes with aryl...

thumbnail image: Angewandte Chemie International Edition

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

December 2017

 


John C. K. Chu, Tomislav Rovis
Complementary Strategies for Directed C(sp3)−H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 62

Mariam Iftikhar, Tivoli J. Olsen, Kaitlin M. Pugliese, William A. Brown, Joshua N. Smith, Sameeran Kunche, Stephan T. Kudlacek, Callum F. G. Ormonde, Tom Z. Yuan, Colin L. Raston, Gregory A. Weiss
Shear‐Stress‐Mediated Refolding of Proteins from Aggregates and Inclusion Bodies [Communication]
ChemBioChem 2015, vol. 16, p. 393

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Ducci
Geheimtinten [Artikel]
Chem. Unserer Zeit 2017, vol. 51, p. 228

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, p. 17

Arezoo Azimi, Ahmad Azari, Mashallah Rezakazemi, Meisam Ansarpour
Removal of Heavy Metals from Industrial Wastewaters: A Review [Review]
ChemBioEng Rev. 2017, vol. 4, p. 37

Ernst J. R. Sudhölter, Jorge Gascon, Hanan Al-Kutubi, Liza Rassaei
Electrosynthesis of Metal–Organic Frameworks: Challenges and Opportunities [Review]
ChemElectroChem 2015, vol. 2, p. 462

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Soumyakanta Prusty, Kohei Yazaki, Michito Yoshizawa, Dillip Kumar Chand
A Truncated Molecular Star [Communication]
Chem. Eur. J. 2017, vol. 23, p. 12456

Ryoji Noyori
Converging and Integrating Our Knowledge to Sustain Humanity [Editorial]
Chem. Asian J. 2018, vol. 13, p. 5

Rui Yan, Zhong-Xia Wang
Rhodium-Catalyzed Alkenyl C−H Activation and Oxidative Coupling with Allylic Alcohols [Full Paper]
Asian J. Org. Chem. 2018, vol. 7, p. 240

Ulrich Lücking, Arne Scholz, Philip Lienau, Gerhard Siemeister, Dirk Kosemund, Rolf Bohlmann, Hans Briem, Ildiko Terebesi, Kirstin Meyer, Katja Prelle, Karsten Denner, Ulf Bömer, Martina Schäfer, Knut Eis, Ray Valencia, Stuart Ince, Franz von Nussbaum, Dominik Mumberg, Karl Ziegelbauer, Bert Klebl, Axel Choidas, Peter Nussbaumer, Matthias Baumann, Carsten Schultz-Fademrecht, Gerd Rühter, Jan Eickhoff, Michael Brands
Identification of Atuveciclib (BAY 1143572), the First Highly Selective, Clinical PTEFb/CDK9 Inhibitor for the Treatment of Cancer [Full Paper]
ChemMedChem 2017, vol. 12, p. 1776

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Wonwoo Nam, Yong-Min Lee, Shunichi Fukuzumi
Artificial Photosynthesis for Production of ATP, NAD(P)H, and Hydrogen Peroxide [Minireview]
ChemPhotoChem 10.1002/cptc.201700146

Courtney A. Downes, Smaranda C. Marinescu
Electrocatalytic Metal-Organic Frameworks for Energy Applications [Minireview]
ChemSusChem 2017, vol. 10, p. 4374

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Peng Liu, Zhiming Wang, Xianming Hu
Highly Efficient Synthesis of Ureas and Carbamates from Amides by Iodosylbenzene‐Induced Hofmann Rearrangement [Full Paper]
Eur. J. Org. Chem. 2012, p. 1994

Cover Picture Lebensmittelchemie 6/2017 [Cover Picture]
Lebensmittelchemie 2017, vol. 71

Christoph Wiedmer, Andrea Büttner
Der Gestank aus Plastikspielzeug [Wissenschaft & Forschung]
Nachr. Chem. 2017, vol. 65, p. 1190

Katrin Sommer, Christina Toschka, Laura Schröder, Thomas Philipp Schröder, Henning Steff, Roland A. Fischer
Modellexperimente im Chemieunterricht. [Artikel]
CHEMKON 2017, vol. 24, p. 13

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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