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Advanced Functional Materials

Enhancement of Anomalous Hall Effect via Interfacial Scattering in Metal‐Organic Semiconductor Fex(C60)1−x Granular Films Near the Metal‐Insulator Transition

Published: 24 June 2019

Author(s): Lingcheng Zheng, Zhihao He, Rui Zhang, Jiangtao Qu, Deqiang Feng, Jie He, Hansheng Chen, Fan Yun, Yahui Cheng, Zhiqing Li, Hui Liu, Xixiang Zhang, Rongkun Zheng

Abstract Ferromagnetic metal‐insulator granular films suffer from superparamagnetism, which causes a decrease in the values and temperature stabilities of the anomalous Hall effect (AHE). In this work, organic semiconductor (OSC) fullerene (C60), instead of the traditional inorganic insulators, is used as the matrix and a series of Fex(C60)1−x (x = 0.58–0.91) granular films are fabricated. By utilizing the strong metal/OSC interfacial hybridization, the temperature stability of both...

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Advanced Functional Materials

Infrared Glass–Ceramics with Multidispersion and Gradient Refractive Index Attributes

Published: 24 June 2019

Author(s): Laura Sisken, Myungkoo Kang, Johann M. Veras, Charmayne Lonergan, Andrew Buff, Anupama Yadav, Devon McClane, Cesar Blanco, Clara Rivero‐Baleine, Theresa S. Mayer, Kathleen A. Richardson

Abstract Infrared (IR) glass–ceramics (GCs) hold the potential to dramatically expand the range of optical material solutions available for use in bulk and planar optical systems in the IR. Current material solutions are limited to single‐ or polycrystalline materials and traditional IR‐transparent optical glasses. GCs that can be processed with spatial control and extent of induced crystallization present the opportunity to realize an effective refractive index variation, enabling arbitrary...

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Advanced Functional Materials

Role of Interface Chemistry in Opening New Radiative Pathways in InP/CdSe Giant Quantum Dots with Blinking‐Suppressed Two‐Color Emission

Published: 24 June 2019

Author(s): Allison M. Dennis, Matthew R. Buck, Feng Wang, Nicolai F. Hartmann, Somak Majumder, Joanna L. Casson, John D. Watt, Stephen K. Doorn, Han Htoon, Milan Sykora, Jennifer A. Hollingsworth

Abstract InP/CdSe core/thick‐shell “giant” quantum dots (gQDs) that exhibit blinking‐suppressed two‐color excitonic emission have been synthesized and optically characterized. These type II heterostructures exhibit photoluminescence from both a charge‐separated, near‐infrared type II excitonic state, and a shell‐localized visible‐color excitonic state. Infrared emission is intrinsic to the type II QD, while visible emission can either be eliminated or enhanced through chemical modification of...

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Advanced Materials

Anisotropic Thermal Boundary Resistance across 2D Black Phosphorus: Experiment and Atomistic Modeling of Interfacial Energy Transport

Published: 24 June 2019

Author(s): Man Li, Joon Sang Kang, Huu Duy Nguyen, Huan Wu, Toshihiro Aoki, Yongjie Hu

Abstract Interfacial thermal boundary resistance (TBR) plays a critical role in near‐junction thermal management of modern electronics. In particular, TBR can dominate heat dissipation and has become increasingly important due to the continuous emergence of novel nanomaterials with promising electronic and thermal applications. A highly anisotropic TBR across a prototype 2D material, i.e., black phosphorus, is reported through a crystal‐orientation‐dependent interfacial transport study. The...

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Advanced Materials

Extrinsic Green Photoluminescence from the Edges of 2D Cesium Lead Halides

Published: 24 June 2019

Author(s): Chong Wang, Yanan Wang, Xinghua Su, Viktor G. Hadjiev, Shenyu Dai, Zhaojun Qin, Hector A. Calderon Benavides, Yizhou Ni, Qiang Li, Jie Jian, Md. Kamrul Alam, Haiyan Wang, Francisco C. Robles Hernandez, Yan Yao, Shuo Chen, Qingkai Yu, Guoying Feng, Zhiming Wang, Jiming Bao

Abstract Since the first report of the green emission of 2D all‐inorganic CsPb2Br5, its bandgap and photoluminescence (PL) origin have generated intense debate and remained controversial. After the discovery that PL centers occupy only specific morphological structures in CsPb2Br5, a two‐step highly sensitive and noninvasive optical technique is employed to resolve the controversy. Same‐spot Raman‐PL as a static property–structure probe reveals that CsPbBr3 nanocrystals are contributing to the...

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Journal of Applied Polymer Science

Recycling of crosslinked high‐density polyethylene through compression molding

Published: 23 June 2019

Author(s): Jardel Nobrega Santos, Raghavan Jayaraman

ABSTRACT Crosslinkable high‐density polyethylene (XHDPE) is used to manufacture large and rigid products such as fuel tanks using rotomolding. Currently, defective and postconsumer parts are not recycled and sent to landfills. Hence, recycling of this material through compression molding is the objective of this study. Thermal analysis revealed that the extent of crosslinking varied across the thickness of the rotomolded part due to the role played by oxygen in air. Despite the crosslinking,...

