Self-Healing Zinc-Ion Battery

  • Author: Angewandte Chemie International Edition
  • Published Date: 20 March 2019
  • Source / Publisher: Angewandte Chemie International Edition/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: Self-Healing Zinc-Ion Battery

Rechargeable zinc-ion batteries (ZIBs) can be damaged and even break when they are subjected to large deformations. As a result, their performance is significantly reduced.

To overcome this issue, Zhiqiang Niu and colleagues, Nankai University, Tianjin, China, have developed a self-healing hydrogel electrolyte. The electrolyte is composed of poly(vinyl alcohol) and zinc trifluoromethanesulfonate (PVA/Zn(CF3SO3)2) and prepared via a freeze-thaw strategy: An aqueous solution of PVA and Zn(CF3SO3)2 is frozen at –18 °C for 15 h and subsequently thawed at room temperature.

During the freezing/thawing process, the crystallization of PVA is enhanced. The resulting crystalline microdomains can serve as cross‐links to give a porous network structure. Poly(vinyl alcohol) (PVA)‐based hydrogels prepared under appropriate conditions can self‐heal due to to a large number of hydroxy side groups, which form hydrogen bonds and repair the gel. Self-healing ZIBs were assembled by integrating the anode, cathode, and a separator into the hydrogel electrolyte matrix.

The ZIBs can heal autonomously (pictured) without the need for any external stimulus. They recover their electrochemical performance completely even after several cutting/healing cycles. In this way, the durability of ZIBs could be significantly improved, their lifetime extended, and electronic waste and costs reduced.


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