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European Journal of Inorganic Chemistry

Synthesis, Structure, and Oxidative Reactivity of a Class of Thiolate‐Bridged Dichromium Complexes Featuring Antiferromagnetic Coupling Interactions

Published: 15 January 2021

Author(s): Jingping Qu, Baomin Wang, Yixin Zhang, Dawei Yang, Nianmin Wei

Abstract Several thiolate‐bridged dichromium complexes with Cp* (Cp*=η5‐C5Me5) as auxiliary ligands were designed and synthesized through the salt metathesis, which all contain two six‐coordinate chromium centers in the formal valence of +3. These complexes are all paramagnetic species, which are in good agreement with the experimental results that broad and paramagnetically shifted proton resonances appear in the 1H NMR spectra. Furthermore, variable‐temperature solid‐state magnetic...

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ChemPhysChem

Enhanced Nanostructure Dynamics on Au(111) with Adsorbed Sulfur due to Au−S Complex Formation

Published: 15 January 2021

Author(s): Patricia A. Thiel, James W. Evans, Theresa L. Windus, Da‐Jiang Liu, Peter M. Spurgeon

Abstract Chemisorbed species can enhance the fluxional dynamics of nanostructured metal surfaces which has implications for applications such as catalysis. Scanning tunneling microscopy studies at room temperature reveal that the presence of adsorbed sulfur (S) greatly enhances the decay rate of 2D Au islands in the vicinity of extended step edges on Au(111). This enhancement is already significant at S coverages, θS, of a few hundredths of a monolayer (ML), and is most pronounced for...

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ChemPhysChem

Metalation of 2HTCNPP on Ag(111) with Zn: Evidence for the Sitting atop Complex at Room Temperature

Published: 15 January 2021

Author(s): Jan Kuliga, Rodrigo Cezar Campos Ferreirra, Rajan Adhikari, Stephen Massicot, Michael Lepper, Helen Hölzel, Norbert Jux, Hubertus Marbach., Abner Siervo, Hans‐Peter Steinrück

Abstract We study the interaction and metalation reaction of a free base 5,10,15,20‐terakis(4‐cyanophenyl)porphyrin (2HTCNPP) with post‐deposited Zn atoms and the targeted reaction product Zn‐5,10,15,20‐terakis(4‐cyanophenyl)porphyrin (ZnTCNPP) on a Ag(111) surface. The investigations are performed with scanning tunneling microscopy at room temperature after Zn deposition and subsequent heating. The goal is to obtain further insights in the metalation reaction and the influence of the...

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ChemCatChem

Activating CoMoS with CoP3 Phase for High‐efficient Hydrogen Evolution Reaction in Acidic Condition

Published: 15 January 2021

Author(s): Yunmei Du, Wensi Wang, Huimin Zhao, Xianliang Jiang, Yanru Liu, Ruixin Chen, Bo Yang, Lei Wang

Abstract Currently, the construction of heterostructures to optimize electrocatalytic activities is a hot research topic, since there is still a certain gap between the electrocatalytic properties of these heterostructures and that of Pt/C. With this in mind, we utilized in‐situ vapor‐phase phosphorization‐sulfurization to obtain the CoP3/MoS2−Co0.75Mo3S3.75 (CoP/CoMoS, for short) heterostructure on carbon cloth (CC), which exhibits Pt‐like electrocatalytic performance and excellent stability...

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ChemPhysChem

Ultrastrong Regulation Effect of the Electric Field on the All‐Carboatomic Ring Cyclo[18]Carbon**

Published: 15 January 2021

Author(s): Tian Lu, Qinxue Chen

Abstract Cyclo[18]carbon has a very unique geometry and electronic structure. We found that an external electric field (EEF) has an ultrastrong regulation effect on various aspects of the cyclo[18]carbon: (1) The EEF makes the shape of the cyclo[18]carbon change from a circle to an oval, the elongation is particularly striking at a large EEF magnitude. (2) The EEF causes a huge polarization of distribution of in‐plane π electrons, and strong EEF can even make some of the electrons detached...

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ChemMedChem

Design and Synthesis of DDR1 Inhibitors with a Desired Pharmacophore Using Deep Generative Models

Published: 15 January 2021

Author(s): Atsushi Yoshimori, Yasunobu Asawa, Enzo Kawasaki, Tomohiko Tasaka, Seiji Matsuda, Toru Sekikawa, Satoshi Tanabe, Masahiro Neya, Hideaki Natsugari, Chisato Kanai

Abstract Discoidin domain receptor 1 (DDR1) inhibitors with a desired pharmacophore were designed using deep generative models (DGMs). DDR1 is a receptor tyrosine kinase activated by matrix collagens and implicated in diseases such as cancer, fibrosis and hypoxia. Herein we describe the synthesis and inhibitory activity of compounds generated from DGMs. Three compounds were found to have sub‐micromolar inhibitory activity. The most potent of which, compound 3...

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Chemistry - A European Journal

Self‐Assembled Two‐Dimensional NiO/CeO2 Heterostructure Rich in Oxygen Vacancies as Efficient Bifunctional Electrocatalyst for Alkaline Hydrogen Evolution and Oxygen Evolution

Published: 15 January 2021

Author(s): Yan Zhang, Fei Ye, Wei‐Dong Z. Li

Abstract The development of high‐efficiency bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline surroundings is essential and challenging for the large‐scale generation of clean hydrogen. Herein, a novel self‐assembled two‐dimensional (2 D) NiO/CeO2 heterostructure (HS) consisting of NiO and CeO2 nanocrystals is prepared through a facile two‐step approach, and utilized as an enhanced bifunctional electrocatalyst for the HER...

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ChemMedChem

Dual‐Mechanism Quenched Fluorogenic Probe Provides Selective and Rapid Detection of Cathepsin L Activity**

Published: 15 January 2021

Author(s): Kelton A. Schleyer, Ben Fetrow, Peter Zannes Fatland, Jun Liu, Maya Chaaban, Biwu Ma, Lina Cui

Abstract Cathepsin L (CTL) is a cysteine protease demonstrating upregulated activity in many disease states. Overlapping substrate specificity makes selective detection of CTL activity difficult to parse from that of its close homologue CTV and the ubiquitous CTB. Current probes of CTL activity have limited applications due to either poor contrast or extra assay steps required to achieve selectivity. We have developed a fluorogenic probe, CTLAP, that displays good selectivity for CTL over CTB...

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ChemPhysChem

Chlorophyll a π‐Cation Radical as Redox Mediator in Superoxide Dismutase (SOD) Mimetics

Published: 15 January 2021

Author(s): Łukasz Orzeł, Dorota Rutkowska‐Zbik, Rudi Eldik, Leszek Fiedor, Grażyna Stochel

Abstract The extensive speciation of copper(II) chloride in organic solvents varies with concentration, temperature, pressure and oxygen content, providing the ability to switch between different chlorophyll transmetalation pathways. We found that one of them is exceptionally suitable for the formation and stabilisation of the chlorophyll π‐cation radical. This is due to unique redox cycling, which is coupled to the generation and transformation of various reactive oxygen species. In the...

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ChemCatChem

Electrocatalytic Nitrogen Reduction Performance of Si‐doped 2D Nanosheets of Boron Nitride Evaluated via Density Functional Theory

Published: 15 January 2021

Author(s): Zhongyuan Guo, Siyao Qiu, Huan Li, Yongjun Xu, Steven J. Langford, Chenghua Sun

Abstract Electrochemical nitrogen fixation under ambient conditions is proposed as a sustainable alternative to the traditional Haber‐Bosch method to combat both a global energy crisis and climate change. However, effective catalysts for electrocatalytic nitrogen reduction reaction (eNRR) under ambient conditions, a crucial part for the electrocatalysis system, still face large challenges of low Faradic efficiency (FE) and low yield of ammonia. Here, we propose Si‐doped BN 2D nanosheets (BNNS)...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

November 2020

 


A. L. Santhosha, Lukas Medenbach, Johannes R. Buchheim, Philipp Adelhelm
The Indium−Lithium Electrode in Solid-State Lithium-Ion Batteries: Phase Formation, Redox Potentials, and Interface Stability [Article]
Batteries & Supercaps 2019, vol. 2, no. 6, p. 524

Merel A. T. Plassche, Marta Barniol-Xicota, Steven H. L. Verhelst
Front Cover: Peptidyl Acyloxymethyl Ketones as Activity-Based Probes for the Main Protease of SARS-CoV-2 (ChemBioChem 23/2020) [Cover Picture]
ChemBioChem 2020, vol. 21, no. 23, p. 3289

Michael Bowker
Methanol Synthesis from CO2 Hydrogenation [Minireview]
ChemCatChem 2019, vol. 11, no. 17, p. 4238

Yuvraj Y. Birdja, Jan Vaes
Towards a Critical Evaluation of Electrocatalyst Stability for CO2 Electroreduction [Viewpoint]
ChemElectroChem 2020, vol. 7, no. 23, p. 4713

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, no. 5, p. 386

Thomas G. Mayerhöfer, Alicja Dabrowska, Andreas Schwaighofer, Bernhard Lendl, Jürgen Popp
Beyond Beer's Law: Why the Index of Refraction Depends (Almost) Linearly on Concentration [Communication]
ChemPhysChem 2020, vol. 21, no. 8, p. 707

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Changxiang Shao, Yang Zhao, Liangti Qu
Tunable Graphene Systems for Water Desalination [Minireview]
ChemNanoMat 2020, vol. 6, no. 7, p. 1028

Tobias P. Haider, Carolin Völker, Johanna Kramm, Katharina Landfester, Frederik R. Wurm
Plastics of the Future? The Impact of Biodegradable Polymers on the Environment and on Society [Minireview]
Angew. Chem. Int. Ed. 2019, vol. 58, no. 1, p. 50

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, no. 3, p. 224

Henrik Petersen, Klaus Roth
To Tattoo or not to Tattoo [Artikel]
Chem. Unserer Zeit 2016, vol. 50, no. 1, p. 44

Regine Herbst-Irmer, Erhard Irmer
Titelbild: Chemische Bindungen experimentell sichtbar machen (CHEMKON 6/2020) [Titelbild]
CHEMKON 2020, vol. 27, no. 6, p. 263

Massenspektrometrie — Eine Einführung von Herbert Budzikiewicz und Mathias Schäfer [Buchbesprechung]
Lebensmittelchemie 2013, vol. 67, no. 2, p. 56

Brigitte Osterath, Eliza Leusmann, Frauke Zbikowski
Biochemikerin trifft Mikrobiologin [Bildung + Gesellschaft]
Nachr. Chem. 2020, vol. 68, no. 11, p. 8

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH