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Advanced Functional Materials

Interlayer Lithium Plating in Au Nanoparticles Pillared Reduced Graphene Oxide for Lithium Metal Anodes

Published: 17 August 2018

Author(s): Jun Pu, Jiachen Li, Zihan Shen, Chenglin Zhong, Jinyun Liu, Haixia Ma, Jia Zhu, Huigang Zhang, Paul V Braun

Abstract Lithium metal anodes suffer from serious safety issues and rapid capacity fade because of nonideal plating/stripping behaviors. Lithium nucleation on undesired positions usually results from nonuniform multiphysical field distributions and the dynamically changing interface thermodynamics. In this study, a sandwich composite anode consisting of gold nanoparticles pillared reduced graphene oxide (rGO) is designed . Because...

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Chemistry - A European Journal

Dynamic Motion of Organic Ligands in Polar Layered Cobalt Phosphonates

Published: 17 August 2018

Author(s): Zhong‐Sheng Cai, Norihisa Hoshino, Song‐Song Bao, Jiage Jia, Tomoyuki Akutagawa, Li‐Min Zheng

Abstract By introducing the polar methoxy group into phenyl‐ or benzyl‐phosphonate ligands, four cobalt phosphonates with layered structures are obtained, namely, [Co(4‐mopp)(H2O)] (1), [Co(4‐mobp)(H2O)] (2), [Co(3‐mopp)(H2O)] (3), and [Co(3‐mobp)(H2O)] (4), where 4‐ or 3‐moppH2 is (4‐ or 3‐methoxyphenyl)phosphonic acid and 4‐ or 3‐mobpH2 is (4‐ or 3‐methoxybenzyl)phosphonic acid. Compounds 1, 2, and 4 crystallize in the polar space groups Pmn21 or Pna21,...

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Advanced Materials

Parts‐per‐Million‐Level Doping Effects in Organic Semiconductor Films and Organic Single Crystals

Published: 17 August 2018

Author(s): Masahiro Hiramoto, Mitsuru Kikuchi, Seiichiro Izawa

Abstract Controlling the pn‐type behavior of a semiconductor such as silicon by adding an extremely small quantity of an impurity (doping) is a central part of inorganic semiconductor electronics since the 20th century. Recent progress in the doping of organic semiconductors strongly suggests the advent of a new era of doped organic semiconductors. Here, the principles and effects of doping at the level of parts per million (ppm) in...

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Angewandte Chemie

Neue Methoden und Designprinzipien für zellgängige Peptide

Published: 17 August 2018

Author(s): Leila Peraro, Joshua A. Kritzer

Abstract Biomoleküle, wie Antikörper, Proteine und Peptide, sind wichtige Werkzeuge in der chemischen Biologie und Ansatzpunkte für die Wirkstoffentwicklung. Sie wurden erfolgreich verwendet, um eine Reihe von extrazellulären Proteinen zu inhibieren, allerdings stellt die Interaktion mit intrazellulären Proteinen eine weit größere Herausforderung dar. In dieser Aufsatz diskutieren wir unterschiedliche chemische Ansätze, die zu...

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Angewandte Chemie

Chiral N,N Ligands Enabling Palladium‐Catalyzed Enantioselective Intramolecular Heck–Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

Published: 17 August 2018

Author(s): Rafaela C. Carmona, Otto D. Köster, Carlos Roque Duarte Correia

Abstract Unprecedented enantioselective intramolecular Heck carbonylation reactions of arenediazonium salts were enabled by a chiral N,N ligand. This reaction constitutes the first enantioselective Heck carbonylation that proceeds through migratory insertion followed by CO insertion. The enantioenriched functionalized dihydrobenzofurans were obtained in good to high yields and enantiomeric ratios of up to 98:2 under mild and...

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Angewandte Chemie

A Practical and General Amidation Method from Isocyanates Enabled by Flow Technology

Published: 17 August 2018

Author(s): Jason D. Williams, William J. Kerr, Stuart G. Leach, David M. Lindsay

Abstract The addition of carbon nucleophiles to isocyanates represents a conceptually flexible and efficient approach to the preparation of amides. This general synthetic strategy has, however, been relatively underutilized owing to narrow substrate tolerance and the requirement for less favourable reaction conditions. Herein, we disclose a high‐yielding, mass‐efficient, and scalable method with appreciable functional group...

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Angewandte Chemie

Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X‐ray Nanospectroscopy

Published: 17 August 2018

Author(s): Ilse K. van Ravenhorst, Charlotte Vogt, Heiko Oosterbeek, Koen W. Bossers, José G. Moya‐Cancino, Alexander P. van Bavel, Ad M. J. van der Eerden, David Vine, Frank M. F. de Groot, Florian Meirer, Bert M. Weckhuysen

Abstract A state‐of‐the‐art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra‐ and interparticular heterogeneities previously believed not to...

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European Journal of Organic Chemistry

Hydrogen‐Bonding Interactions in the Ley–Griffith Oxidation: Practical Considerations for the Synthetic Chemist

Published: 17 August 2018

Author(s): Peter W. Moore, Timothy J. Zerk, Jed M. Burns, Paul V. Bernhardt, Craig M. Williams

The Ley–Griffith oxidation, which is catalyzed by tetra‐n‐propylammonium perruthenate (TPAP, nPr4N[RuO4]), is a popular method for not only controlled oxidation of primary alcohols to aldehydes, but also a host of other synthetically useful transformations. While the fundamental reaction mechanism has recently been elucidated, several key hydrogen‐bonding interactions between the reagents were implicated but not investigated. Herein the prevalence of...

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Chemistry - A European Journal

Norbornadiene‐Based Photoswitches with Exceptional Combination of Solar Spectrum Match and Long‐Term Energy Storage

Published: 17 August 2018

Author(s): Martyn Jevric, Anne U. Petersen, Mads Mansø, Sandeep Kumar Singh, Zhihang Wang, Ambra Dreos, Christopher Sumby, Mogens Brøndsted Nielsen, Karl Börjesson, Paul Erhart, Kasper Moth‐Poulsen

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018

 


Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald
A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli
Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview]
ChemBioChem 2018

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Klaus Roth
Die Suche nach dem Blau der „Blauen Blume“ [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 192

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov
Leone Spiccia Memorial Issue [Editorial]
ChemPlusChem 2018, vol. 83, p. 548

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko
Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review]
ChemNanoMat 2018, vol. 4, p. 598

R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius
DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication]
Chem. Eur. J. 2018

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan
Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper]
ChemMedChem 2018

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber
Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article]
ChemPhotoChem 2018

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu
Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview]
Eur. J. Org. Chem. 2018, p. 2301

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Markus Hiebel, Katharina Reh
Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 606

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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