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Angewandte Chemie International Edition

ORCHEM Prizes for Ivana Fleischer and Florian Beuerle / Emil Fischer Medal for Thorsten Bach / Leonidas Zervas Award for Christian P. R. Hackenberger / Hanwha‐Total IUPAC Young Scientist Award for Andreas Walther / Thieme–IUPAC Prize for Seth Herzon / Greifswald Research Award for Uwe T. Bornscheuer / Melvin Calvin Award for Troels Skrydstrup

Published: 17 August 2018

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Chemistry - A European Journal

Highly Efficient Encapsulation and Phase Separation of Apolar Molecules by Magnetic Shell‐by‐Shell‐Coated Nanocarriers in Water

Published: 17 August 2018

Author(s): Tobias Luchs, Marco Sarcletti, Lukas Zeininger, Luis Portilla, Christian Fischer, Sjoerd Harder, Marcus Halik, Andreas Hirsch

Abstract We report on the development of a supramolecular nanocarrier concept that allows for the encapsulation and separation of small apolar molecules from water. The nanocarriers consist of shell‐by‐shell‐coated nanoparticles such as TiO2 and ferromagnetic Fe3O4. The first ligand shell is provided by covalently bound hexadecyl phosphonic acid (PAC16) and the second shell by noncovalently assembled amphiphiles rendering the hybrid architecture soluble in...

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Angewandte Chemie International Edition

Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X‐ray Nanospectroscopy

Published: 17 August 2018

Author(s): Ilse K. van Ravenhorst, Charlotte Vogt, Heiko Oosterbeek, Koen W. Bossers, José G. Moya‐Cancino, Alexander P. van Bavel, Ad M. J. van der Eerden, David Vine, Frank M. F. de Groot, Florian Meirer, Bert M. Weckhuysen

Abstract A state‐of‐the‐art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced by Fischer–Tropsch catalysis. This allows determination of, at a spatial resolution of approximately 50 nm, the interdependence of formed hydrocarbon species in the inorganic catalyst. Observed trends show intra‐ and interparticular heterogeneities previously believed not to...

Phytotherapy Research

Liquorice ( Glycyrrhiza glabra ): A phytochemical and pharmacological review

Published: 17 August 2018

Author(s): Giulia Pastorino, Laura Cornara, Sónia Soares, Francisca Rodrigues, M. Beatriz P.P. Oliveira

In the last years, consumers are paying much more attention to natural medicines and principles, mainly due to the general sense that natural compounds are safe. On the other hand, there is a growing demand by industry for plants used in traditional medicine that could be incorporated in foods, nutraceuticals, cosmetics, or even pharmaceuticals. Glycyrrhiza glabra Linn. belongs to the Fabaceae family and has been recognized since ancient times for...

Angewandte Chemie International Edition

Jishan Wu

Published: 17 August 2018

British Journal of Clinical Pharmacology

Gadolinium deposition and the potential for toxicological sequelae – A literature review of issues surrounding gadolinium‐based contrast agents

Published: 17 August 2018

Author(s): Kerry A. Layne, Paul I. Dargan, John R. H. Archer, David M. Wood

Every year, approximately 30 million magnetic resonance imaging scans are enhanced with gadolinium‐based contrast agents (GBCAs) worldwide. Although the development of nephrogenic systemic fibrosis in patients with renal impairment is well‐documented, over recent years it has become apparent that exposure to GBCAs can potentially result in gadolinium deposition within human bone and brain tissue even in the presence of normal renal...

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Angewandte Chemie

Yujie Xiong

Published: 17 August 2018

European Journal of Organic Chemistry

Cleavage of C–C and C–O Bonds to Form C–C Bonds: Direct Cross‐Coupling between Acetylenic Alcohols and Benzylic Carbonates

Published: 17 August 2018

Author(s): Zhiyuan Mi, Jiahao Tang, Zhipeng Guan, Wei Shi, Hao Chen

A palladium‐catalyzed cross‐coupling reaction between C(sp) and C(sp3) centers was achieved in excellent yields via C–C bond cleavage and C–O bond cleavage. This procedure uses relatively stable acetylenic alcohols as reactants instead of unstable/volatile terminal alkynes. The use of benzylic carbonates also avoids the involvement of benzyl halides, making this method more practical in synthesis. Ligands play an important role in the procedure ...

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Chemistry - A European Journal

Regio‐ and Stereoselective Synthesis of Bicyclic Limonene‐Based Chiral Aminodiols and Spirooxazolidines

Published: 17 August 2018

Author(s): Tam Minh Le, Antal Csámpai, Ferenc Fülöp, Zsolt Szakonyi

Abstract A library of monoterpene‐based aminodiols was synthesized and applied as chiral catalysts in the addition of diethylzinc to benzaldehyde. The reduction of a bicyclic α‐methylene ketone, derived from natural (−)‐limonene followed by epoxidation, gave the key epoxy alcohol intermediate. Ring opening of the oxirane ring with primary amines induced by lithium perchlorate afforded the required aminodiols. Substituent‐dependent...

