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European Journal of Organic Chemistry

Stereoselective Synthesis of the β‐Amino Acid Moiety of Fijiolide A

Published: 14 December 2018

Author(s): Timon Kurzawa, Eric Kerste, Paul Nikodemiak, Daniel Bothe, Klaus Harms, Ulrich Koert

An enantioselective synthesis of the β‐amino acid moiety of fijiolide A is described. Starting from eugenol, two sulfamates could be obtained on gram scale as substrates for an enantioselective C–H amination using Rh2(R/S‐nap)4. Acylation and ring opening of the resulting oxathiazinanes, followed by stepwise oxidation of the corresponding amino alcohol and TES‐protection of the catechol gave rise to Cramer's amino acid fragment from the total...

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Chemistry - A European Journal

Recent Progress on Cyclic Nitrenoid Precursors in Transition‐Metal‐Catalyzed Nitrene‐Transfer Reactions

Published: 14 December 2018

Author(s): Takuya Shimbayashi, Kohei Sasakura, Akira Eguchi, Kazuhiro Okamoto, Kouichi Ohe

Abstract Nitrene‐transfer reactions are powerful synthetic tools for the direct incorporation of nitrogen atoms into organic molecules. The discovery of novel nitrene‐transfer reactions has been dominantly supported not only by improvements in transition‐metal catalysts but also by the employment of novel precursors of nitrenoids. Since pioneering work involving the use of organic azides and iminoiodinanes as practical synthetic...

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Chemistry - A European Journal

Synthesis and Characterization of Liquid‐Crystalline Tetraoxapentacene Derivatives Exhibiting Aggregation‐Induced Emission

Published: 14 December 2018

Author(s): Lana K. Hiscock, Brooke M. Raycraft, Monika Wałęsa‐Chorab, Coralie Cambe, Alexandre Malinge, W. G. Skene, Hi Taing, S. Holger Eichhorn, Louise N. Dawe, Kenneth E. Maly

Abstract A series of new tetrakis(dialkoxyphenyl) dicyanotetraoxapentacene derivatives (1 a–c) were prepared by reaction of the appropriate terphenyl diols with tetrafluoroterephthalonitrile in good yields. Compounds 1 b and 1 c, which bear hexyloxy and decyloxy side chains, exhibited columnar hexagonal mesophases, as shown by polarized optical microscopy, variable‐temperature powder X‐ray diffraction, and differential scanning calorimetry....

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Chemistry - A European Journal

Intertwined Titanium Carbide MXene within a 3 D Tangled Polypyrrole Nanowires Matrix for Enhanced Supercapacitor Performances

Published: 14 December 2018

Author(s): Thi Anh Le, Ngoc Quang Tran, Yeseul Hong, Hyoyoung Lee

Abstract The exploration of the rational design and synthesis of unique and robust architectured electrodes for the high capacitance, rate capability, and stability of supercapacitors is crucial to the future of energy storage technology. Herein, an in situ synthesis of multilayered titanium carbide MXene tightly caging within a 3 D conducting tangled polypyrrole (PPy) nanowire (NW) network is proposed as an effective strategy to...

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Chemistry - A European Journal

Cu@Cu 3 P Core–Shell Nanowires Attached to Nickel Foam as High‐Performance Electrocatalysts for the Hydrogen Evolution Reaction

Published: 14 December 2018

Author(s): Haiyan Zheng, Xiubing Huang, Hongyi Gao, Guilong Lu, Wenjun Dong, Ge Wang

Abstract The development of highly efficient and inexpensive electrocatalysts is of great importance for generating renewable energy. In this work, Cu@Cu3P core–shell nanowires grown on nickel foam (Cu@Cu3P/NF) are prepared by a novel in situ reduction of CuSO4⋅5 H2O, which forms Cu, followed by surface oxidation and low‐temperature phosphorization. The unique hierarchical architecture of Cu@Cu3P/NF integrates the advantages of enlarged surface...

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Chemistry - A European Journal

Phosphorus versus Sulfur: Discovery of Benzenephosphonamidates as Versatile Sulfonamide‐Mimic Chemotypes Acting as Carbonic Anhydrase Inhibitors

Published: 14 December 2018

Author(s): Alessio Nocentini, Paola Gratteri, Claudiu T. Supuran

Abstract The first zinc‐binding group (ZBG) to have been identified as inhibitor of the metallo‐enzymes carbonic anhydrases (CA, EC was the sulfonamide. From then on several classes of zinc‐binders have been described. This work reports the benzenephosponamidates as a new chiral aromatic sulfonamide‐mimic ZBG able to meet the requirements for effectively binding the enzyme active site. Several low micromolar CA I, II, VII,...

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Chemistry - A European Journal

Visible‐Light Photocatalysis of the Ketyl Radical Coupling Reaction

Published: 14 December 2018

Author(s): Qing Xia, Jianyang Dong, Hongjian Song, Qingmin Wang

Abstract Ketyl radical coupling reactions for the construction of diversely functionalized alcohols have been continuously developed for many decades. Based on the recently widespread application of photocatalysis, ketyl radical coupling reactions have also witnessed rapid development. This Minireview aims to briefly and concisely summarize the methods to construct ketyl radical intermediates through visible‐light photocatalysis...

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Chemistry - A European Journal

Well‐Defined Alkyne Metathesis Catalysts: Developments and Recent Applications

Published: 14 December 2018

Author(s): Henrike Ehrhorn, Matthias Tamm

Abstract Although alkyne metathesis has been known for 50 years, rapid progress in this field has mostly occurred during the last two decades. In this article, the development of several highly efficient and thoroughly studied alkyne metathesis catalysts is reviewed, which includes novel well‐defined, in situ formed and heterogeneous systems. Various alkyne metathesis methodologies, including alkyne cross‐metathesis (ACM),...

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Chemistry - A European Journal

AuBr 3 ‐Catalyzed Chemoselective Annulation of Isocyanates with 2 H ‐Azirine

Published: 14 December 2018

Author(s): Yufeng Wu, Bing Tian, Sina Witzel, Hongming Jin, Xianhai Tian, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi

Abstract The chemoselective cyclization of isocyanates with 2H‐azirine was achieved with AuBr3 as catalyst. This transfer sets the stage for the synthesis of aromatic oxazole‐ureas in a tandem process. The addition of a catalytic amount of phosphite enhances the process enormously. The reaction can also be performed in a one‐pot process using benzoyl azide instead of isocyanate under the same conditions. A detailed study on the role of the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Star‐Shaped and Fused Electron Acceptors based on C 3h ‐Symmetric Coplanar Trindeno[1, 2‐b: 4, 5‐b′: 7, 8‐b′′]trithiophene Core for Non‐Fullerene Solar Cells

Published: 14 December 2018

Author(s): Weijie Wang, Xiaofu Wu, Hao Hang, Hua Li, Yonghong Chen, Qian Xu, Hui Tong, Lixiang Wang

Abstract Two new star‐shaped and fused electron acceptors, TITT‐3IC and TITT‐3ICF have been designed and synthesized, which consist of a C3h‐symmetric coplanar trindeno[1, 2‐b: 4, 5‐b′: 7, 8‐b′′]trithiophene (TITT) as the central core and 3‐(dicyanomethylidene)indan‐1‐one and 2‐(5,6‐difluoro‐3‐oxo‐2,3‐dihydro‐1H‐inden‐1‐ylidene) malononitrile as the peripheral electron‐withdrawing groups, respectively. With the large coplanar configuration and...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

September 2018


Runze Mao, Jonathan Balon, Xile Hu
Decarboxylative C(sp3)−O Cross-Coupling [Communication]
Angew. Chem. Int. Ed. 2018, vol. 57, p. 13624

Klaus F. Wagenbauer, Floris A. S. Engelhardt, Evi Stahl, Vera K. Hechtl, Pierre Stömmer, Fabian Seebacher, Letizia Meregalli, Philip Ketterer, Thomas Gerling, Hendrik Dietz
How We Make DNA Origami [Concept]
ChemBioChem 2017, vol. 18, p. 1873

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Epple, Joachim Enax
Moderne Zahnpflege aus chemischer Sicht [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 218

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Peter Buchholz, Torsten Brandenburg
Demand, Supply, and Price Trends for Mineral Raw Materials Relevant to the Renewable Energy Transition Wind Energy, Solar Photovoltaic Energy, and Energy Storage [Review]
Chem. Ing. Tech. 2018, vol. 90, p. 141

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, p. 6

Hejin Jiang, Li Zhang, Minghua Liu
Self-Assembly of 1D Helical Nanostructures into Higher Order Chiral Nanostructures in Supramolecular Systems [Focus Review]
ChemNanoMat 2018, vol. 4, p. 720

Sa Xiao, Yi Lu, Xin Li, Bing-Yu Xiao, Liang Wu, Jian-Ping Song, Yu-Xuan Xiao, Si-Ming Wu, Jie Hu, Yong Wang, Gang-Gang Chang, Ge Tian, Silvia Lenaerts, Christoph Janiak, Xiao-Yu Yang, Bao-Lian Su
Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage [Full Paper]
Chem. Eur. J. 2018, vol. 24, p. 13246

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Michael C. Willis, Edward J. Emmett
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review]
Asian J. Org. Chem. 2015, vol. 4, p. 602

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

Gloria Tabacchi
Supramolecular Organization in Confined Nanospaces [Review]
ChemPhysChem 2018, vol. 19, p. 1249

Baokun Qiao, Zhiyong Jiang
Catalytic Photoreduction Induced by Visible Light [Minireview]
ChemPhotoChem 2018, vol. 2, p. 703

Xinyue Zhang, Mingyue Jiang, Na Niu, Zhijun Chen, Shujun Li, Shouxin Liu, Jian Li
Natural-Product-Derived Carbon Dots: From Natural Products to Functional Materials [Review]
ChemSusChem 2018, vol. 11, p. 11

Ross J. Marshall, Ross S. Forgan
Postsynthetic Modification of Zirconium Metal-Organic Frameworks [Microreview]
Eur. J. Inorg. Chem. 2016, p. 4310

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Cover Picture Lebensmittelchemie 4/2018 [Cover Picture]
Lebensmittelchemie 2018, vol. 72

Thomas U. Probst
Umbrüche beim Kunststoffrecycling [Industrie & Technik]
Nachr. Chem. 2018, vol. 66, p. 868

Alexander Engl, Alexandra Schmelzer, Björn Risch
Chemie Pur - Unterrichten in der Natur: Ätherischen Ölen auf der Spur [Artikel]
CHEMKON 2018, vol. 25, p. 7

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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