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My Early View Articles

The Chemical Record

The Longer Route can be Better: Electrosynthesis in Extended Path Flow Cells

Published: 24 July 2021

Author(s): Richard C. D. Brown

Abstract This personal account provides an overview of work conducted in my research group, and through collaborations with other chemists and engineers, to develop flow electrolysis cells and apply these cells in organic electrosynthesis. First, a brief summary of my training and background in organic synthesis is provided, leading in to the start of flow electrosynthesis in my lab in collaboration with Derek Pletcher. Our work on the development of extended path electrolysis flow reactors is...

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Advanced Materials

Chiral Phonons and Giant Magneto‐Optical Effect in CrBr3 2D Magnet

Published: 24 July 2021

Author(s): Qihua Xiong, Su Ying Quek, Zdenek Sofer, David Sedmidubsky, Marco Serra, Lifa Zhang, Yuqing Huang, Andrés Granados del Águila, Sheng Liu, Kanchan Ajit Ulman, Tingting Yin

Abstract Phonons with chirality determine the optical helicity of inelastic light scattering processes due to their nonzero angular momentum. Here it is shown that 2D magnetic CrBr3 hosts chiral phonons at the Brillouin‐zone center. These chiral phonons are linear combinations of the doubly‐degenerate Eg phonons, and the phonon eigenmodes exhibit clockwise and counterclockwise rotational vibrations corresponding to angular momenta of l = ± 1. Such Eg chiral phonons completely switch the...

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Berichte zur Wissenschaftsgeschichte

Galileis Verbrechen: Kepler, Galilei und das crimen laesae humanitatis

Published: 24 July 2021

Author(s): Andreas Kleinert

Abstract Johannes Kepler is often cited as a witness to scholars’ resistance to the shift from Latin to vernacular languages in the scientific literature in the early 17th century. Allegedly he was unable to read Italian, and reacted to Galileo's transition from Latin to Italian by accusing him of committing a crimen laesae humanitatis, with the double sense of “crime against humanity” and “crime against classical scholarship”. The paper shows that this claim is groundless. The arguments are...

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Advanced Materials

Molecular Alignment of Homoleptic Iridium Phosphors in Organic Light‐Emitting Diodes

Published: 24 July 2021

Author(s): Moon Chul Jung, John Facendola, Jongchan Kim, Daniel Sylvinson Muthiah Ravinson, Peter I. Djurovich, Stephen R. Forrest, Mark E. Thompson

Abstract The orientation of facial (fac) tris‐cyclometalated iridium complexes in doped films prepared by vacuum deposition is investigated by altering the physical shape and electronic asymmetry in the molecular structure. Angle‐dependent photoluminescence spectroscopy and Fourier‐plane imaging microscopy show that the orientation of roughly spherical fac‐tris(2‐phenylpyridyl)iridium (Ir(ppy)3) is isotropic, whereas complexes that are oblate spheroids,...

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Advanced Materials

Significant Improvements in Dielectric Constant and Energy Density of Ferroelectric Polymer Nanocomposites Enabled by Ultralow Contents of Nanofillers

Published: 24 July 2021

Author(s): Qing Wang, Lijie Dong, Chuanxi Xiong, Yan Zhao, Guanghui Zhao, Yao Zhou, Yang Liu, Ting Han, Yunyun Cheng, Jingsai Cheng, Li Li

Abstract Polymer dielectrics with excellent processability and high breakdown strength (Eb) enable the development of high‐energy‐density capacitors. Although the improvement of dielectric constant (K) of polymer dielectric has been realized by adding high‐K inorganic fillers with high contents ( 10 vol%), this approach faces significant challenges in scalable film processing. Here, the incorporation of ultralow ratios (

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Advanced Functional Materials

Preclinical Cancer Theranostics—From Nanomaterials to Clinic: The Missing Link

Published: 24 July 2021

Author(s): Kochurani K. Johnson, Pramod Koshy, Jia‐Lin Yang, Charles C. Sorrell

Abstract Nanomaterials with cancer‐imaging and therapeutic properties have emerged as the principal focus of nanotheranostics. The past decade has experienced a significant increase in research in the design, formulation, and preclinical and clinical trials of theranostic nanosystems. However, current theranostic nanoformulations have yet to be approved by the FDA for clinical use. Consequently, the present review focuses on the importance of the careful examination of the in vivo preclinical...

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Advanced Materials

A Universal Compensation Strategy to Anchor Polar Organic Molecules in Bilayered Hydrated Vanadates for Promoting Aqueous Zinc‐Ion Storage

Published: 24 July 2021

Author(s): Fang Wan, Zhimeng Hao, Shuai Wang, Youxuan Ni, Jiacai Zhu, Zhiwei Tie, Songshan Bi, Zhiqiang Niu, Jun Chen

Abstract The electrochemical performance of layered vanadium oxides is often improved by introducing guest species into their interlayer. Guest species with high stability in the interlayer and weak interaction with Zn2+ during charge/discharge process are desired to promoting reversible Zn2+ transfer. Herein, a universal compensation strategy was developed to introduce various polar organic molecules into the interlayer of AlxV2O5·nH2O by replacing partial crystal water. The high‐polar groups...

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Journal of Applied Polymer Science

A new flame‐retardant medium density fiberboard with no formaldehyde release: Wood fiber cell walls template zeolite via in situ thermocompression

Published: 24 July 2021

Author(s): Ran Li, Lifei Feng, Yuxin Liang, Jie Gao, Wenbin Yang

Abstract Fiberboard which is not flame retardant and releases formaldehyde is widely used in residents' life, which brings serious problems. Now, we use water glass and Al2(SO4)3 to form zeolite precursor, and use UP as adhesive to prepare zeolite‐based flame retardant formaldehyde‐free medium density fiberboard in situ within a few minutes. The molecular sieve structure was characterized by SEM, TEM, BET, and XRD. At the same time, we put forward the possible mechanism of zeolite formation...

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Advanced Materials

Large‐Area Vertically Aligned Bismuthene Nanosheet Arrays from Galvanic Replacement Reaction for Efficient Electrochemical CO2 Conversion

Published: 24 July 2021

Author(s): Jia Fan, Xuan Zhao, Xinnan Mao, Jie Xu, Na Han, Hao Yang, Binbin Pan, Yongshen Li, Lu Wang, Yanguang Li

Abstract There is a lack of straightforward methods to prepare high‐quality bismuthene nanosheets, or, even more challengingly, to grow their arrays due to the low melting point and high oxophilicity of bismuth. This synthetic obstacle has hindered their potential applications. In this work, it is demonstrated that the galvanic replacement reaction can do the trick. Under well‐controlled conditions, large‐area vertically aligned bismuthene nanosheet arrays are grown on Cu substrates of various...

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Advanced Materials

2D Ruddlesden–Popper Perovskite with Ordered Phase Distribution for High‐Performance Self‐Powered Photodetectors

Published: 24 July 2021

Author(s): Liangliang Min, Wei Tian, Fengren Cao, Jun Guo, Liang Li

Abstract 2D Ruddlesden–Popper perovskites exhibit great potential in optoelectronic devices for superior stability compared with their 3D counterparts. However, to achieve a high level of device performance, it is crucial but challenging to regulate the phase distribution of 2D perovskites to facilitate charge carrier transfer. Herein, using a solvent additive method (adding a small amount of dimethyl sulfoxide (DMSO) in N,N‐dimethylformamide (DMF)) combined with a hot‐casting process, the...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

June 2021

 


Fang Zhang, Juewen Liu
Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review]
Anal. Sens. 2021, vol. 1, no. 1, p. 30

Rola Houhou, Thomas Bocklitz
Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review]
Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128

Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster
High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article]
Batteries Supercaps 2021, vol. 4, no. 6, p. 934

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Matthew Kottwitz, Yuanyuan Li, Haodong Wang, Anatoly I. Frenkel, Ralph G. Nuzzo
Single Atom Catalysts: A Review of Characterization Methods [Review]
Chem. Methods 2021, vol. 1, no. 6, p. 278

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Sebastian Gisbertz, Bartholomäus Pieber
Heterogeneous Photocatalysis in Organic Synthesis [Review]
ChemPhotoChem 2020, vol. 4, no. 7, p. 456

Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview]
ChemPhysChem 2018, vol. 19, no. 11, p. 1315

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Saheed E. Elugoke, Abolanle S. Adekunle, Omolola E. Fayemi, Ekemini D. Akpan, Bhekie B. Mamba, El-Sayed M. Sherif, Eno E. Ebenso
Molecularly imprinted polymers (MIPs) based electrochemical sensors for the determination of catecholamine neurotransmitters - Review [REVIEW]
Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2000026

Agustí Lledós
Computational Organometallic Catalysis: Where We Are, Where We Are Going [Essay]
Eur. J. Inorg. Chem. 2021, p. 2547

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Rituparno Chowdhury, Venkata Sai Sreyas Adury, Amal Vijay, Reman K. Singh, Arnab Mukherjee
Atomistic De-novo Inhibitor Generation-Guided Drug Repurposing for SARS-CoV-2 Spike Protein with Free-Energy Validation by Well-Tempered Metadynamics [Full Paper]
Chem. Asian J. 2021, vol. 16, no. 12, p. 1634

Jennifer Schnabel, Romy Ettlinger, Hana Bunzen
Zn-MOF-74 as pH-Responsive Drug-Delivery System of Arsenic Trioxide [Full Paper]
ChemNanoMat 2020, vol. 6, no. 8, p. 1229

Julian Baars, Isabelle Grimm, Dirk Blunk, Jörg-Martin Neudörfl, Hans-Günther Schmalz
Enantioselective Total Synthesis and Structural Revision of Dysiherbol A [Communication]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 27, p. 14915

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Emiliano Feresin*, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen*
Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel]
Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

Thomas Waitz, Erhard Irmer
Nachhaltigkeit in der Chemie [Editorial]
CHEMKON 2021, vol. 28, no. 4, p. 146

Cover Picture Lebensmittelchemie 3/2021 [Cover Picture]
Lebensmittelchemie 2021, vol. 75, no. 3

Robert Schlögl
Pro: E-Fuels [Bildung + Gesellschaft]
Nachr. Chem. 2021, vol. 69, no. 6, p. 8

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH