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Greenhouse Gases: Science and Technology

Experimental investigations and developing multilayer neural network models for prediction of CO2 solubility in aqueous MDEA/PZ and MEA/MDEA/PZ blends

Published: 18 May 2021

Author(s): Tianci Li, Puttipong Tantikhajorngosol, Congning Yang, Paitoon Tontiwachwuthikul

Abstract In this research, a new set of experimental data for CO2 solubility in aqueous blended amine solvents were investigated experimentally over the CO2 partial pressure range from 8 to 100 kPa at 40 °C and were compared with the benchmark aqueous 30 wt.% MEA solution. This work developed two multilayer neural network models named models A and B, for predicting the CO2 solubility in various aqueous blended amine solvents including 36 wt.% MDEA + 17 wt.% PZ, 24 wt.% MDEA + 26 wt.% PZ, and 6...

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Drug Testing and Analysis

Application of single hair analysis reveals multiple administration of a drug mixture in a case of drug‐facilitated sexual assault of a child

Published: 18 May 2021

Author(s): Christopher Wiedfeld, Gisela Skopp, Uta Kuepper, Frank Musshoff

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Greenhouse Gases: Science and Technology

Diffusion coefficients of CO2–SO2–water and CO2–N2–water systems and their impact on the CO2 sequestration process: Molecular dynamics and dissolution process simulations

Published: 18 May 2021

Author(s): Sina Omrani, Saeed Mahmoodpour, Behzad Rostami, Mehdi Salehi Sedeh, Ingo Sass

Abstract The high cost of the CO2 sequestration in saline aquifers is a barrier to the implementation of them. However, a large portion of the cost is invested to purify and transport the CO2 from the flue gas stream of the emission sources. Therefore, the possibility of injecting impure CO2 will reduce the costs strongly. The diffusion coefficient is an important factor that plays a significant role in different aspects of the process. In spite of its importance, it is got less attention due...

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European Journal of Inorganic Chemistry

Theoretical Investigation of Hydrogen‐Bond‐Assisted Tetradentate N4 Copper(I) Chloride and trans‐1,2‐Peroxodicopper Complexes

Published: 18 May 2021

Author(s): Min Zhang, Guangchao Liang, Mengjiang Xing

Abstract Biological oxygenation catalyzed by copper‐containing enzymes involves a dicopper O2 adduct as the key intermediate. Significant insights were offered by the trans‐1,2‐peroxodicopper intermediates. To understand the activity of the trans‐1,2‐peroxodicopper intermediate in the oxygenation, a series of hydrogen‐bond‐assisted CuI(L)−Cl and trans‐1,2‐peroxodicopper complexes [Cu2−O2]2+ were investigated by DFT computations. A reasonable two‐parameter structure‐activity model (R2=0.8611)...

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Applied Organometallic Chemistry

Gelatin‐pyrolyzed mesoporous N‐doped carbon supported Pd as high‐performance catalysts for aqueous Heck reactions

Published: 18 May 2021

Author(s): Shuai Yang, Yuli Chen, Shuaijian Huang, Lu Deng, Yuanyuan Wu, Xiu Zheng, Shakhzodjon Omonov, Minfeng Zeng

Nitrogen‐doped mesoporous carbon‐supported Pd (Pd@N‐C) catalysts were prepared by pyrolyzing gelatin/templates/PdCl2 hydrogels under N2 atmosphere at 800°C. Using poly (ethylene glycol) block poly (propylene glycol) block poly (ethylene glycol) (P123) as soft template and/or colloidal SiO2 as hard templates can significantly improve the Brunauer‐Emmett‐Teller (BET) surface area, porous structure, and pore volumes of the resultant Pd@N‐C catalysts. Pd nanoparticles sized from 10–20 nm can be...

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Journal of Food Process Engineering

Design and parameters optimization of root cutting tool based on garlic numerical simulation model

Published: 18 May 2021

Author(s): Jianneng Chen, Binsong Zhou, Jiangming Jia, Zhiwei Chen, Chennan Yu, Shuanglei Cai

Abstract To obtain the best tool parameters for garlic root cutting to reduce the root cutting force and improve efficiency, a linkage occlusion‐cutting mechanism was designed for a garlic root cutting force test. The physical and mechanical properties of garlic meat and garlic skin were measured and calculated by using a universal material testing machine. A plastic follow‐up model (MAT‐3) in the LS‐DYNA material library was used as a simulated garlic material model. A three‐dimensional model...

