Conformational Preferences in Smart Materials

  • Author: Theresa Kueckmann
  • Published Date: 01 December 2015
  • Source / Publisher: Chemistry – An Asian Journal/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
thumbnail image: Conformational Preferences in Smart Materials

Artificial supramolecular systems with potential applications in the fabrication of smart materials respond to external stimuli with changes in structure, configuration, and supramolecular interaction. In contrast, nature uses the conformational preferences of proteins to respond to stimuli with excellent accuracy, sensitivity, and reversibility. This principle has rarely been utilized in artificial stimuli-responsive systems.


In collaboration with Yuguo Ma of Peking University, Xin Zhao, Ren-Xiao Wang, Zhan-Ting Li and their colleagues at Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, have developed two chiral (A)6B-type supramolecular cages from hydrogen-bonded C6-symmetric zinc porphyrin hexamers and chiral C3-symmetric pyridyl hexadentate linkers with a 1,3,5-triphenylbenzene core. These cages exhibit unique temperature-dependent conformational preferences, which result in different conformational chirality at different temperatures.


The conformational preferences can be transferred and amplified in the whole supramolecular entity, revealing the temperature dependence of the conformational chirality bias. The principle of chirality transfer and amplification on the basis of conformational preference might open up a new route to smart materials with high sensitivity and excellent reversibility.


 

Article Views: 3073

Sign in Area

Please sign in below

Additional Sign In options

Please note that to comment on an article you must be registered and logged in.
Registration is for free, you may already be registered to receive, e.g., the newsletter. When you register on this website, please ensure you view our terms and conditions. All comments are subject to moderation.

Article Comments - To add a comment please sign in

If you would like to reuse any content, in print or online, from ChemistryViews.org, please contact us first for permission. more

Follow on Facebook Follow on Twitter Follow on LinkedIn Follow on Instagram RSS Sign up for newsletters

Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH