Heusler Alloys in the Oxygen Evolution Reaction

Water electrolysis driven by sustainable electricity can be used to produce green hydrogen fuel. However, the oxygen evolution reaction (OER) is a bottleneck of water electrolysis. This reaction could benefit from the development of electrocatalysts with improved effectiveness.

Claudia Felser, Max Planck Institute for Chemical Physics of Solids, Dresden, Germany, Harun Tüysüz, Max Planck Institute for Coal Research, Mülheim an der Ruhr, Germany, and colleagues have used Co₂YZ-type Heusler compounds as OER catalysts. Heusler compounds are intermetallic compounds with the chemical formula X₂YZ or XYZ, where X and Y are transition metals and Z is usually a main group element or a transition metal. The team prepared a range of Co₂YZ-type compounds (Co₂MnZ with Z = Ti, Al, V, Ga; Co₂VZ with Z = Sn, Ga) by arc melting stoichiometric amounts of the respective elements.

These alloys have high conductivities and crystallinities. They also have well-defined topological surfaces that are suitable for electrocatalytic applications. The electronic structure of reactive cobalt sites was adjusted by varying the other, unreactive metal sites. A systematic electrocatalytic investigation showed a correlation between the occupancy of d-type orbitals of the cobalt centers and OER performance, with Co₂MnTi and Co₂VSn achieving the best OER activities.

• Tunable e_g orbital occupancy in Heusler compounds for oxygen evolution reaction,
  Mingquan Yu, Guowei Li, Chenguang Fu, Enke Liu, Kaustuv Manna, Eko Budiyanto, Qun Yang, Claudia Felser, Harun Tüysüz,
  Angew. Chem. Int. Ed. 2020.
  https://doi.org/10.1002/anie.202013610

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