Nanoflakes Catalyze Nitrogen Monoxide Decomposition

  • Author:
  • Published: 11 June 2017
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
  • Source / Publisher: Dalton Transactions/Royal Society of Chemistry (RSC)
  • Associated Societies: Royal Society of Chemistry (RSC), UK
thumbnail image: Nanoflakes Catalyze Nitrogen Monoxide Decomposition

Nitrogen monoxide (NO) is a pollutant that can contribute to acid rain and ozone layer depletion. It is produced during combustion in cars and its emissions are reduced by the vehicle's catalytic converter. There are a number of silicon-based nanomaterials which act as photocatalysts, but none had been used for NO decomposition so far.

Hiroshi Itahara, Toyota Central R&D Labs., Inc., Nagakute, Japan, and colleagues have developed the first Si-based nanomaterial that is active in the photocatalytic decomposition of NO. The team heated a mixture of CaSi2 and NiCl2 at up to 500 °C. The formation of CaCl2 during this process acts as driving force to extract Ca from the layered CaSi2. The resulting product is a nanocomposite powder composed of Si nanoflakes and metallic particles (Ni and Ni3Si). The CaCl2 was removed by washing with dimethylformamide (DMF).

The nanocomposite has a catalytic activity for NO decomposition under irradiation with light (λ > 290 nm) that is higher than for Si or SiO powders and comparable to TiO2, a commonly used photocatalyst. The activity does not degrade over time. According to the researchers, the same strategy could be used for the production of other high-performance Si-based photocatalysts.


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