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Chemistry - A European Journal

Probing the Lewis Acidity of Boronic Acids through Interactions with Arene Substituents

Published: 22 January 2022

Author(s): Jie Jian, Roel Hammink, Christine J. McKenzie, F. Matthias Bickelhaupt, Jordi Poater, Jasmin Mecinović

Abstract Boronic acids are Lewis acids that exist in equilibrium with boronate forms in aqueous solution. Here we experimentally and computationally investigated the Lewis acidity of 2,6‐diarylphenylboronic acids; specially designed phenylboronic acids that possess two flanking aromatic rings with tunable aromatic character. Hammett analysis of 2,6‐diarylphenylboronic acids reveals that their Lewis acidity remains unchanged upon the introduction of EWG/EDG at the distant para position of the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Abnormal Association between Metal−Organic Cages and Counterions Regulated by the Hydration Shells

Published: 22 January 2022

Author(s): Yuqing Yang, Ehsan Raee, Tianbo Liu

Abstract A unique trend in the binding affinity between cationic metal−organic cages (MOCs) and external counteranions in aqueous media was observed. Similar to many macroions, two MOCs, sharing similar structures but carrying different number of charges, self‐assembled into hollow spherical single‐layered blackberry‐type structures through counterion‐mediated attraction. Dynamic and static light scattering and isothermal titration calorimetry measurements confirm the stronger interactions...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Ring Opening Reactions of β‐Propiolactam in Superacidic Media

Published: 22 January 2022

Author(s): Stefanie Beck, Vanessa Rück, Lea‐Viktoria Pietsch, Christoph Jessen, Andreas J. Kornath

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C6F5)3 Lewis Pair

Published: 22 January 2022

Author(s): Jinxiong Lin, Friedrich Wossidlo., Nathan T. Coles, Manuela Weber, Simon Steinhauer, Tobias Böttcher, Christian Müller

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Sandacrabins – Structurally Unique Antiviral RNA Polymerase Inhibitors from a Rare Myxobacterium**

Published: 22 January 2022

Author(s): Chantal D. Bader, Fabian Panter, Ronald Garcia, Egor P. Tchesnokov, Sibylle Haid, Christine Walt, Cathrin Spröer, Alexander F. Kiefer, Matthias Götte, Jörg Overmann, Thomas Pietschmann, Rolf Müller

Abstract Structure elucidation and total synthesis of five unprecedented terpenoid‐alkaloids, the sandacrabins, are reported, alongside with the first description of their producing organism Sandaracinus defensii MSr10575, which expands the Sandaracineae family by only its second member. The genome sequence of S. defensii as presented in this study was utilized to identify enzymes responsible for sandacrabin formation, whereby dimethylbenzimidazol, deriving from cobalamin biosynthesis, was...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Heteropolymetallic Architectures as Snapshots of Transmetallation Processes at Different Degrees of Transfer

Published: 22 January 2022

Author(s): David Campillo, Daniel Escudero, Miguel Baya, Antonio Martín

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes

Published: 22 January 2022

Author(s): Nithin Suryadevara, Asato Mizuno, Lea Spieker, Soma Salamon, Stephan Sleziona, André Maas, Erik Pollmann, Benoît Heinrich, Marika Schleberger, Heiko Wende, Senthil Kumar Kuppusamy, Mario Ruben

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Computational Insights into the Allosteric Effect and Dynamic Structural Features of the SARS‐COV‐2 Spike Protein

Published: 22 January 2022

Author(s): Qiao Xue, Xian Liu, Wenxiao Pan, Aiqian Zhang, Jianjie Fu, Guibin Jiang

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Electrostatic Perturbations in the Substrate‐Binding Pocket of Taurine/α‐Ketoglutarate Dioxygenase Determine its Selectivity

Published: 22 January 2022

Author(s): Hafiz Saqib Ali, Sam P. Visser

Abstract Taurine/α‐ketoglutarate dioxygenase is an important enzyme that takes part in the cysteine catabolism process in the human body and selectively hydroxylates taurine at the C1‐position. Recent computational studies showed that in the gas‐phase the C2−H bond of taurine is substantially weaker than the C1−H bond, yet no evidence exists of 2‐hydroxytaurine products. To this end, a detailed computational study on the selectivity patterns in TauD was performed. The calculations show that...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Release of Molecular Cargo from Polymer Systems by Mechanochemistry

Published: 22 January 2022

Author(s): Robin Küng, Robert Göstl, Bernd M. Schmidt

Abstract The design and manipulation of (multi)functional materials at the nanoscale holds the promise of fuelling tomorrow's major technological advances. In the realm of macromolecular nanosystems, the incorporation of force‐responsive groups, so called mechanophores, has resulted in unprecedented access to responsive behaviours and enabled sophisticated functions of the resulting structures and advanced materials. Among the diverse force‐activated motifs, the on‐demand release or activation...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

December 2021

 


Dolonchampa Maji, Donghyeon Oh, Krishna Sharmah Gautam, Mingzhou Zhou, Haini Zhang, Jeff Kao, Daryl Giblin, Matthew Smith, Junha Lim, Seunghyun Lee, Youngnam Kang, Won Jong Kim, Chulhong Kim, Samuel Achilefu
Copper-Catalyzed Covalent Dimerization of Near-Infrared Fluorescent Cyanine Dyes: Synergistic Enhancement of Photoacoustic Signals for Molecular Imaging of Tumors [Cover Profile]
Anal. Sens. 2022, vol. 2, eLoc. e202100065

Oindrila Hossain, Ehsanur Rahman, Hridoy Roy, Md. Shafiul Azam, Shoeb Ahmed
Synthesis, characterization, and comparative assessment of antimicrobial properties and cytotoxicity of graphene-, silver-, and zinc-based nanomaterials [Research Article]
Anal. Sci. Adv. https://doi.org/10.1002/ansa.202100041

Witali Beichel, Julian Skrotzki, Petra Klose, Christian Njel, Burkhard Butschke, Stephan Burger, Lili Liu, Ralf Thomann, Yi Thomann, Daniel Biro, Simon Thiele, Ingo Krossing
An Artificial SEI Layer Based on an Inorganic Coordination Polymer with Self-Healing Ability for Long-Lived Rechargeable Lithium-Metal Batteries [Research Article]
Batteries Supercaps https://doi.org/10.1002/batt.202100347

Zhenyi Hu, Craig M. Crews
Recent Developments in PROTAC-Mediated Protein Degradation: From Bench to Clinic [Review]
ChemBioChem https://doi.org/10.1002/cbic.202100270

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Patrick Wilson, Sabrina Sorto, Aaron K. Apawu
Optimizing an Electrochemical Protocol for Quantitative Analysis of Ascorbic Acid in Dietary Supplements [Full Paper]
Chem. Methods https://doi.org/10.1002/cmtd.202100049

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Stefanie Dehnen, Peter R. Schreiner, Sangam Chatterjee, Kerstin Volz, Nils W. Rosemann, Wolf-Christian Pilgrim, Doreen Mollenhauer, Simone Sanna
Front Cover: Amorphous Molecular Materials for Directed Supercontinuum Generation (ChemPhotoChem 12/2021) [Cover Picture]
ChemPhotoChem 2021, vol. 5, no. 12, p. 1027

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Ben S. Pilgrim, Neil R. Champness
Metal-Organic Frameworks and Metal-Organic Cages - A Perspective [Review]
ChemPlusChem 2020, vol. 85, no. 8, p. 1842

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Ankit Kumar, Hem Kanwar Rathore, Debasish Sarkar, Ashok Shukla
Nanoarchitectured transition metal oxides and their composites for supercapacitors [REVIEW]
Electrochem. Sci. Adv. https://doi.org/10.1002/elsa.202100187

Maximilian Dehmel, Marius A. Wünsche, Helmar Görls, Robert Kretschmer
Dinuclear Chlorotetrylenes of Silicon, Germanium, and Tin Based on a Backbone-Bridged Bis(amidine) [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 4806

Oleksandr O. Grygorenko
Enamine Ltd.: The Science and Business of Organic Chemistry and Beyond [Editorial]
Eur. J. Org. Chem. 2021, p. 6474

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Bin Zuo, Zeye Lu, Xiaoqiang Wu, Weiwei Fang, Wanfang Li, Mingxian Huang, Dong-Yuan Yang, Qinyue Deng, Tao Tu
Cover Feature: A N-Heterocyclic Carbene-Palladacycle with Constrained Aliphatic Linker: Synthesis, Characterization and Its Catalytic Application towards Suzuki-Miyaura Cross-Coupling (Asian J. Org. Chem. 12/2021) [Cover Picture]
Asian J. Org. Chem. 2021, vol. 10, no. 12, p. 3051

Dan Zhao, Xinliang Feng
A Special Collection on 2D Materials and Their Applications [Editorial]
Chem. Asian J. 2021, vol. 16, no. 24, p. 4009

Qi Wang, Guoxiang Yang, Yangjie Fu, Ningyi Li, Derek Hao, Shengqian Ma
Nanospace Engineering of Metal-Organic Frameworks for Heterogeneous Catalysis [Review]
ChemNanoMat 2022, vol. 8, eLoc. e202100396

Johannes G. H. Hermens, Andries Jensma, Ben L. Feringa
Highly Efficient Biobased Synthesis of Acrylic Acid [Research Article]
Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.202112618

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, no. 1-2, p. 17

Joachim Simon, Patrick Théato, Thomas Früh
Perspektiven der Makromolekularen Chemie [Editorial]
Chem. Unserer Zeit 2021, vol. 55, no. 6, p. 367

Marco Oetken, Jens Friedrich
Chemiedidaktik - bunt und vielfältig [Editorial]
CHEMKON 2021, vol. 28, no. 8, p. 326

Toxikologische Risikobewertung im Lebensmittelbereich [Analytik]
Lebensmittelchemie 2021, vol. 75, no. 6, p. 198

Elementerätsel 12/2021: Das schwarze Schaf [Ausgeblättert]
Nachr. Chem. 2021, vol. 69, no. 12, p. 99

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.

 


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH