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Chemistry - A European Journal

Reversible Nanogate System for Mesoporous Silica Nanoparticles Based on Diels–Alder Adducts

Published: 24 April 2018

Author(s): Rafael R. Castillo, David Hernández‐Escobar, Sergio Gómez‐Graña, María Vallet‐Regí

Abstract The implementation of nanoparticles as nanomedicines requires sophisticated surface modifications to reduce the immune response and enhance recognition abilities. Mesoporous silica nanoparticles present extraordinary host–guest abilities and facile surface functionalization. These two factors make them ideal candidates for the development of novel drug‐delivery systems, at the expense of increasing structural complexity....

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Energy Technology

Piezoelectric Energy Harvesting Systems—Essentials to Successful Developments

Published: 24 April 2018

Author(s): Kenji Uchino

Abstract In recent years, industrial and academic research units have focused on harvesting energy from mechanical vibrations using piezoelectric transducers. These efforts have provided research guidelines and have brought to light the problems and limitations of piezoelectric systems. There are three major phases associated with piezoelectric energy harvesting: (i) mechanical–mechanical energy transfer, including mechanical...

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ChemCatChem

Electrospun BiOCl/Bi 2 Ti 2 O 7 Nanorod Heterostructures with Enhanced Solar Light Efficiency in the Photocatalytic Degradation of Tetracycline Hydrochloride

Published: 24 April 2018

Author(s): Yuxian Xu, Daifeng Lin, Xinping Liu, Yongjin Luo, Hun Xue, Baoquan Huang, Qinghua Chen, Qingrong Qian

Abstract Bismuth titanates (BTs) can be fabricated by electrospinning combined with calcination at different temperatures. BiOCl/Bi2Ti2O7 nanorod heterostructures were obtained at 500 °C. They possess excellent photocatalytic efficiency and stability for tetracycline hydrochloride (TC‐HCl) degradation under simulated solar light. The excellent catalytic activity is predominantly attributed to the heterostructure between BiOCl and Bi2Ti2O7,...

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ChemCatChem

Green Organocatalytic Oxidative Methods using Activated Ketones

Published: 24 April 2018

Author(s): Ierasia Triandafillidi, Dimitrios Ioannis Tzaras, Christoforos G. Kokotos

Abstract Alkenes are very important moieties in organic chemistry and have been employed as starting materials for the synthesis of important organic compounds. In this review, we present organocatalytic reactions in which alkenes play a central role, especially their organocatalytic oxidation to epoxides. This topic plays a pivotal role in our recent research, for which we utilize H2O2 as a green oxidant and a ketone as the...

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ChemCatChem

Graphene‐Based Carbocatalysts for Thermoset Polymers and for Diastereoselective and Enantioselective Organic Synthesis

Published: 24 April 2018

Author(s): Maria Rosaria Acocella, Gaetano Guerra

Abstract This review reports on the catalytic activity of graphene oxide (GO) and high‐surface‐area graphite (HSAG) for some relevant organic reactions. It is shown that the main drawbacks of graphite‐based catalysts, that is, high catalyst loading and generally poor selectivity, can often be removed by operating under solvent‐free conditions. Moreover, some reactions that are catalyzed by GO as well as HSAG are presented. For these...

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Chemistry - A European Journal

Feasibility of Activation Energy Prediction of Gas‐Phase Reactions by Machine Learning

Published: 24 April 2018

Author(s): Sunghwan Choi, Yeonjoon Kim, Jin Woo Kim, Zeehyo Kim, Woo Youn Kim

Abstract Machine learning based on big data has emerged as a powerful solution in various chemical problems. We investigated the feasibility of machine learning models for the prediction of activation energies of gas‐phase reactions. Six different models with three different types, including the artificial neural network, the support vector regression, and the tree boosting methods, were tested. We used the structural and...

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Biotechnology Journal

Relevance of Local Flexibility Near the Active Site for Enzymatic Catalysis: Biochemical Characterization and Engineering of Cellulase Cel5A From Bacillus agaradherans

Published: 24 April 2018

Author(s): Juan M. Saavedra, Mauricio A. Azócar, Vida Rodríguez, César A. Ramírez‐Sarmiento, Barbara A. Andrews, Juan A. Asenjo, Loreto P. Parra

Detailed molecular mechanisms underpinning enzymatic reactions are still a central problem in biochemistry. The need for active site flexibility to sustain catalytic activity constitutes a notion of wide acceptance, although its direct influence remains to be fully understood. With the aim of studying the relationship between structural dynamics and enzyme catalysis, the cellulase Cel5A from Bacillus agaradherans is...

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European Journal of Lipid Science and Technology

Effects of Calcium Content and Homogenization Method on the Microstructure, Rheology, and Stability of Emulsions Prepared with Soybean Flour Dispersions

Published: 24 April 2018

Author(s): Andrés L. Márquez, Jorge R. Wagner, Gonzalo G. Palazolo

The objective is to study the microstructure, rheology, and quiescent stability of oil‐in‐water emulsions prepared with defatted soybean flour dispersions, analyzing the effects of calcium concentration and homogenization method. Dispersions are prepared without or with addition of calcium chloride at different concentrations (30, 60, and 90 mg Ca 100 g−1) and treated by heating (100 °C, 40 min) and high‐pressure homogenization...

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European Journal of Lipid Science and Technology

Facile Enzymatic Synthesis of Phosphatidylthreonine Using an Engineered Phospholipase D

Published: 24 April 2018

Author(s): Jasmina Damnjanović, Nozomi Matsunaga, Masaatsu Adachi, Hideo Nakano, Yugo Iwasaki

Here is described the newly established method for direct enzymatic synthesis of phosphatidylthreonine (PtdThr). It is the first report on enzymatic synthesis of this rare phospholipid. It utilizes phospholipase D (PLD)‐catalyzed transphosphatidylation, in which the head group of phosphatidylcholine (PtdCho) is exchanged to L‐Threonine (L‐Thr). An attempt to catalyze the reaction between PtdCho and L‐Thr using...

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European Journal of Lipid Science and Technology

Inclusion of Flaxseed, Broken Rice, and Distillers Dried Grains with Solubles (DDGS) in Broiler Chicken Ration Alters the Fatty Acid Profile, Oxidative Stability, and Other Functional Properties of Meat

Published: 24 April 2018

Author(s): Nasir Akbar Mir, Praveen K. Tyagi, Ashim K. Biswas, Pramod K. Tyagi, A. B. Mandal, Faneshwar Kumar, Divya Sharma, Avishek Biswas, Arun K. Verma

The objective of the study is to evaluate the fatty acid profile, oxidative stability, and other associated quality attributes of broiler chicken meat as affected by feeding ration containing flaxseed, broken rice, and distillers dried grains with solubles (DDGS). Six dietary treatments are formulated with no flaxseed in the first one and 10% in the other five; and 20% broken rice, 40% broken rice, 5% DDGS, and 10%...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018

 


Zhang Luo, Bing Liu
Shape‐Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture]
Angew. Chem. Int. Ed. 10.1002/anie.201802726

Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens
MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication]
ChemBioChem 2018, vol. 19, p. 434

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber
Analytik mit Licht - Das Smartphone-Photometer [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 52

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2′‐bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication]
Chem. Eur. J. 2018, vol. 24, p. 4552

Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo
Aromatic Aminocatalysis [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 740

Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki
Abstract [Focus Review]
Asian J. Org. Chem. 10.1002/ajoc.201800013

Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 2018, vol. 13, p. 614

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 2018, vol. 2, p. 161

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson
The Use of Halide‐Substituted Anilines for the Formation of Magnesium Imides [Full Paper]
Eur. J. Inorg. Chem. 2008, p. 3935

D. B. Ramachary [Author Profile]
Eur. J. Org. Chem. 10.1002/ejoc.201800182

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Peter Chen
Chemistry 4.0 [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 203

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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