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Starch - Stärke

Effect of Sodium Chloride on the Structure and Properties of Fried Starch

Published: 23 June 2019

Author(s): Miaomiao Shi, Mingyue Zhang, Liuzhi Yang, Dan Li, Yizhe Yan, Xianqing Huang, Yanqi Liu

The effects of NaCl on the structure and properties of fried starch samples are investigated in the present study. Potato starches with different NaCl contents (0, 1, 3, 5, and 7%; w/w) are fried at 180 °C for 3 min. In the presence of NaCl, some starch samples expanded, ruptured, and glued together. The granule structure changes of fried starch become more significant with the increasing NaCl content. Compared to native starch, the crystal structure of fried starches is destroyed according to...

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Starch - Stärke

Rapid Preparation of Oxidized Starch with High Carbonyl Contents Using NaBrO as Oxidizer

Published: 23 June 2019

Author(s): Jinhui Yang, Man Wang, Yinan Zhang, Xiangxiang Jia, Yanxue Chen, Tai Liu, Ziyi Zhang, Hongzhao Yang, Qi Wu, Huining Xiao

In this work, oxidized starch with high carbonyl contents is obtained in a rather simple way using corn starch as raw material and NaBrO as an oxidizer. The produced oxidized starch is evaluated by measuring the carboxyl content, carbonyl content, yield, and the intrinsic viscosity. The influences of pH, reaction time, temperature and oxidizer content on carbonyl content, carboxyl content, intrinsic viscosity, and yield of the oxidized starch are investigated in detail. It is found that the...

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Starch - Stärke

Resistant Starch‐Supplemented Udon Noodles Prevent Impaired Glucose Tolerance and Induce Intestinal Immunoglobulin‐A Secretion in Mice

Published: 23 June 2019

Author(s): Kenji Matsumoto, Hiroki Shimada, Hiroki Morishima, Reina Akahori, Naotaka Kida

Resistant starch (RS) has received considerable attention recently because of its potential benefits upon glucose/lipid metabolism and intestinal conditions. RS‐supplemented Udon noodles (RS‐Udon) are prepared and their functional properties are compared with those of Udon noodles without RS (C‐Udon) in C57BL/6J mice. Both Udon samples are used after lyophilization. Single administration (250 mg kg−1 body weight, p.o.) of RS‐Udon tends to increase blood glucose levels less than that elicited...

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Starch - Stärke

Enzymatic Modification of Granular Potato Starch ‐ Effect of Debranching on Morphological, Molecular, and Functional Properties

Published: 23 June 2019

Author(s): Saeed A. Asiri, Eckhard Flöter, Marco Ulbrich

The debranching enzyme pullulanase (PUL) is used in order to conduct a partial conversion of a regular granular potato starch (PS) improving the techno‐functional properties when used as a gelling agent. The starch is hydrolyzed systematically by grading the amount of a technical enzyme solution added (1, 2, 3, 4, 5, 10, 20, and 40 mL PUL solution) resulting 400 g of a 20% (w/w) suspension. Morphological characteristics of the granules (scanning electron microscopy, SEM), swelling behavior...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

February 2019

 


Pingyu Zhang, Huaiyi Huang, Samya Banerjee, Guy J. Clarkson, Chen Ge, Cinzia Imberti, Peter J. Sadler
Nucleus-Targeted Organoiridium-Albumin Conjugate for Photodynamic Cancer Therapy [Communication]
Angew. Chem. Int. Ed. 2019, vol. 58, p. 2350

Marion Rusch, Arnaud Thevenon, Dominic Hoepfner, Thomas Aust, Christian Studer, Maude Patoor, Patrick Rollin, Madeleine Livendahl, Beatrice Ranieri, Esther Schmitt, Carsten Spanka, Karl Gademann, Laure C. Bouchez
Design and Synthesis of Metabolically Stable tRNA Synthetase Inhibitors Derived from Cladosporin [Communication]
ChemBioChem 2019, vol. 20, p. 644

Wei Jin, Laura Pastor-Pérez, DeKui Shen, Antonio Sepúlveda-Escribano, Sai Gu, Tomas Ramirez Reina
Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review [Review]
ChemCatChem 2019, vol. 11, p. 924

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, p. 50

Thomas Wirth
Meet the Board of ChemistryOpen: Thomas Wirth [Meet the Board]
ChemistryOpen 2019, vol. 8, p. 251

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Mao Jiang, Kangli Wang, Shu Gao, Ruxing Wang, Jing Han, Jie Yan, Shijie Cheng, Kai Jiang
Selenium as Extra Binding Site for Sulfur Species in Sulfurized Polyacrylonitrile Cathodes for High Capacity Lithium-Sulfur Batteries [Article]
CHEMELECTROCHEM 2019, vol. 6, p. 1365

Tianchao Niu, Jialin Zhang, Wei Chen
Surface Engineering of Two-Dimensional Materials [Focus Review]
ChemNanoMat 2019, vol. 5, p. 6

Dennis Rottschäfer, Beate Neumann, Hans-Georg Stammler, Ryohei Kishi, Masayoshi Nakano, Rajendra S. Ghadwal
A Phosphorus Analogue of p-Quinodimethane with a Planar P4 Ring: A Metal-Free Diphosphorus Source [Communication]
Chem. Eur. J. 2019, vol. 25, p. 3244

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, p. 32

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, p. 386

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Mabuatsela V. Maphoru, Josef Heveling, Sreejarani Kesavan Pillai
Solvent and Temperature Effects on the Platinum‐Catalyzed Oxidative Coupling of 1‐Naphthols [Full Paper]
Eur. J. Org. Chem. 2016, p. 331

Cover Picture Lebensmittelchemie 1/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, p. 37

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2017

 


Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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