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Chemistry - A European Journal

Homoleptic Trifluoromethyl Derivatives of Ag I and Ag III

Published: 16 August 2018

Author(s): Daniel Joven‐Sancho, Miguel Baya, Antonio Martín, Babil Menjón

Abstract The homoleptic silver(I) compound [PPh4][CF3AgCF3] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4][Ag(CF3)4] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their structural and spectroscopic properties have been experimentally established. Moreover, their electronic structures have been calculated by theoretical methods. The electronic structure of the oxidized...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Fluorescent Trimethylated Naphthyridine Derivative with an Aminoalkyl Side Chain as the Tightest Non‐aminoglycoside Ligand for the Bacterial A‐site RNA

Published: 16 August 2018

Author(s): Yusuke Sato, Masafumi Rokugawa, Sho Ito, Sayaka Yajima, Hiroki Sugawara, Norio Teramae, Seiichi Nishizawa

Abstract The bacterial ribosomal decoding region of the aminoacyl‐tRNA site (A‐site) is one of the most validated target RNAs for antibiotic agents. Although natural aminoglycosides are well‐characterized A‐site binding ligands, high off‐target effects and the growing emergence of bacterial resistance against aminoglycosides limit their clinical use. To circumvent these concerns with the aminoglycoside family, non‐aminoglycoside...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Transition Metal Carbide Complex Architectures for Energy‐Related Applications

Published: 16 August 2018

Author(s): Tao Meng, Minhua Cao

Abstract Transition metal carbides (TMCs), as a family of special interstitial alloys, exhibit novel intrinsic characteristics such as high melting point, high electronic conductivity, excellent mechanical and chemical stability, and good corrosion resistance, and hence have attracted ever‐growing attention as promising electrode materials for energy‐related applications. In this regard, we give a comprehensive overview of the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Norbornadiene‐Based Photoswitches with Exceptional Combination of Solar Spectrum Match and Long‐Term Energy Storage

Published: 16 August 2018

Author(s): Martyn Jevric, Anne U. Petersen, Mads Mansø, Sandeep Kumar Singh, Zhihang Wang, Ambra Dreos, Christopher Sumby, Mogens Brøndsted Nielsen, Karl Börjesson, Paul Erhart, Kasper Moth‐Poulsen

Abstract Norbornadiene‐quadricyclane (NBD‐QC) photoswitches are candidates for applications in solar thermal energy storage. Functionally, they rely on an intramolecular [2+2] cycloaddition reaction, which couples the S0 landscape on the NBD side to the S1 landscape on the QC side of the reaction and vice‐versa. This commonly results in an unfavourable correlation between the first absorption maximum and the barrier for thermal back‐conversion....

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Pentafluoroethylated Compounds of Silicon, Germanium and Tin

Published: 16 August 2018

Author(s): Markus Wiesemann, Berthold Hoge

Abstract In this contribution we present an account on pentafluoroethylated compounds of silicon, germanium and tin. The pronounced electron‐withdrawing effect of the pentafluoroethyl group leads to a markedly increased Lewis acidity at the central atom which results in the stabilization of hypervalent complexes, anionic element(II) species as well as remarkable reactivities of element‐element and element‐hydrogen bonds. By addition...

thumbnail image: Chemistry - A European Journal

Journal of Chemical Technology & Biotechnology

Probing the viability of palladium‐challenged bacterial cells using flow cytometry

Published: 16 August 2018

Author(s): Jacob B Omajali, Iryna P Mikheenko, Tim W Overton, Mohamed L Merroun, Lynne E Macaskie

Abstract BACKGROUND The ability of bacterial cells to retain membrane integrity and membrane potential when challenged with palladium (II) solution has not being examined previously, which would provide a platform towards the bio‐fabrication of a multifunctional tandem bio‐nanoparticles. This study investigates the use of flow cytometry coupled with fluorescent probes to determine membrane integrity...

thumbnail image: Journal of Chemical Technology & Biotechnology

Angewandte Chemie

Light‐Triggered Release of Trapped Charges in Molecular Assemblies

Published: 16 August 2018

Author(s): Renata Balgley, Yadid M. Algavi, Neta Elool Dov, Michal Lahav, Milko E. van der Boom

Abstract We demonstrate the mediation of charge transport and release in thin films and devices by shifting the redox properties of layers of metal complexes by light. The nanoscale surface arrangement of both photo‐ and electrochemically‐active components is essential for the function of the thin films. Layers of well‐defined ruthenium complexes on indium‐tin‐oxide electrodes provide electron‐transport channels that allow the...

thumbnail image: Angewandte Chemie

ChemSusChem

Inexpensive but Highly Efficient Co–Mn Mixed‐Oxide Catalysts for Selective Oxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid

Published: 16 August 2018

Author(s): Kasanneni Tirumala Venkateswara Rao, Jennifer Lorraine Rogers, Sadra Souzanchi, Luana Dessbesell, Madhumita Bhowmick Ray, Chunbao (Charles) Xu

Abstract A highly active and inexpensive Co–Mn mixed‐oxide catalyst was prepared and used for selective oxidation of 5‐hydroxymethylfurfural (HMF) into 2, 5‐furandicarboxylic acid (FDCA). Co–Mn mixed‐oxide catalysts with different Co/Mn molar ratios were prepared through a simple solid‐state grinding method—a low‐cost and green catalyst preparation method. The activity of these catalysts was evaluated for selective aerobic oxidation...

thumbnail image: ChemSusChem

ChemSusChem

Building a Thermostable Metabolon for Facilitating Coenzyme Transport and In Vitro Hydrogen Production at Elevated Temperature

Published: 16 August 2018

Author(s): Hui Chen, Rui Huang, Eui‐Jin Kim, Yi‐Heng P. Job Zhang

Abstract To facilitate coenzyme transport and in vitro enzymatic hydrogen production, a multi‐enzyme metabolon comprising a miniscaffoldin containing three cohesins, a dockerin‐containing mutant dehydrogenase, a dockerin‐containing diaphorase, and a Histidine‐tagged (His‐tagged) NiFe hydrogenase was constructed. As the NiFe hydrogenase has very complicated structure and cannot be fused directly with a dockerin, a bifunctional...

thumbnail image: ChemSusChem

Chemistry - An Asian Journal

Recent Advances in the Organocatalytic Enantioselective Synthesis of Functionalized β‐Lactones

Published: 16 August 2018

Author(s): Subrata Mukherjee, Akkattu T. Biju

Abstract This Focus Review highlights recent developments in the organocatalytic enantioselective synthesis of β‐lactone derivatives. Owing to the importance of β‐lactones as a heterocyclic motif that is present in a variety of natural products and biologically active molecules, several catalytic methods have been developed for the synthesis of these compounds in their enantiomerically pure form. Organocatalytic methods that employ...

thumbnail image: Chemistry - An Asian Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018

 


Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald
A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli
Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview]
ChemBioChem 2018

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Klaus Roth
Die Suche nach dem Blau der „Blauen Blume“ [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 192

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov
Leone Spiccia Memorial Issue [Editorial]
ChemPlusChem 2018, vol. 83, p. 548

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko
Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review]
ChemNanoMat 2018, vol. 4, p. 598

R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius
DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication]
Chem. Eur. J. 2018

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan
Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper]
ChemMedChem 2018

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber
Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article]
ChemPhotoChem 2018

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu
Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview]
Eur. J. Org. Chem. 2018, p. 2301

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Markus Hiebel, Katharina Reh
Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 606

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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