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ChemCatChem

Bacterial Lysis via Photocatalysis ‐ A Critical Mechanistic Review

Published: 21 February 2020

Author(s): Rimzhim Gupta, Jayant Modak

Abstract This Review discusses one of the most important area of photocatalytic reactions. In current research scenario, photocatalysis is well utilized strategy for a wide variety of applications including organic/ inorganic decontamination, solar fuel generation, microbial disinfection etc. This Review touches upon the mechanistic aspect of microbial disinfection, the growth in the research, issues to be addressed in future to make it a sustainable technology for this application. This...

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ChemCatChem

Hydroconversion of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran and 2,5‐Dihydroxymethyltetrahydrofuran over Non‐promoted Ni/SBA‐15

Published: 21 February 2020

Author(s): Shuo Chen, Carmen Ciotonea, Karine De Oliveira Vigier, François Jérôme, Robert Wojcieszak, Franck Dumeignil, Eric Marceau, Sebastien Royer

Abstract The selective hydroconversion of 5‐hydroxymethylfurfural (HMF) to biofuels is currently highly sought‐for. While the literature has demonstrated that this reaction is possible on promoted Ni catalysts, we show here that a monometallic, non‐promoted Ni/SBA‐15 catalyst, prepared by incipient wetness impregnation, can convert HMF to 2,5‐dimethylfuran (DMF) and to 2,5‐dimethyltetrahydrofuran (DMTHF) at 180 °C, in a consecutive way. Through a control over reaction time, high yields to DMF...

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ChemPhysChem

Anisotropic Dynamics of Binary Particles in Confined Geometries

Published: 21 February 2020

Author(s): Kun Liu, Yue Wang, Zhongjie Du, Chen Zhang, Jianguo Mi

Abstract The diffusion dynamics of colloidal particles in a good solvent confined between two parallel quartz walls have been studied within the framework of dynamical density functional theory. The highly ordered density layers induced by interfacial effects give rise to the oscillating dynamics, resulting in position‐dependent structural relaxations and diffusivities. Further investigation reveals that particle size, particle‐wall interaction, and slitpore width play different roles in...

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ChemSusChem

Electrocatalytic Oxidative Transformation of Organic Acids for Carbon–Heteroatom and Sulfur–Heteroatom Bond Formation

Published: 21 February 2020

Author(s): Man Li, Junting Hong, Wei Xiao, Yang Yang, Di Qiu, Fanyang Mo

Abstract The electrolysis of organic acids has garnered increasing attention in recent years. In addition to the famous electrochemical decarboxylation known as Kolbe electrolysis, a number of other electrochemical processes have been recently established that allow for the construction of carbon–heteroatom and sulfur–heteroatom bonds from organic acids. Herein, recent advances in electrochemical C−X and S−X (X=N, O, S, Se) bond‐forming reactions from five classes of organic acids and their...

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ChemCatChem

Yolk‐Shell‐Structured CuO−ZnO−In2O3 Trimetallic Oxide Mesocrystal Microspheres as an Efficient Catalyst for Trichlorosilane Production

Published: 21 February 2020

Author(s): Xin Li, Yongjun Ji, Jing Li, Yu Zhang, Hezhi Liu, Qiongguang Li, Lihua Jia, Xiangfeng Guo, Ziyi Zhong, Fabing Su

Abstract Trichlorosilane (TCS), the primary chemical feedstock for production of high‐purity Si used in Si‐based solar cells, is currently manufactured industrially via a non‐catalytic hydrochlorination of metallurgical Si. This process generates a huge amount of undesirable silicon tetrachloride (STC) byproduct. Here we report the synthesis of yolk‐shell‐structured CuO−ZnO−In2O3 trimetallic oxide mesocrystal microspheres that can be employed as an efficient catalyst to produce TCS...

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European Journal of Inorganic Chemistry

Combined Occupancy of Gadolinium at the Lattice Sites of β‐Ca3(PO4)2 and t‐ZrO2 Crystal Structures

Published: 21 February 2020

Author(s): Ponnusamy Nandha Kumar, Sanjeevi Kannan, José M. F. Ferreira

An in situ aqueous precipitation with the aid of Gd3+ as a stabilizer has been used to attain a series of β‐Ca3(PO4)2/t‐ZrO2 composites. Analytical characterization techniques were used to investigate the formation of desired composite during progressive heat treatments. The transformation of calcium deficient apatite to β‐Ca3(PO4)2, which usually occurs at ≈ 780 °C for pure systems, is delayed to beyond 1100 °C, depending upon the concentration of Gd3+/Zr4+ used in the synthesis. Gd3+ prefers...

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European Journal of Inorganic Chemistry

Dipodal, Tripodal, and Discoidal Coordination Modes of Kemp's Triacid Anions

Published: 21 February 2020

Author(s): Jack Harrowfield, Pierre Thuéry

In order to probe the conformational preferences of the anions of Kemp's triacid (cis,cis‐1,3,5‐trimethyl‐1,3,5‐cyclohexanetricarboxylic acid, H3kta) in their metal ion complexes, and their influence on the structures thereof, six complexes with widely different metal cations (alkali, alkaline‐earth, 3d‐block and actinide) were synthesized and crystallographically characterized. All these complexes crystallize as diperiodic assemblies, but with three different conformations of the...

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European Journal of Inorganic Chemistry

Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes

Published: 21 February 2020

Author(s): Mary C. Eaton, Brian J. Knight, Vincent J. Catalano, Leslie J. Murray

We report catalytic silylation of dinitrogen to tris(trimethylsilyl)amine by a series of trinuclear first row transition metal complexes (M = Cr, Mn, Fe, Co, Ni) housed in our tris(β‐diketiminate) cyclophane (L3–). Yields are expectedly dependent on metal ion type ranging from 14 to 199 equiv. NH4+/complex after protonolysis for the Mn to Co congeners, respectively. For the series of complexes, the observed trend for the number of turnovers as a function of metal ion type is Co Fe Cr Ni ...

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European Journal of Inorganic Chemistry

High Performance Flexible Piezocomposites Based on a Particle Alignment Strategy

Published: 21 February 2020

Author(s): Chenwei Wang, Mupeng Zheng, Xin Gao, Jing Fu, Mankang Zhu, Yudong Hou

Piezocomposites composed of piezoelectric inorganic particles dispersed in a flexible polymer have emerged as promising materials for flexible energy harvesters and sensors. In this work, to overcome the inefficient stress transfer capability in flexible piezocomposites for energy harvester, KNbO3 (KN) particles prepared by conventional solid oxide process were aligned to form chain‐distributed particles in polydimethylsiloxane (PDMS) matrix by dielectrophoresis. The composite with 8 vol.‐% KN...

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Chemistry - A European Journal

Transition‐Metal‐Free Multiple Functionalization of Piperidines to 4‐Substituted and 3,4‐Disubstituted 2‐Piperidinones

Published: 21 February 2020

Author(s): Delfino Chamorro‐Arenas, Alejandro A. Nolasco‐Hernández, Lilia Fuentes, Leticia Quintero, Fernando Sartillo‐Piscil

Abstract Remote and multiple functionalization of piperidines without the use of transition‐metal catalysts and elaborate directing groups is one of the major challenges in organic synthesis. Herein is reported an unprecedented two‐step protocol that enables the multiple functionalization of piperidines to either 4‐substituted or trans‐3,4‐disubstituted 2‐piperidones. First, by exploiting the duality of TEMPO reactivity, which under oxidative and thermal conditions fluctuates between cationic...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

December 2019

 


Duanyang Kong, Patrick J. Moon, Odey Bsharat, Rylan J. Lundgren
Direct Catalytic Decarboxylative Amination of Aryl Acetic Acids [Research Article]
Angew. Chem. Int. Ed. 2020, vol. 59, no. 3, p. 1313

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, no. 7, p. 1159

Wolfgang Pfeiffer, Van Than Nguyen, Jan Neumann, Dirk Awe, Jens Tränckner
Operation and Control of a Full-Scale Biogas Plant Treating Wastewater from the Cleaning of Car Tanks [Research Article]
Chem. Eng. Technol. 2020, vol. 43, no. 1, p. 84

Dieter Wöhrle
Kunststoffe [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

Luling Wu, Xue Tian, Hai-Hao Han, Jie Wang, Robin R. Groleau, Paramabhorn Tosuwan, Boontana Wannalerse, Adam C. Sedgwick, Steven D. Bull, Xiao-Peng He, Tony D. James
A Simple Near-Infrared Fluorescent Probe for the Detection of Peroxynitrite [Communication]
ChemistryOpen 2019, vol. 8, no. 12, p. 1407

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Ekkehard Schwab, Sebastian Schiebahn, Georg Schaub, Martin Reuter, Konstantin Räuchle, Ludolf Plass, Marcell Peuckert, Anja Metzelthin, Falko Mahlendorf, Wolfram Koch, Renate Hoer, Angelika Heinzel, Sigmar Bräuninger, Martin Bertau, Christian Beilmann, Florian Ausfelder, Ferdi Schüth, Detlef Stolten, Gisa Teßmer, Kurt Wagemann, Karl-Friedrich Ziegahn
Energiespeicherung als Element einer sicheren Energieversorgung [Übersichtsbeitrag]
Chem. Ing. Tech. 2015, vol. 87, no. 1-2, p. 17

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Lucia Mazzapioda, Carmelo Lo Vecchio, Annalisa Paolone, Antonino Salvatore Aricò, Vincenzo Baglio, Maria Assunta Navarra
Enhancing Oxygen Reduction Reaction Catalytic Activity Using a Sub-Stoichiometric CaTiO3−δ Additive [Cover Profile]
ChemElectrochem 2019, vol. 6, no. 24, p. 5910

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

Frank Tabellion, Christoph Peters, Uwe Fischbeck, Manfred Regitz, Fritz Preuss
Imidovanadium(V) Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes: Synthesis of 1,2,4‐Azaphosphavanada(V)‐cyclobutenes, 1,3,5‐Triphosphabenzenes, and 1H‐1,2,4‐Azadiphospholes [Organophosphorus Compounds, Part 148 : Full Paper]
Chem. Eur. J. 2000, vol. 6, no. 24, p. 4558

Byunghyuck Jung, Jungkyu K. Lee, Jungnam Kim, Eunhye K. Kang, Sang Yeong Han, Hee-Yoon Lee, Insung S. Choi
Synthetic Strategies for (−)-Cannabidiol and Its Structural Analogs [Minireview]
Chem. Asian J. 2019, vol. 14, no. 21, p. 3749

Arun K. Sinha, Danish Equbal
Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review]
Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Mingshuai Ma, Lin Dai, Chuanling Si, Lanfeng Hui, Zhong Liu, Yonghao Ni
Front Cover: A Facile Preparation of Super Long-Term Stable Lignin Nanoparticles from Black Liquor (ChemSusChem 24/2019) [Cover Picture]
ChemSusChem 2019, vol. 12, no. 24, p. 5213

Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief
The Periodic Table of the Chemical Elements and Sustainable Development [Essay]
Eur. J. Inorg. Chem. 2019, p. 4170

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 6/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 6

Elementerätsel 1 [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 12, p. 40

Schüleraufgabe: CHEMKON 2/2017 [Schüleraufgabe]
CHEMKON 2017, vol. 24, no. 2, p. 91

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2017

 


Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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A product of ChemPubSoc Europe (16 European Chemical Societies)published by Wiley-VCH