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European Journal of Organic Chemistry

Metal‐Catalyzed Cyclization: Synthesis of (Benzo)morpholines and (Benzo)[1,4]dihydrooxazines

Published: 13 November 2019

Author(s): Thomas Aubineau, Janine Cossy

A review of the most recent metal‐catalyzed cyclizations to access morpholines and their unsaturated derivatives, from 1993 to 2019, is reported. The review is organized according to the bond(s) formed during the process. Special importance has been given to the mechanistic details of the reactions.

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European Journal of Inorganic Chemistry

N‐Heterocyclic Carbene Platinum Complexes: A Big Step Forward for Effective Antitumor Compounds

Published: 13 November 2019

Author(s): Stéphane Bellemin‐Laponnaz

The discovery of cisplatin is an important milestone in the history of successful anticancer drugs. This is also a notable example of the translational scientific achievement that remains a driving force in multidisciplinary research. The clinical success of cisplatin has led chemists to vary the ligands around the platinum metal to improve cisplatin's effectiveness while reducing its side effects. While there have been more failures than successes, key developments in the elucidation of...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe3] with SF4 or Me3SnF

Published: 13 November 2019

Author(s): Thomas Braun, Erhard Kemnitz, Pooja Tomar

Various reaction routes have been developed to synthesize the N‐heterocyclic carbene (NHC) stabilized Al(III) fluorides [(SIMes)Al(F)3] (2) and [(SIMes)Al(F)Me2] (3) through fluorination of [(SIMes)AlMe3] (1) (SIMes: 1,3‐bis(2,4,6‐trimethylphenyl)‐imidazolidin‐2‐ylidene) with fluorinating agents such as SF4, SF6 and Me3SnF. The reactivity of 2 was investigated towards a F/Cl exchange reaction by treating it with Me3SiCl.

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ChemBioChem

Engineering of a Red Fluorogenic Protein/Merocyanine Complex for Live‐Cell Imaging

Published: 13 November 2019

Author(s): Elizabeth M. Santos, Tetyana Berbasova, Wenjing Wang, Rahele Esmatpour Salmani, Wei Sheng, Chrysoula Vasileiou, James H. Geiger, Babak Borhan

Abstract A reengineered human cellular retinol binding protein II (hCRBPII), a 15‐kDa protein belonging to the intracellular lipid binding protein (iLBP) family, generates a highly fluorescent red pigment through the covalent linkage of a merocyanine aldehyde to an active site lysine residue. The complex exhibits “turn‐on” fluorescence, due to a weakly fluorescent aldehyde that “lights up” with subsequent formation of a strongly fluorescent merocyanine dye within the binding pocket of the...

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ChemMedChem

Synthesis of Combretastatin‐A4 Carboxamidest that Mimic Sulfonyl Piperazines by a Molecular Hybridization Approach: in vitro Cytotoxicity Evaluation and Inhibition of Tubulin Polymerization

Published: 13 November 2019

Author(s): Chetna Jadala, Manda Sathish, Pratibha Anchi, Ramya Tokala, Uppu Jaya Lakshmi, Velma Ganga Reddy, Nagula Shankaraiah, Chandraiah Godugu, Ahmed Kamal

Abstract Molecular hybridization approach is a promising structural modification tool to design new chemical entities (NCEs) by mimicking two different pharmacophoric units into one scaffold to enhance the biological properties. With this aim, combretastatin‐A4 acids were integrated with sulfonyl piperazine scaffolds as a one molecular platform and evaluated for their in vitro antiproliferative activity against a panel of human cancer lines cell lines namely, lung (A549), mouse melanoma...

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European Journal of Inorganic Chemistry

Amine‐Functionalized Spin Crossover Building Blocks

Published: 13 November 2019

Author(s): Henrik Flötotto, Tim Secker, Paul Kögerler, Claire Besson

Abstract Invited for the cover of this issue is the group of Paul Kögerler from RWTH Aachen University, Germany. The cover image shows an aluminum sheet painted with thermochromic lacquer based on functionalized derivatives of iron(II) bis(tris(pyrazolyl)borate) complexes.

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Metallo‐Corroles Supported on Carbon Nanostructures as Oxygen Reduction Electrocatalysts in Neutral Media

Published: 13 November 2019

Author(s): Michele Raggio, Barbara Mecheri, Sara Nardis, Alessandra D'Epifanio, Silvia Licoccia, Roberto Paolesse

In this work, we report the investigation of Fe and Co triphenylcorrole complexes supported on two different carbon supports as eletrocatalysts for the ORR in neutral pH media, comparing their performances with the corresponding tetraphenylporphyrin complexes. Cyclic voltammetry experiments were acquired in neutral phosphate buffer demonstrating that corroles exhibit a superior catalytic activity towards ORR than porphyrins, as demonstrated by more positive oxygen reduction peak potential...

thumbnail image: European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Front Cover: Amine‐Functionalized Spin Crossover Building Blocks (Eur. J. Inorg. Chem. /2019)

Published: 13 November 2019

Author(s): Henrik Flötotto, Tim Secker, Paul Kögerler, Claire Besson

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Chemistry - A European Journal

Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations

Published: 13 November 2019

Author(s): Philipp S. Steinlandt, Wei Zuo, Klaus Harms, Eric Meggers

Abstract A new class of bis‐cyclometalated rhodium(III) catalysts containing two inert cyclometalated 6‐tert‐butyl‐2‐phenyl‐2H‐indazole ligands and two labile acetonitriles is introduced. Single enantiomers ( 99 % ee) were obtained through a chiral‐auxiliary‐mediated approach using a monofluorinated salicyloxazoline. The new chiral‐at‐metal complex is capable of catalyzing the visible‐light‐induced enantioselective α‐cyanoalkylation of 2‐acyl imidazoles in which it serves a dual function as...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Consecutive Supramolecular Polymerization of a Rylene‐Based Twistacene

Published: 13 November 2019

Author(s): Manuel A. Martínez, Elisa E. Greciano, Luis Sánchez

Abstract The synthesis and self‐assembling features of twistacene 1 are reported. The supramolecular polymerization of 1 displays a consecutive pathway to afford slipped (AggI) and rotationally displaced (AggII) aggregates conditioned by the formation of intramolecularly H‐bonded pseudocycles. In methylcyclohexane, both AggI and AggII are highly stable and the interconversion of the kinetically controlled AggI into the thermodynamically controlled AggII takes several weeks to occur. The...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

August 2019

 


Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless
Click Chemistry: Diverse Chemical Function from a Few Good Reactions [Review]
Angew. Chem. Int. Ed. 2001, vol. 40, no. 11, p. 2004

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Petra E. de Jongh, Deryn E. Fogg, Li-Zhu Wu, Sandra González-Gallardo
Meet the Women of Catalysis [Editorial]
ChemCatChem 2019, vol. 11, no. 16, p. 3557

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Rainer Stosch, Olaf Rienitz, Axel Pramann, Bernd Güttler
Wie viele Moleküle enthält ein Mol? [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 4, p. 256

Benjamin A. E. Lehner, Vera A. E. C. Janssen, Ewa M. Spiesz, Dominik Benz, Stan J. J. Brouns, Anne S. Meyer, Herre S. J. van der Zant
Creation of Conductive Graphene Materials by Bacterial Reduction Using Shewanella Oneidensis [Full Paper]
ChemistryOpen 2019, vol. 8, no. 7, p. 888

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, no. 7, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Michael C. Zimmermann, Thomas N. Otto, Simon Wodarz, Thomas A. Zevaco, Stephan Pitter
Mesoporous H-ZSM-5 for the Conversion of Dimethyl Ether to Hydrocarbons [Research Article]
Chem. Ing. Tech. 2019, vol. 91, no. 9, p. 1302

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Andrey Shatskiy, Helena Lundberg, Markus D. Kärkäs
Organic Electrosynthesis: Applications in Complex Molecule Synthesis [Review]
ChemElectroChem 2019, vol. 6, no. 16, p. 4067

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

João M. J. M. Ravasco, Hélio Faustino, Alexandre Trindade, Pedro M. P. Gois
Bioconjugation with Maleimides: A Useful Tool for Chemical Biology [Review]
Chem. Eur. J. 2019, vol. 25, no. 1, p. 43

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

Adrian G. Amador, Evan M. Sherbrook, Tehshik P. Yoon
A Redox Auxiliary Strategy for Pyrrolidine Synthesis via Photocatalytic [3+2] Cycloaddition [Full Paper]
Asian J. Org. Chem. 2019, vol. 8, no. 7, p. 978

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Biwei Xiao, Teófilo Rojo, Xiaolin Li
Hard Carbon as Sodium-Ion Battery Anodes: Progress and Challenges [Minireview]
ChemSusChem 2019, vol. 12, no. 1, p. 133

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Kennedy J. Ngwira, Jonas Kühlborn, Quintino A. Mgani, Charles B. de Koning, Till Opatz
Front Cover: Valorisation of Cashew Nut Shell Liquid Phenolics in the Synthesis of UV Absorbers (Eur. J. Org. Chem. 30/2019) [Cover Picture]
Eur. J. Org. Chem. 2019, p. 4763

Cover Picture Lebensmittelchemie 4/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 4

Olaf Deutschmann, Roland Dittmeyer, Jan-Dierk Grunwaldt, Gunther Kolb, Stefan Löbbecke, Gregor D. Wehinger
Technische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 6, p. 50

Titelbild: (CHEMKON 5/2019) [Titelbild]
CHEMKON 2019, vol. 26, no. 5, p. 173

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2017

 


Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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