Stuck like Glue

  • Author: Rosalyne Cowie
  • Published Date: 04 December 2010
  • Source / Publisher: Chemistry - A European Journal/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
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Host–guest interactions have been exploited to create new linear and cyclic AABB supramolecular polymers composed of tetraphosphonate cavitands and N-methylpyridinium salts.

Enrico Dalcanale and co-workers, Parma, Italy, have designed the new polymers by controlling the flexibility of the ditopic guest spacer, the solvent, and the concentrations used in the system. Solid-state studies have shown that linear polymerization is preferred.

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Magazine of Chemistry Europe (16 European Chemical Societies)published by Wiley-VCH