European Journal of Organic Chemistry

Aminodecalone Scaffolds – Enantioselective Synthesis, Indole and Quinoline Annulation

Published: 17 August 2018

Author(s): Benjamin Schäfer, Marc Schmidtmann, Jens Christoffers

Optically active benzo[b]carbazole and benzo[b]acridine derivatives were prepared by Fischer indole or Friedländer quinoline annulation from 2‐oxodecalone‐4a‐carboxylates with a quaternary stereocenter. As an additional point for diversification, the target compounds carry a nitro function, which was transformed to an amide or lactam after reduction. The scaffold itself was accessed by asymmetric, copper catalyzed Michael reaction of a...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

June 2018


	Saki Ichikawa, Shaolin Zhu, Stephen L. Buchwald A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination [Communication] Angew. Chem. Int. Ed. 2018, vol. 57, p. 8714

	Parker Nichols, Alexandra Born, Morkos Henen, Dean Strotz, Celestine N Chi, Peter Güntert, Beat Rolf Vögeli Extending the Applicability of Exact Nuclear Overhauser Enhancements to Large Proteins and RNA [Minireview] ChemBioChem 2018

	Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper] ChemCatChem 2011, vol. 3, p. 1159

	Klaus Roth Die Suche nach dem Blau der „Blauen Blume“ [Artikel] Chem. Unserer Zeit 2018, vol. 52, p. 192

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, p. 401

	Philip C. Andrews, Lisandra L. Martin, Alexandr N. Simonov Leone Spiccia Memorial Issue [Editorial] ChemPlusChem 2018, vol. 83, p. 548

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, p. 6055

	Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen Regulatory Aspects of Nanomaterials in the EU [Research Article] Chem. Ing. Tech. 2017, vol. 89, p. 224

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, p. 75

	Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review] ChemElectroChem 2018, vol. 5, p. 6

	Santosh K. Tiwari, Raghvendra Kumar Mishra, Sung Kyu Ha, Andrzej Huczko Evolution of Graphene Oxide and Graphene: From Imagination to Industrialization [Focus Review] ChemNanoMat 2018, vol. 4, p. 598

	R. Aleyda Garza-Sanchez, Tuhin Patra, Adrian Tlahuext-Aca, Felix Strieth-Kalthoff, Frank Glorius DMSO as a Switchable Alkylating Agent in Heteroarene C−H Functionalization [Communication] Chem. Eur. J. 2018

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, p. 2696

	Yunhe Jin, Hua Fu Visible-Light Photoredox Decarboxylative Couplings [Focus Review] Asian J. Org. Chem. 2017, vol. 6, p. 368

	Christopher J Matheson, Kimberly A Casalvieri, Donald S Backos, Philip Reigan Development of potent pyrazolopyrimidinone-based WEE1 inhibitors with limited single-agent cytotoxicity for cancer therapy [Full Paper] ChemMedChem 2018

	Gloria Tabacchi Supramolecular Organization in Confined Nanospaces [Review] ChemPhysChem 2018, vol. 19, p. 1249

	Emily B. Corcoran, François Lévesque, Jonathan P. McMullen, John R. Naber Studies Toward the Scaling of Gas-Liquid Photocycloadditions [Article] ChemPhotoChem 2018

	An-Na Cho, Nam-Gyu Park Impact of Interfacial Layers in Perovskite Solar Cells [Review] ChemSusChem 2017, vol. 10, p. 3687

	Ross J. Marshall, Ross S. Forgan Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview] Eur. J. Inorg. Chem. 2016, p. 4310

	Romaric Gérardy, Noémie Emmanuel, Thomas Toupy, Victor-Emmanuel Kassin, Nelly Ntumba Tshibalonza, Michaël Schmitz, Jean-Christophe M. Monbaliu Continuous Flow Organic Chemistry: Successes and Pitfalls at the Interface with Current Societal Challenges [Microreview] Eur. J. Org. Chem. 2018, p. 2301

	46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung] Lebensmittelchemie 2018, vol. 72, p. 1

	Markus Hiebel, Katharina Reh Kreislaufwirtschaft: Von Anfang an ans Ende denken [Industrie & Technik] Nachr. Chem. 2018, vol. 66, p. 606

	Alexander Engl, Alexandra Schmelzer, Björn Risch Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel] CHEMKON 2018, vol. 25, p. 7

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2016


	Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

	Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke Fluorescent Probes for G-Quadruplex Structures [Review] ChemBioChem 2013, vol. 14, pp. 540–558

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Marc Steinmetz, Stefan Grimme Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper] ChemistryOpen 2013, vol. 2, pp. 115–124

	Philipp Scharf, Jens Müller Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review] ChemPlusChem 2013, vol. 78, pp. 20–34

	Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess Production of Liquid Hydrocarbons with CO₂ as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article] Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper] Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chem. Asian J. 2014, vol. 9, pp. 26–47

	Naohiko Yoshikai, Ye Wei Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review] Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

	Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper] ChemMedChem 2013, vol. 8, pp. 313–321

	Peter Politzer, Jane S. Murray Halogen Bonding: An Interim Discussion [Review] ChemPhysChem 2013, vol. 14, pp. 278–294

	Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review] ChemSusChem 2013, vol. 6, pp. 746–789

	Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou Spin Crossover at the Nanometre Scale [Microreview] Eur. J. Inorg. Chem. 2013, pp. 653–661

	Junichiro Yamaguchi, Kei Muto, Kenichiro Itami Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview] Eur. J. Org. Chem. 2013, pp. 19–30

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941