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Journal of Applied Toxicology

Effect of ketamine on gene expression in zebrafish embryos

Published: 18 May 2021

Author(s): Qiang Gu, Jyotshna Kanungo

Ketamine at 2 mM (anesthetic dose) altered expression of specific genes related to hypoxia, p53, Wnt, Notch, TGFβ, PPAR, and oxidative stress pathways. The data will help understand ketamine effects at the molecular level.

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Chemistry - A European Journal

The Efficient K Ion Storage of M2P2O7/C (M=Fe, Co, Ni) Anode Derived from Organic‐Inorganic Phosphate Precursors

Published: 18 May 2021

Author(s): Yibo Zhang, Yuying Zheng, Hongbo Geng, Yang Yang, Minghui Ye, Yufei Zhang, Cheng Chao Li

Abstract Metal phosphates have been widely explored in lithium ion batteries and sodium ion batteries owing to high theoretical capacities, mild toxicity and low cost. However, their potassium ion battery applications are less reported due to the limited conductivity and the slow diffusion kinetics. Considering these drawbacks, novel structured M2P2O7/C (M=Fe, Co, Ni) nanoflake composites are prepared through an organic‐phosphors precursor‐assisted solvothermal method and a subsequent high...

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Chemistry - A European Journal

Chiral Chromium Salen@rGO as Multipurpose and Recyclable Heterogeneous Catalyst

Published: 18 May 2021

Author(s): Mariam Abd El Sater, Mohamed Mellah, Diana Dragoe, Emilie Kolodziej, Nada Jaber, Emmanuelle Schulz

Abstract The first immobilization of a pyrene‐tagged chromium salen complex through π‐π noncovalent interactions on reduced graphene oxide (rGO) is described. A very robust supported catalytic system is obtained to promote asymmetric catalysis in repeated cycles, without loss of activity or enantioselectivity. This specific behavior was demonstrated in two different catalytic reactions (up to ten reuses) promoted by chromium salen complexes, the cyclohexene oxide ring‐opening reaction and the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Self‐Foaming Metal‐Organic Gels Based on Phytic Acid and Their Mechanical, Moldable, and Load‐Bearing Properties.

Published: 18 May 2021

Author(s): Yali Xiao, Xi Gong, Jianyong Zhang

Abstract A catalogue of metal‐organic gels are synthesized from phytic acid (PA) and a diversity of metal ions (Fe3+, Cr3+, Al3+, Ce3+, Y3+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, Mg2+) upon heating at 80 °C. PA−M gels have various morphologies, including irregular granular (PA−Fe, PA−Al, PA−Ce, PA−Cr, PA−Ni, PA−Co), spongy (PA−Y), and hollow tremella‐like (PA−Cu) morphologies. Interestingly for PA−Fe‐1 : 4 (PA:Fe3+=1 : 4) a large amount of gas is generated during the gelation process leading to a...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

March 2021

 


Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang
Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview]
Batteries & Supercaps 2021, vol. 4, no. 4, p. 585

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Sebastian Gisbertz, Bartholomäus Pieber
Heterogeneous Photocatalysis in Organic Synthesis [Review]
ChemPhotoChem 2020, vol. 4, no. 7, p. 456

Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview]
ChemPhysChem 2018, vol. 19, no. 11, p. 1315

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar
Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 1373

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun
Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview]
ChemNanoMat 2020, vol. 6, no. 3, p. 336

Huaibo Zhao, Daniele Leonori
Minimization of Back-Electron Transfer Enables the Elusive sp3 C−H Functionalization of Secondary Anilines [Communication]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Emiliano Feresin*, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen*
Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel]
Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

Hilbert Meyer
Guter Unterricht an guten Schulen? [Aufsatz]
CHEMKON 2006, vol. 13, no. 2, p. 77

Bambus in Coffee-to-go-Bechern [Analytik]
Lebensmittelchemie 2021, vol. 75, no. 1, p. 2

Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter
Organische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2021, vol. 69, no. 3, p. 38

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH