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Energy Technology

Hydrogen Productivity Analysis Using Low Concentration of TiO2–Au Nanoparticles on a Ultraviolet‐LED‐Based Photocatalytic Reactors

Published: 25 November 2021

Author(s): Felipe Varas-Concha, Diego Guzmán, Mauricio Isaacs, César Sáez-Navarrete

The productivity of photocatalytic hydrogen generation via photo‐reforming of organic compounds has not been studied under low concentrations of catalyst, which could lead to relevant cost savings in future real‐scale applications. Herein, it uses half of the lowest concentration of nanoparticles reported of modified P25 TiO2 partially coated with gold. The nanomaterial is prepared using a non‐energy intensive, chemical reduction method. Gold content on the TiO2 surface is reported...

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Angewandte Chemie

A Defective Nanotube Molecule of C552H496N24 with Pyridinic and Pyrrolic Nitrogen Atoms

Published: 25 November 2021

Author(s): Koki Ikemoto, Shotaro Harada, Seungmin Yang, Taisuke Matsuno, Hiroyuki Isobe

Abstract A 3‐nm molecule comprising a cylindrical core and cross‐shaped rims was designed and synthesized by developing a modular synthetic route. By using a cyclic precursor from previous studies as a starting material, multiple carbazole units were installed at the rims of the defective cylinder. The defective cylinder was synthetically doped with two types of nitrogen atoms, that is, pyridinic and pyrrolic nitrogen atoms, which resulted in solvatochromic shifts in fluorescence by...

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Angewandte Chemie

Fangfang Zhang

Published: 25 November 2021

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Angewandte Chemie International Edition

Fangfang Zhang

Published: 25 November 2021

thumbnail image: Angewandte Chemie International Edition


Protonated Ethylene Carbonate: A Highly Resonance‐Stabilized Cation

Published: 25 November 2021

Author(s): Stefanie Beck, Christoph Jessen, Andreas J. Kornath

Abstract Invited for this month's cover picture is the group of Prof. Andreas J. Kornath at the LMU in Munich (Germany). The cover picture shows the crystal structure of the salt of protonated ethylene carbonate [C3H5O3][Sb2F11]. Protonated ethylene carbonate was synthesized by reacting the neutral compound in the superacidic system HF/SbF5 at low temperature. Interestingly, the single‐crystal X‐ray structure analysis revealed a planar CO3 moiety with nearly equal CO bond lengths. Further...

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Angewandte Chemie International Edition

Supernova: A Deoxyribozyme that Catalyzes a Chemiluminescent Reaction

Published: 25 November 2021

Author(s): Katerina Svehlova, Ondřej Lukšan, Martin Jakubec, Edward A. Curtis

Abstract Functional DNA molecules are useful components in nanotechnology and synthetic biology. To expand the toolkit of functional DNA parts, in this study we used artificial evolution to identify a glowing deoxyribozyme called Supernova. This deoxyribozyme transfers a phosphate from a 1,2‐dioxetane substrate to its 5′ hydroxyl group, which triggers a chemiluminescent reaction and a flash of blue light. An engineered version of Supernova is only catalytically active in the presence of an...

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Angewandte Chemie International Edition

Two‐Dimensional Fluorinated Covalent Organic Frameworks with Tunable Hydrophobicity for Ultrafast Oil–Water Separation

Published: 25 November 2021

Author(s): Yuhao Liu, Wei Li, Chen Yuan, Lei Jia, Yan Liu, Aisheng Huang, Yong Cui

Abstract Covalent organic frameworks (COFs) hold great potentials for addressing the challenge of highly efficient oil–water separation, but they are restricted by the poor wettability and processability as crystalline membranes. Here we report the design and synthesis of two‐dimensional (2D) robust COFs with controllable hydrophobicity and processability, allowing the COF layers to be directly grown on the support surfaces. Three 2D COFs with AA or ABC stacking are prepared by condensation of...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Intrinsically Disordered Tardigrade Proteins Self‐Assemble into Fibrous Gels in Response to Environmental Stress

Published: 25 November 2021

Author(s): Anas Malki, Jean‐Marie Teulon, Aldo R. Camacho‐Zarco, Shu‐wen W. Chen, Wiktor Adamski, Damien Maurin, Nicola Salvi, Jean‐Luc Pellequer, Martin Blackledge

Abstract Tardigrades are remarkable for their ability to survive harsh stress conditions as diverse as extreme temperature and desiccation. The molecular mechanisms that confer this unusual resistance to physical stress remain unknown. Recently, tardigrade‐unique intrinsically disordered proteins have been shown to play an essential role in tardigrade anhydrobiosis. Here, we characterize the conformational and physical behaviour of CAHS‐8 from Hypsibius exemplaris. NMR spectroscopy reveals...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie International Edition

Clip‐off Chemistry: Synthesis by Programmed Disassembly of Reticular Materials**

Published: 25 November 2021

Author(s): Yunhui Yang, Anna Broto‐Ribas, Borja Ortín‐Rubio, Inhar Imaz, Felipe Gándara, Arnau Carné‐Sánchez, Vincent Guillerm, Sergio Jurado, Félix Busqué, Judith Juanhuix, Daniel Maspoch

Abstract Bond breaking is an essential process in chemical transformations and the ability of researchers to strategically dictate which bonds in a given system will be broken translates to greater synthetic control. Here, we report extending the concept of selective bond breaking to reticular materials in a new synthetic approach that we call Clip‐off Chemistry. We show that bond‐breaking in these structures can be controlled at the molecular level; is periodic, quantitative, and selective;...

thumbnail image: Angewandte Chemie International Edition

Angewandte Chemie

Geomimetic Hydrothermal Synthesis of Polyimide‐Based Covalent Organic Frameworks

Published: 25 November 2021

Author(s): Taehyung Kim, Se Hun Joo, Jintaek Gong, Sungho Choi, Ju Hong Min, Yongchul Kim, Geunsik Lee, Eunji Lee, Soojin Park, Sang Kyu Kwak, Hee‐Seung Lee, Byeong‐Su Kim

Abstract Despite its abundance, water is not widely used as a medium for organic reactions. However, under geothermal conditions, water exhibits unique physicochemical properties, such as viscosity and a dielectric constant, and the ionic product become similar to those of common organic solvents. We have synthesized highly crystalline polyimide‐based covalent organic frameworks (PICs) under geomimetic hydrothermal conditions. By exploiting triphenylene‐2,3,6,7,10,11‐hexacarboxylic acid in...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

October 2021


Fang Zhang, Juewen Liu
Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review]
Anal. Sens. 2021, vol. 1, no. 1, p. 30

Rola Houhou, Thomas Bocklitz
Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review]
Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128

Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster
High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article]
Batteries Supercaps 2021, vol. 4, no. 6, p. 934

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Keita Sakamoto, Akihiro Hakamata, Arihiro Iwasaki, Kiyotake Suenaga, Masashi Tsuda, Haruhiko Fuwa
Cover Feature: Total Synthesis, Stereochemical Revision, and Biological Assessment of Iriomoteolide-2a (Chem. Eur. J. 36/2019) [Cover Picture]
Chem. Eur. J. 2019, vol. 25, no. 36, p. 8429

Guilherme L. Tripodi, Max T. G. M. Derks, Floris P. J. T. Rutjes, Jana Roithová
Tracking Reaction Pathways by a Modular Flow Reactor Coupled to Electrospray Ionization Mass Spectrometry [Cover Profile]
Chemistry–Methods 2021, vol. 1, no. 10, p. 428

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors [Communication]
ChemPhotoChem 2021, vol. 5, no. 9, p. 808

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Francesco Bisconti, Antonella Giuri, Gianluigi Marra, Alberto Savoini, Paolo Fumo, Rosamaria Marrazzo, Stefano Zanardi, Gianni Corso, Riccardo Po, Paolo Biagini, Eleonora Quadrivi, Riikka Suhonen, Thomas M. Kraft, Mari Ylikunnari, Andrea Listorti, Carola Esposito Corcione, Silvia Colella, Aurora Rizzo
Polymer-Assisted Single-Step Slot-Die Coating of Flexible Perovskite Solar Cells at Mild Temperature from Dimethyl Sulfoxide [Full Paper]
ChemPlusChem 2021, vol. 86, no. 10, p. 1442

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Saheed E. Elugoke, Abolanle S. Adekunle, Omolola E. Fayemi, Ekemini D. Akpan, Bhekie B. Mamba, El-Sayed M. Sherif, Eno E. Ebenso
Molecularly imprinted polymers (MIPs) based electrochemical sensors for the determination of catecholamine neurotransmitters - Review [REVIEW]
Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2000026

Mauricio Cattaneo, Giovanny A. Parada, Adam L. Tenderholt, Werner Kaminsky, James M. Mayer
Structural, Electronic, and Thermochemical Preference for Multi-PCET Reactivity of Ruthenium(II)-Amine and Ruthenium(IV)-Amido Complexes [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 4066

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Michael C. Willis, Edward J. Emmett
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review]
Asian J. Org. Chem. 2015, vol. 4, no. 7, p. 602

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

B. Lilli Neumeier, Mikhail Khorenko, Frauke Alves, Oliver Goldmann, Joanna Napp, Ute Schepers, Holger M. Reichardt, Claus Feldmann
Fluorescent Inorganic-Organic Hybrid Nanoparticles [Focus Review]
ChemNanoMat 2019, vol. 5, no. 1, p. 24

Xiaoye Yu, Constantin G. Daniliuc, Fatmah Ali Alasmary, Armido Studer
Direct Access to α-Aminosilanes Enabled by Visible-Light-Mediated Multicomponent Radical Cross-Coupling [Research Article]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 43, p. 23335

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Manami Ishida, Dieter Weiß
Blausäure im Haushalt [Magazin]
Chem. Unserer Zeit 2021, vol. 55, no. 5, p. 359

Digitalisierung nach der Pandemie [Editorial]
CHEMKON 2021, vol. 28, no. 6, p. 234

Cover Picture Lebensmittelchemie 5/2021 [Cover Picture]
Lebensmittelchemie 2021, vol. 75, no. 5

Sonja Herres-Pawlis, Johannes Liermann
Den Datenschatz endlich heben [Leitartikel]
Nachr. Chem. 2021, vol. 69, no. 10, p. 3

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH