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B‐factor Guided Proline Substitutions in Chromobacterium violaceum Amine Transaminase: Evaluation of the Proline Rule as a Method for Enzyme Stabilization

Published: 19 March 2019

Author(s): Henrik Land, Jonatan C. Campillo‐Brocal, Maria Svedendahl Humble, Per Berglund

Abstract Biocatalysis is attracting interest in the chemical industry as a sustainable alternative in large‐scale chemical transformations. However, low operational stability of naturally evolved enzymes is a challenge and major efforts are required to engineer protein stability, usually by directed evolution. The development of methods for protein stabilization based on rational design is of great interest, as it would minimize the efforts needed to generate stable enzymes. Here we present a...

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Chemistry - A European Journal

Photosensitive Tin Sulfur Dioxide Complexes with Unexpected Bonding Modes

Published: 19 March 2019

Author(s): Xing Liu, Xiao‐Rui Liu

Abstract Infrared spectra of the matrix‐isolated Sn(η2‐O2S), Sn(η2‐OSO), Sn(η2‐O2S)(η1‐OSO), Sn(η2‐O2S)2, OSn2(η2‐SO), and Sn(μ2‐O2)SnS molecules were observed following laser‐ablated Sn atom reactions with SO2 during condensation in solid argon. The assignments for the major vibrational modes were confirmed by appropriate S18O2 and 34SO2 isotopic shifts and density functional vibrational frequency calculations (B3LYP and BPW91). Interestingly, the mononuclear complexes are interconvertible;...

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New Kids in Lactide Polymerization: Highly Active and Robust Iron Guanidine Complexes as Superior Catalysts

Published: 19 March 2019

Author(s): Ruth D. Rittinghaus, Pascal M. Schäfer, Pascal Albrecht, Christian Conrads, Alexander Hoffmann, Agnieszka N. Ksiazkiewicz, Olga Bienemann, Andrij Pich, Sonja Herres‐Pawlis

Abstract Polylactide is a biodegradable versatile material based on annually renewable resources and thus CO2‐neutral in its lifecycle. Until now, tin(II)octanoate [Sn(Oct2)] was used as catalyst for the industrial ring‐opening polymerization of lactide in spite of its cytotoxicity. On the way towards a sustainable catalyst, three iron(II) hybrid guanidine complexes were investigated concerning their molecular structure and applied to the ring‐opening polymerization of lactide. The complexes...

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Bacterially Derived Antibody Binders as Small Adapters for DNA‐PAINT Microscopy

Published: 19 March 2019

Author(s): Thomas Schlichthaerle, Mahipal Ganji, Alexander Auer, Orsolya Kimbu Wade, Ralf Jungmann

Abstract Current optical super‐resolution implementations are capable of resolving features spaced just a few nanometers apart. However, translating this spatial resolution to cellular targets is limited by the large size of traditionally employed primary and secondary antibody reagents. Recent advancements in small and efficient protein binders for super‐resolution microscopy, such as nanobodies or aptamers, provide an exciting avenue for the future; however, their widespread availability is...

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Chemistry - A European Journal

Direct and Oriented Conversion of CO2 into Value‐Added Aromatics

Published: 19 March 2019

Author(s): Yang Wang, Weizhe Gao, Shun Kazumi, Hangjie Li, Guohui Yang, Noritatsu Tsubaki

Abstract The oriented conversion of CO2 into target high‐value chemicals is an effective way to reduce carbon emissions, but still presents a challenge. In this communication, we report the oriented conversion of CO2 into value‐added aromatics, especially para‐xylene, in a single pass by combining core–shell structured Zn‐doped H‐ZSM‐5 (Zn‐ZSM‐5@SiO2) and a Cr2O3 component. Through precise regulation of the acidity of Zn‐ZSM‐5@SiO2, high para‐xylene selectivity (38.7 % in the total products)...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Revisiting Bond Breaking and Making in EuCo2P2: Where are the Electrons?

Published: 19 March 2019

Author(s): Vincent Yannello, Francois Guillou, Alexander A. Yaroslavtsev, Zachary P. Tener, Fabrice Wilhelm, Alexander N. Yaresko, Serguei L. Molodtsov, Andreas Scherz, Andrei Rogalev, Michael Shatruk

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Understanding the Impact of Bismuth Heterovalent Doping on the Structural and Photophysical Properties of CH3NH3PbBr3 Halide Perovskite Crystals with Near‐IR Photoluminescence

Published: 19 March 2019

Author(s): Rui Meng, Guangbao Wu, Jiyu Zhou, Huiqiong Zhou, Honghua Fang, Maria A. Loi, Yuan Zhang

Abstract A comprehensive study unveiling the impact of heterovalent doping with Bi3+ on the structural, semiconductive, and photoluminescent properties of a single crystal of lead halide perovskites (CH3NH3PbBr3) is presented. As indicated by single‐crystal XRD, a perfect cubic structure in Bi3+‐doped CH3NH3PbBr3 crystals is maintained in association with a slight lattice contraction. Time‐resolved and power‐dependent photoluminescence (PL) spectroscopy illustrates a progressively quenched PL...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Supramolecular Crowding Can Avoid Oxygen Quenching of Photon Upconversion in Water

Published: 19 March 2019

Author(s): Hironori Kouno, Yoichi Sasaki, Nobuhiro Yanai, Nobuo Kimizuka

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Low‐Valent Group 14 NHC‐Stabilized Phosphinidenide ate Complexes and NHC‐Stabilized K/P‐Clusters

Published: 19 March 2019

Author(s): Markus Balmer, Florian Weigend, Carsten von Hänisch

Abstract The N‐heterocyclic carbene (NHC)‐stabilized phosphinidenide, SIMesPK [SIMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazolidine‐2‐ylidene], was used as an (NHC)P‐transfer reagent for the synthesis of the low‐valent Group 14 ate complexes K[(SIMesP)3E] (E=Ge: 2, Sn: 3, Pb: 4), which were characterized by 1H NMR, 31P NMR, IR spectroscopy as well as elemental and X‐ray analysis. Furthermore, SIMesPK was used in reactions with potassium amides and alkoxides to form the molecular...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Supramolecular Crowding Can Avoid Oxygen Quenching of Photon Upconversion in Water

Published: 19 March 2019

Author(s): Hironori Kouno, Yoichi Sasaki, Nobuhiro Yanai, Nobuo Kimizuka

Abstract Invited for the cover of this issue is the group of Nobuhiro Yanai and Nobuo Kimizuka at Kyushu University. The image depicts the photon upconverting self‐assemblies of amphiphilic chromophores in water. Read the full text of the article at 10.1002/chem.201806076.

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

January 2019


Kui Wu, Lushun Wang, Sonivette Colón-Rodríguez, Gerd-Uwe Flechsig, Ting Wang
Amidyl Radical Directed Remote Allylation of Unactivated sp3 C−H Bonds by Organic Photoredox Catalysis [Communication]
Angew. Chem. Int. Ed. 2019, vol. 58, p. 1774

Oliver Plettenburg
Milestones in Bioorganic Chemistry [Editorial]
ChemBioChem 2019, vol. 20, p. 129

Ziwei Li, Zhigang Wang, Sibudjing Kawi
Sintering and Coke Resistant Core/Yolk Shell Catalyst for Hydrocarbon Reforming [Review]
ChemCatChem 2019, vol. 11, p. 202

Frank Scheufler
Haare im Fokus der forensischen Analytik [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 26

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Lei Han, Meng-Ke Wu, Fei-Yan Yi, Dongxiao Chen, Hai-Long Jiang
Chemical Sensors Based on Metal-Organic Frameworks [Review]
ChemPlusChem 2016, vol. 81, p. 675

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Peter Buchholz, Torsten Brandenburg
Demand, Supply, and Price Trends for Mineral Raw Materials Relevant to the Renewable Energy Transition Wind Energy, Solar Photovoltaic Energy, and Energy Storage [Review]
Chem. Ing. Tech. 2018, vol. 90, p. 141

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Lucyano J. A. Macedo, Rodrigo M. Iost, Ayaz Hassan, Kannan Balasubramanian, Frank N. Crespilho
Bioelectronics and Interfaces Using Monolayer Graphene [Review]
CHEMELECTROCHEM 2019, vol. 6, p. 31

Maofeng Zhang, Tun Chen, Yongkai Liu, Jiping Zhu, Jiaqin Liu, Yucheng Wu
Front Cover: Three-Dimensional TiO2−Ag Nanopore Arrays for Powerful Photoinduced Enhanced Raman Spectroscopy (PIERS) and Versatile Detection of Toxic Organics (ChemNanoMat 1/2019) [Cover Picture]
ChemNanoMat 2019, vol. 5, p. 1

A. Suresh Kumar, Guguloth Thirupathi, G. Surendra Reddy, Dhevalapally B. Ramachary
Stereoselective Insertion of Benzynes into Lawsones: Synthesis of Biologically Important Benzannulated Bicyclo[3.3.0]octanes [Communication]
Chem. Eur. J. 2019, vol. 25, p. 1177

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, p. 2696

Yunhe Jin, Hua Fu
Visible-Light Photoredox Decarboxylative Couplings [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, p. 368

Hartmut Beck, Mario Jeske, Kai Thede, Friederike Stoll, Ingo Flamme, Metin Akbaba, Jens-Kerim Ergüden, Gunter Karig, Jörg Keldenich, Felix Oehme, Hans-Christian Militzer, Ingo V. Hartung, Uwe Thuss
Discovery of Molidustat (BAY 85-3934): A Small-Molecule Oral HIF-Prolyl Hydroxylase (HIF-PH) Inhibitor for the Treatment of Renal Anemia [Full Paper]
ChemMedChem 2018, vol. 13, p. 988

György Tarczay, Marko Förstel, Sándor Góbi, Pavlo Maksyutenko, Ralf I. Kaiser
Cover Picture: Synthesis of the Smallest Member of the Silylketene Family: H3SiC(H)=C=O (ChemPhysChem 8/2017) [Cover Picture]
ChemPhysChem 2017, vol. 18, p. 865

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, p. 24

Junting Hong, Man Li, Jianning Zhang, Beiqi Sun, Fanyang Mo
C−H Bond Carboxylation with Carbon Dioxide [Review]
ChemSusChem 2019, vol. 12, p. 6

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Elementerätsel I [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, p. 55

Titelbild: (CHEMKON 8/2018) [Titelbild]
CHEMKON 2018, vol. 25, p. 313

Jun Huang, Zhangquan Peng
Understanding the Reaction Interface in Lithium-Oxygen Batteries [Minireview]
Batteries & Supercaps 2019, vol. 2, p. 37

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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