Flame-Retardant Battery Electrolyte

  • Author: Angewandte Chemie International Edition
  • Published Date: 14 June 2019
  • Source / Publisher: Angewandte Chemie International Edition/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: Flame-Retardant Battery Electrolyte

High-energy-density lithium-metal batteries are susceptible to dendrite formation, which can cause short circuits and thus, heat. In the presence of a flammable battery electrolyte, fires or explosions can occur. Electrolytes that use flame-retardant solvents, such as organic phosphate electrolytes (OPEs), could eliminate fire hazards and ensure safer working batteries.

Yu-Guo Guo, Beijing National Laboratory for Molecular Sciences, Chinese Academy of Sciences (CAS), and colleagues have developed a Li-metal battery containing a lithium nitrate additive, which is compatible with the flame-retarding electrolyte triethyl phosphate. The researchers investigated the lithium-plating process at the solid electrolyte interface (SEI) using scanning electron microscopy and optical microscopy.

In the presence of the additive, lithium was deposited uniformly at the Li-metal anode and dendrite formation was avoided—even at a high 16 mA cm–2 current density. The homogeneous Li/electrolyte interface has a low resistance and allows a working battery to function with a higher Coulombic efficiency and a longer cycling life compared with an additive-free cell.


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