ChemPubSoc Europe Early View Journal Articles


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ChemMedChem

Synthesis and Antimicrobial Activity Evaluation of Imidazole‐Fused Imidazo[2,1‐b][1,3,4]thiadiazole Analogues

Published: 22 April 2021

Author(s): Fang Yan Guo, Chang Ji Zheng, Meiyuan Wang, Jiangping Ai, Lan Ying Han, Liu Yang, Ye Fang Lu, Yu Xuan Yang, Ming Guan Piao, Hu‐Ri Piao, Chun‐Mei Jin, Cheng Hua Jin

Abstract Three series of new imidazole‐fused imidazo[2,1‐b][1,3,4]thiadiazole analogues (compounds 20 a–g, 21 a–g, and 22 a–g) have been synthesized, and their antibacterial and antifungal activities have been evaluated. All the target compounds showed strong antifungal activity and high selectivity for the test fungus Candida albicans over Gram‐positive and ‐negative bacteria....

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European Journal of Inorganic Chemistry

Burning Rate Performance Study of Ammonium Perchlorate Catalyzed by Heteroleptic Copper(I) Complexes with Pyrazino[2,3‐f][1,10]phenanthroline‐Based Ligands

Published: 22 April 2021

Author(s): Manuel A. Escobar, Cesar Morales‐Verdejo, Juan Luis Arroyo, Paulina Dreyse, Iván González, Iván Brito, Desmond MacLeod‐Carey, David Moreno da Costa, Alan R. Cabrera

Abstract This contribution describes the catalytic effect of heteroleptic Cu(I) complexes with pyrazino[2,3‐f][1,10]phenanthroline‐based ligands (C1‐7) on the thermal decomposition of ammonium perchlorate (AP). The complexes C2 and C4‐7 were synthesized and characterized by NMR, HRMS and, in the case of C7, by X‐ray diffraction. The burning rate performance of C1‐7 on thermal decomposition of AP was studied by differential scanning calorimetry technique. The effect of the counter ion type, the...

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ChemSusChem

Modification of Ti‐doped Hematite Photoanode with Quasi‐molecular Cocatalyst: A Comparison of Improvement Mechanism Between Non‐noble and Noble Metals

Published: 22 April 2021

Author(s): Ruiling Wang, Yasutaka Kuwahara, Kohsuke Mori, Xufang Qian, Yixin Zhao, Hiromi Yamashita

Abstract Loading of molecular catalyst on the surface of semiconductors is an attractive way to boost the water oxidation activity. As active sites, molecular water oxidation cocatalysts show increasing attraction and application possibility. In order to compare the advantages between molecular catalysts with non‐noble and noble metals, the loading of the Fe(salen) and Ru(salen) as cocatalyst precursors on the surface of Ti−Fe2O3 was investigated Quasi‐Fe(salen) and Ru(salen) improved the...

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ChemBioChem

Enzymatic RNA Production from NTPs Synthesized from Nucleosides and Trimetaphosphate**

Published: 22 April 2021

Author(s): Fabio Chizzolini, Alexandra D. Kent, Luiz F. M. Passalacqua, Andrej Lupták

Abstract A mechanism of nucleoside triphosphorylation would have been critical in an evolving “RNA world” to provide high‐energy substrates for reactions such as RNA polymerization. However, synthetic approaches to produce ribonucleoside triphosphates (rNTPs) have suffered from conditions such as high temperatures or high pH that lead to increased RNA degradation, as well as substrate production that cannot sustain replication. Previous reports have demonstrated that cyclic trimetaphosphate...

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ChemBioChem

Chemoproteomic Profiling of Covalent XPO1 Inhibitors to Assess Target Engagement and Selectivity

Published: 22 April 2021

Author(s): Jeffrey G. Martin, Jennifer A. Ward, Felix Feyertag, Lu Zhang, Shalise Couvertier, Kevin Guckian, Kilian V. M. Huber, Douglas S. Johnson

Abstract Selinexor, a covalent XPO1 inhibitor, is approved in the USA in combination with dexamethasone for penta‐refractory multiple myeloma. Additional XPO1 covalent inhibitors are currently in clinical trials for multiple diseases including hematologic malignancies, solid tumor malignancies, glioblastoma multiforme (GBM), and amyotrophic lateral sclerosis (ALS). It is important to measure the target engagement and selectivity of covalent inhibitors to understand the degree of engagement...

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ChemBioChem

A Mutation‐Based Method for Pinpointing a DNA N6‐Methyladenine Methyltransferase Modification Site at Single Base Resolution

Published: 22 April 2021

Author(s): Mohan Cheng, Xiao Shu, Jie Cao, Minsong Gao, Siying Xiang, Fengqin Wang, Yizhen Wang, Jianzhao Liu

Abstract DNA N6‐methyladenine (6mA) has recently received notable attention due to an increased finding of its functional roles in higher eukaryotes. Here we report an enzyme‐assisted chemical labeling method to pinpoint the DNA 6mA methyltransferase (MTase) substrate modification site at single base resolution. A designed allyl‐substituted MTase cofactor was applied in the catalytic transfer reaction, and the allyl group was installed to the N6‐position of adenine within a specific DNA...

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Chemistry - A European Journal

Reevaluating the Solution Photophysics of Tetraphenylethylene at the Origin of their Aggregation‐Induced Emission Properties

Published: 22 April 2021

Author(s): Jean Rouillon, Cyrille Monnereau, Chantal Andraud

Abstract Although tetraphenylethylene (TPE) and its derivatives have been the most commonly used building blocks in the construction of molecules with aggregation‐induced emission (AIE) properties, no absolute consensus exists regarding the mechanisms at the origin of the phenomenon. Restriction of intramolecular rotations (RIR) of peripheral phenyls has historically been a dominant paradigm, which has served as a valuable guideline in the molecular engineering of AIEgens. Yet, an increasing...

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Chemistry - A European Journal

Ultraviolet‐Cured Semi‐Interpenetrating Network Polymer Electrolytes for High‐Performance Quasi‐Solid‐State Lithium Metal Batteries

Published: 22 April 2021

Author(s): Hui‐xin Xie, Qian‐gang Fu, Zhuo Li, Shuang Chen, Jia‐min Wu, Lu Wei, Xin Guo

Abstract Solid polymer electrolytes with relatively low ionic conductivity at room temperature and poor mechanical strength greatly restrict their practical applications. Herein, we design semi‐interpenetrating network polymer (SNP) electrolyte composed of an ultraviolet‐crosslinked polymer network (ethoxylated trimethylolpropane triacrylate), linear polymer chains (polyvinylidene fluoride‐co‐hexafluoropropylene) and lithium salt solution to satisfy the demand of high ionic conductivity, good...

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Chemistry - A European Journal

Synthesis of Spirocycles via Ni‐Catalyzed Intramolecular Coupling of Thioesters and Olefins

Published: 22 April 2021

Author(s): Wenfei Liu, Wenhua Xu, Juanjuan Wang, Hong Lu, Peng‐Fei Xu, Hao Wei

Abstract A nickel‐catalyzed intramolecular coupling of thioesters and olefins has been developed for the efficient synthesis of spirocycles, a privileged scaffold commonly found in natural products. This transformation is characterized by the simultaneous transfer of both acyl and thiol moieties to the alkene, with the suppression of decarbonylation and β‐hydrogen elimination. Initial mechanistic investigations are consistent with an oxidative addition/olefin insertion/reductive elimination...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Cyclopentadienone Derivative Dimers as Tunable Photoswitches

Published: 22 April 2021

Author(s): Ru‐Qiang Lu, You‐Zhen Zhuo, Yue‐Hua Bao, Lin‐Lin Yang, Hang Qu, Xiao Tang, Xin‐Chang Wang, Zhi‐Hao Li, Xiao‐Yu Cao

Abstract A series of photoswitchable cyclopentadienone derivative dimers bearing bromo, thienyl, 4‐(dimethylamino)phenyl, 3‐pyridinyl, 4‐nitrophenyl and cyano groups was designed and facilely synthesized. Photoswitching properties such as the photoconversions in the photostationary state (PSS), the thermal kinetics and thermal half‐lives of photoisomers were systematically investigated. These photoswitches show high fatigue resistance and large photoconversions in the PSS. This work proves...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

March 2021

 


Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang
Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview]
Batteries & Supercaps 2021, vol. 4, no. 4, p. 585

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Sebastian Gisbertz, Bartholomäus Pieber
Heterogeneous Photocatalysis in Organic Synthesis [Review]
ChemPhotoChem 2020, vol. 4, no. 7, p. 456

Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview]
ChemPhysChem 2018, vol. 19, no. 11, p. 1315

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar
Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 1373

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun
Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview]
ChemNanoMat 2020, vol. 6, no. 3, p. 336

Huaibo Zhao, Daniele Leonori
Minimization of Back-Electron Transfer Enables the Elusive sp3 C−H Functionalization of Secondary Anilines [Communication]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Emiliano Feresin*, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen*
Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel]
Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28

Hilbert Meyer
Guter Unterricht an guten Schulen? [Aufsatz]
CHEMKON 2006, vol. 13, no. 2, p. 77

Bambus in Coffee-to-go-Bechern [Analytik]
Lebensmittelchemie 2021, vol. 75, no. 1, p. 2

Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter
Organische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2021, vol. 69, no. 3, p. 38

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH