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  • ChemPubSoc Europe Logo
  • Author: Angew. Chem. Int. Ed.
  • Published Date: 15 July 2010
  • Source / Publisher: Angew. Chem. Int. Ed./Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
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The crystalline aluminophosphate melecular sieve with the largest pore openings (20 MR) to date, DNL-1, has been prepared. Zhijian Tian, Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian, China, and co-workers describe the ionothermal synthesis of DNL-1 using a co-structure-directing agent and the confirmation of its structure by Rietveld refinement of PXRD and NMR analysis. The new material has a -CLO framework.

Compared with zeolite analogue of gallophosphate (GaPO4) cloverite, DNL-1 exhibits excellent stability, which suggests potential applications in separation, catalysis, and gas storage.

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