New Nitride-Hydride Synthesized

  • Author:
  • Published: 17 February 2019
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
  • Source / Publisher: Inorganic Chemistry/ACS Publications
  • Associated Societies: American Chemical Society (ACS), USA
thumbnail image: New Nitride-Hydride Synthesized

There are few examples of mixed anionic compounds containing both nitride and hydride. One of these rare examples is Ca6Cr2N6H, in which Cr is trigonal-planar coordinated by nitrogen, while the hydride is surrounded by a distorted Ca octahedron and, thus, isolated from the transition metal. Compounds with a similar quarternary composition might also be stable.

Based on this theory, Tiglet Besara, National High Magnetic Field Laboratory, Tallahassee, FL, USA, Missouri State University, Springfield, USA, and colleagues have synthesized a new nitride-hydride, Ba3CrN3H. The team used a molten metal flux technique to prepare the compound. They combined freshly cut barium metal pieces, magnesium turnings, barium hydride powder, and chromium nitride powder in a stainless steel tube, which was welded shut and sealed in an evacuated quartz ampule. The ampule was heated to 850–1000 °C.

The researchers obtained the desired product as greenish hexagonal crystals, which decompose rapidly under ambient conditions. The compound was characterized using energy-dispersive spectroscopy (EDS), X-ray diffraction, and 1H solid-state nuclear magnetic resonance (NMR). The team found that the compound (pictured) contains trigonal planar [CrN3]5– units and octahedral [HBa6]11+ units. The presence of the hydride was confirmed by the NMR results.


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