Catalytic Formaldehyde Removal From Indoor Air

  • Author: Lois O'Leary
  • Published Date: 08 January 2014
  • Source / Publisher: ChemCatChem/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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Toxic formaldehyde gas, which can be found in trace amounts (<1 ppm) in indoor air, can cause serious health problems. In an advance in formaldehyde conversion chemistry, Jean-François Lamonier and co-workers, Lille University of Science and Technology, France, have created mesoporous silica-confined MnO2 nanoparticles as a highly active catalyst, with complete selectivity towards carbon dioxide.

The heterogeneous catalyst is an excellent noble-metal-free alternative to titania-supported platinum, the hitherto most active material for formaldehyde oxidation. Furthermore, the Mn-based process requires limited energy consumption, with operating temperatures as low as 130 °C. Confined-space crystallization of MnO2 on a SBA-15 silica support produces the active material as a hexagonal array of size-adjustable mesopores, possibly with a second microporous network. Mn valence state is integral to the catalytic activity: materials with high Mn4+ content show high activity, whereas a decrease in the mean Mn oxidation state is followed by a decrease in catalytic activity.

Mn-containing nanocomposites could substitute noble metal catalysts not only in the oxidation of formaldehyde but also of other volatile organic compounds.

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH