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European Journal of Organic Chemistry

Selective Catalytic Hydration of Alkynes in the Presence of Au‐Cavitands: A Study in Structure–Activity Relationships

Published: 17 August 2018

Author(s): Mami Inoue, Katto Ugawa, Tomoyuki Maruyama, Tetsuo Iwasawa

The effects of the catalytic cavities in gold‐functionalized cavitands in the hydration of internal alkynes have been studied. Variations on cavitand structures revealed the importance of two features that were studied: (1) flanking aromatic rings, and (2) an adjacent P=O moiety. The di‐quinoxaline‐spanned resorcin[4]arene system provides a well‐defined compartment, in which a cationic Au ion activates an internal alkyne for conversion...

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Indoor Air

Impact of material emissions and sorption of volatile organic compounds on indoor air quality in a low energy building: Field measurements and modeling

Published: 17 August 2018

Author(s): Malak Rizk, Fangfang Guo, Marie Verriele, Michael Ward, Sebastien Dusanter, Nadège Blond, Nadine Locoge, Coralie Schoemaecker

Abstract The assessment of VOC emission rates and sorption coefficients was performed for ten surfaces present within a classroom, using field and laboratory emission cells (FLEC) coupled to online and off‐line VOC quantification techniques. A total of 21 identified VOCs were emitted by the different surfaces. VOC emission rates measured using PTR‐ToF‐MS were compared to gas chromatographic measurements. The results showed that the...

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Journal of the American Ceramic Society

Understanding the structural origin of intermediate glasses

Published: 17 August 2018

Author(s): Siva Priya Jaccani, Siddharth Sundararaman, Liping Huang

Abstract Intermediate glasses show nearly constant elastic moduli with temperature and/or pressure. These glasses would prove useful in designing a‐thermal optical fibers for enhanced telecommunication, fiber sensing applications, and in designing glass products for applications where a broad range of thermal and mechanical stimulation is expected. In this study, intermediate glasses belonging to the Na2O–SiO2, Na2O–Al2O3–SiO2, and...

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Chemistry - A European Journal

Intramolecular Pd‐Catalyzed Formal anti ‐Carboalkoxylation of Alkynes: Access to Tetrasubstituted Enol Ethers

Published: 17 August 2018

Author(s): Theresa Schitter, Peter G. Jones, Daniel B. Werz

Abstract An intramolecular Pd‐catalyzed formal anti‐carboalkoxylation reaction is presented that provides access to tetrasubstituted enol ethers. The key to success is a cascade consisting of a formal anti‐carbopalladation of a carbon–carbon triple bond followed by a nucleophilic attack of a hydroxy group at the emerging vinyl organopalladium species. The desired transformation proceeded smoothly with primary, secondary, and tertiary alcohols,...

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Angewandte Chemie International Edition

Emerging Methods and Design Principles for Cell‐Penetrant Peptides

Published: 17 August 2018

Author(s): Leila Peraro, Joshua A. Kritzer

Abstract Biomolecules such as antibodies, proteins, and peptides are important tools for chemical biology and leads for drug development. They have been used to inhibit a variety of extracellular proteins, but accessing intracellular proteins has been much more challenging. In this review, we discuss diverse chemical approaches that have yielded cell‐penetrant peptides and identify three distinct strategies: masking backbone amides,...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Three‐Dimensional Heterocycles by Iron‐Catalyzed Ring‐Closing Sulfoxide Imidation

Published: 17 August 2018

Author(s): Hao Yu, Zhen Li, Carsten Bolm

Abstract A general and atom‐economical method for the synthesis of cyclic sulfoximines by intramolecular imidations of azido‐containing sulfoxides using a commercially available FeII phthalocyanine (FeIIPc) as catalyst has been developed. The method conveys a broad functional group tolerance and the resulting three‐dimensional heterocycles can be modified by cross‐coupling reactions.

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Chiral N,N Ligands Enabling Palladium‐Catalyzed Enantioselective Intramolecular Heck–Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

Published: 17 August 2018

Author(s): Rafaela C. Carmona, Otto D. Köster, Carlos Roque Duarte Correia

Abstract Unprecedented enantioselective intramolecular Heck carbonylation reactions of arenediazonium salts were enabled by a chiral N,N ligand. This reaction constitutes the first enantioselective Heck carbonylation that proceeds through migratory insertion followed by CO insertion. The enantioenriched functionalized dihydrobenzofurans were obtained in good to high yields and enantiomeric ratios of up to 98:2 under mild and...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

A Practical and General Amidation Method from Isocyanates Enabled by Flow Technology

Published: 17 August 2018

Author(s): Jason D. Williams, William J. Kerr, Stuart G. Leach, David M. Lindsay

Abstract The addition of carbon nucleophiles to isocyanates represents a conceptually flexible and efficient approach to the preparation of amides. This general synthetic strategy has, however, been relatively underutilized owing to narrow substrate tolerance and the requirement for less favourable reaction conditions. Herein, we disclose a high‐yielding, mass‐efficient, and scalable method with appreciable functional group...

thumbnail image: Angewandte Chemie International Edition

Chemistry - A European Journal

Thieno[3,4‐ c ]pyrrole‐4,6‐dione Oligothiophenes Have Two Crossed Paths for Electron Delocalization

Published: 17 August 2018

Author(s): Dafei Yuan, Samara Medina Rivero, Paula Mayorga Burrezo, Longbin Ren, María E. Sandoval‐Salinas, Sławomir J. Grabowski, David Casanova, Xiaozhang Zhu, Juan Casado

Abstract A new series of electron‐deficient oligothiophenes, thieno[3,4‐c]pyrrole‐4,6‐dione oligothiophenes (OTPDn), from the monomer to hexamer, is reported. The optical and structural properties in the neutral states have been analyzed by absorption and emission spectroscopy together with vibrational Raman spectroscopy. In their reduced forms, these molecules could stabilize both anions and dianions in similar ways. For the dianions, two...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018

 


Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald
A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli
Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview]
ChemBioChem 2018

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Klaus Roth
Die Suche nach dem Blau der „Blauen Blume“ [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 192

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov
Leone Spiccia Memorial Issue [Editorial]
ChemPlusChem 2018, vol. 83, p. 548

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko
Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review]
ChemNanoMat 2018, vol. 4, p. 598

R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius
DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication]
Chem. Eur. J. 2018

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan
Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper]
ChemMedChem 2018

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber
Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article]
ChemPhotoChem 2018

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu
Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview]
Eur. J. Org. Chem. 2018, p. 2301

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Markus Hiebel, Katharina Reh
Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 606

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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