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ChemMedChem

Plasmid DNA‐Based Bioluminescence‐Activated System for Photodynamic Therapy in Cancer Treatment

Published: 05 March 2021

Author(s): Di Fan, Ting Wang, Jinhui Hu, Lin Zhou, Jiahong Zhou, Shaohua Wei

Abstract The low depth of tissue penetration by therapeutic light sources severely restricts photodynamic therapy (PDT) in treating deep‐seated tumors. Using a luciferase/d‐luciferin bioluminescence system to artificially create internal light sources in cells instead of external light sources is an effective means of solving the above problems. However, high‐efficiency bioluminescence requires a higher concentration of luciferase in the cell, which poses a considerable challenge to the...

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Chemistry - A European Journal

Natural and Synthetic Oligoarylamides: Privileged Structures for Medical Applications

Published: 04 March 2021

Author(s): Tim Seedorf, Andreas Kirschning, Danny Solga

Abstract The term “privileged structure” refers to a single molecular substructure or scaffold that can serve as a starting point for high‐affinity ligands for more than one receptor type. In this report, a hitherto overlooked group of privileged substructures is addressed, namely aromatic oligoamides, for which there are natural models in the form of cystobactamids, albicidin, distamycin A, netropsin, and others. The aromatic and heteroaromatic core, together with a flexible selection of...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Reactivity of Single Transition Metal Atoms on a Hydroxylated Amorphous Silica Surface: A Periodic Conceptual DFT Investigation

Published: 04 March 2021

Author(s): Xavier Deraet, Jan Turek, Mercedes Alonso, Frederik Tielens, Stefaan Cottenier, Paul W. Ayers, Bert M. Weckhuysen, Frank De Proft

Abstract The drive to develop maximal atom‐efficient catalysts coupled to the continuous striving for more sustainable reactions has led to an ever‐increasing interest in single‐atom catalysis. Based on a periodic conceptual density functional theory (cDFT) approach, fundamental insights into the reactivity and adsorption of single late transition metal atoms supported on a fully hydroxylated amorphous silica surface have been acquired. In particular, this investigation revealed that the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Computational Insights into Different Mechanisms for Ag‐, Cu‐, and Pd‐Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones

Published: 04 March 2021

Author(s): Yong Wu, Shanshan Cao, Iskander Douair, Laurent Maron, Xihe Bi

Abstract The [2+1] cycloaddition reaction of a metal carbene with an alkene can produce important cyclopropane products for synthetic intermediates, materials, and pharmaceutical applications. However, this reaction is often accompanied by side reactions, such as coupling and self‐coupling, so that the yield of the cyclopropanation product of non‐silver transition‐metal carbenes and hindered alkenes is generally lower than 50 %. To solve this problem, the addition of a low concentration of...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

How the Physicochemical Properties of the Bulk Material Affect the Ablation Crater Profile, Mass Balance, and Bubble Dynamics During Single‐Pulse, Nanosecond Laser Ablation in Water

Published: 04 March 2021

Author(s): Mark‐Robert Kalus, Stephan Barcikowski, Bilal Gökce

Abstract Understanding the key steps that drive the laser‐based synthesis of colloids is a prerequisite for learning how to optimize the ablation process in terms of nanoparticle output and functional design of the nanomaterials. Even though many studies focus on cavitation bubble formation using single‐pulse ablation conditions, the ablation efficiency and nanoparticle properties are typically investigated under prolonged ablation conditions with repetition rate lasers. Linking single‐pulse...

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Chemistry - A European Journal

Zirconium Catalyzed Hydroaminoalkylation for the Synthesis of α‐Arylated Amines and N‐Heterocycles

Published: 04 March 2021

Author(s): Ana Koperniku, Laurel L. Schafer

Abstract The zirconium catalyzed hydroaminoalkylation of alkenes with N‐aryl‐ and sterically demanding N‐alkyl‐α‐arylated secondary amines by using commercially available Zr(NMe2)4 is reported. N‐phenyl‐ and N‐isopropylbenzylamine are used as amine substrates to establish the alkene substrate scope. Exclusively linear products are obtained in the presence of bulky vinylsilanes. Challenging α‐heteroarylated amines and functionalized alkene substrates are compatible with this easy to use...

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Chemistry - A European Journal

Crystal Structure and Ferroelectric Evidence of BaZnSi3O8, a Low‐Permittivity Microwave Dielectric Ceramic

Published: 04 March 2021

Author(s): Zheng‐Yu Zou, Xiao‐Qiang Song, Lei Jiang, Chang‐Lai Yuan, Wen‐Zhong Lu, Yong‐Ming Hu, Wen Lei

Abstract BaZnSi3O8 ceramic was prepared by the conventional solid‐state method and sintered at 1100 °C. XRD and synchrotron Rietveld refinement analyses revealed the BaZnSi3O8 ceramic presented a monoclinic structure with a space group of P21/a (No.14), which is reported for the first time. The BaZnSi3O8 ceramic presented a weak ferroelectricity, which was confirmed by the P–E loop and the 90° nanoscale ferroelectric domain. Although ϵr–T displayed two ϵr abnormal peaks at 400 °C and 460 °C,...

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Chemistry - A European Journal

High‐pressure Nucleation of Low‐Density Polymorphs**

Published: 04 March 2021

Author(s): Szymon Sobczak, Paulina Ratajczyk, Andrzej Katrusiak

Abstract New polymorphs β and γ of bis‐3‐nitrophenyl disulphide, crystallized above 0.3 GPa, are less dense than the ambient‐pressure polymorph α. This counterintuitive density relation results from the high‐entropy nucleation and subsequent kinetic crystallization. The work performed by pressure compensates the high entropy and temperature product, substantiated in varied conformers and increased chemical potential. Pressure‐increased viscosity promotes the kinetic polymorphs, in accordance...

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Chemistry - A European Journal

Synthesis and Evaluation of Novel Ring‐Strained Noncanonical Amino Acids for Residue‐Specific Bioorthogonal Reactions in Living Cells

Published: 04 March 2021

Author(s): Christopher D. Reinkemeier, Christine Koehler, Paul F. Sauter, Nataliia V. Shymanska, Cecile Echalier, Anna Rutkowska, David W. Will, Carsten Schultz, Edward A. Lemke

Abstract Bioorthogonal reactions are ideally suited to selectively modify proteins in complex environments, even in vivo. Kinetics and product stability of these reactions are crucial parameters to evaluate their usefulness for specific applications. Strain promoted inverse electron demand Diels–Alder cycloadditions (SPIEDAC) between tetrazines and strained alkenes or alkynes are particularly popular, as they allow ultrafast labeling inside cells. In combination with genetic code expansion...

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Chemistry - A European Journal

Electrochemically Enabled One‐Pot Multistep Synthesis of C19 Androgen Steroids

Published: 04 March 2021

Author(s): Florian Sommer, C. Oliver Kappe, David Cantillo

Abstract The synthesis of many valuable C19 androgens can be accomplished by removal of the C17 side chain from more abundant corticosteroids, followed by further derivatization of the resulting 17‐keto derivative. Conventional chemical reagents pose significant drawbacks for this synthetic strategy, as large amounts of waste are generated, and quenching of the reaction mixture and purification of the 17‐ketosteroid intermediate are typically required. Herein, we present mild, safe, and...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

December 2020

 


Xu Xiao, Wei Yao, Jun Tang, Chuanfang Liu, Ruqian Lian, Patrick Urbankowski, Mark Anayee, Shijie He, Jianmin Li, Hao Wang, Yu Gao, Yingjin Wei, Yury Gogotsi
Cover Feature: Interconnected Two-dimensional Arrays of Niobium Nitride Nanocrystals as Stable Lithium Host (Batteries & Supercaps 1/2021) [Cover Picture]
Batteries & Supercaps 2021, vol. 4, no. 1, p. 4

Hiroki Sakuta, Fumika Fujita, Tsutomu Hamada, Masahito Hayashi, Kingo Takiguchi, Kanta Tsumoto, Kenichi Yoshikawa
Self-Emergent Protocells Generated in an Aqueous Solution with Binary Macromolecules through Liquid-Liquid Phase Separation [Communication]
ChemBioChem 2020, vol. 21, no. 23, p. 3323

Michael Bowker
Methanol Synthesis from CO2 Hydrogenation [Minireview]
ChemCatChem 2019, vol. 11, no. 17, p. 4238

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Armin Welker, Christian Kersten, Christin Müller, Ramakanth Madhugiri, Collin Zimmer, Patrick Müller, Robert Zimmermann, Stefan Hammerschmidt, Hannah Maus, John Ziebuhr, Christoph Sotriffer, Tanja Schirmeister
Structure-Activity Relationships of Benzamides and Isoindolines Designed as SARS-CoV Protease Inhibitors Effective against SARS-CoV-2 [Full Paper]
ChemMedChem 2021, vol. 16, no. 2, p. 340

Sebastian Gisbertz, Bartholomäus Pieber
Heterogeneous Photocatalysis in Organic Synthesis [Review]
ChemPhotoChem 2020, vol. 4, no. 7, p. 456

Thomas G. Mayerhöfer, Alicja Dabrowska, Andreas Schwaighofer, Bernhard Lendl, Jürgen Popp
Beyond Beer's Law: Why the Index of Refraction Depends (Almost) Linearly on Concentration [Communication]
ChemPhysChem 2020, vol. 21, no. 8, p. 707

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Andrei Dragan
A New Era [Editorial]
Asian J. Org. Chem. 2021, vol. 10, no. 1, p. 3

Daniela Rodrigues Silva, Lucas Azevedo Santos, Matheus P. Freitas, Célia Fonseca Guerra, Trevor A. Hamlin
Nature and Strength of Lewis Acid/Base Interaction in Boron and Nitrogen Trihalides [Full Paper]
Chem. Asian J. 2020, vol. 15, no. 23, p. 4043

Yubing Lu, Zihao Zhang, Fan Lin, Huamin Wang, Yong Wang
Single-atom Automobile Exhaust Catalysts [Minireview]
ChemNanoMat 2020, vol. 6, no. 12, p. 1659

Conor Lanphere, Patrick M. Arnott, Sioned Fôn Jones, Katarina Korlova, Stefan Howorka
A Biomimetic DNA-Based Membrane Gate for Protein-Controlled Transport of Cytotoxic Drugs [Research Article]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 4, p. 1903

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Annette Hille-Rehfeld
Die Geochemie des schneeweißen Gebirgsbachs [Treffpunkt Forschung]
Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 6

Katrin Kruse, Katrin Knickmeier, Daniela Honorato-Zimmer, Magdalena Gatta-Rosemary, Anna Weinmann, Tim Kiessling, Katrin Schöps, Martin Thiel, Ilka Parchmann
Titelbild: Dem Plastikmüll auf der Spur - Ein internationales Citizen-Science-Projekt zur Förderung der naturwissenschaftlichen Grundbildung von Schülerinnen und Schülern (CHEMKON 7/2020) [Titelbild]
CHEMKON 2020, vol. 27, no. 7, p. 301

Cover Picture Lebensmittelchemie 6/2020 [Cover Picture]
Lebensmittelchemie 2020, vol. 74, no. 6

Elementerätsel Dezember 2020 [Ausgeblättert]
Nachr. Chem. 2020, vol. 68, no. 12, p. 98

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH