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European Journal of Inorganic Chemistry

Synthesis and Structure of Tin and Germanium Complexes as Precursors Containing Alkoxyaminoalkoxide Ligands for Thin Film Transistors

Published: 26 May 2020

Author(s): Ga Yeon Lee, Ji Hun Lee, Seong Ho Han, Bo Keun Park, Seung Uk Son, Chang Gyoun Kim, Dong Ju Jeon, Taek‐Mo Chung

This paper describes the preparation of four novel Sn and Ge complexes containing alkoxyaminoalkoxide type ligands {L1H = 1‐[methoxy(methyl)amino]‐2‐methylpropan‐2‐ol; L2H = 1‐[methoxy(methyl)amino]‐2‐methylbutan‐2‐ol} for potential use as precursors for thin film transistors. All compounds were prepared at room temperature by stirring a solution containing Sn(btsa)2 [btsa = bis(trimethylsilyl)amide] or Ge(btsa)2 with two equivalents of L1H or L2H to form Sn(L1)2 (1), Sn(L2)2 (2), Ge(L1)2 (3)...

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European Journal of Organic Chemistry

Design of Hydrazone‐Modified 1,8‐Naphthalimides as Fluorogenic Click Probes Based on Nitrile Imine‐Alkyne Cycloaddition

Published: 26 May 2020

Author(s): Xiang Li, Yongcheng Wang, Hong Yang, Dali Yin, Yulin Tian

We designed four 4‐hydrazone‐1,8‐naphthalimides as novel fluorogenic click probes, from which the in situ generated nitrile imines react with bicyclo[6.1.0]nonyne through strain‐promoted 1,3‐dipolar cycloaddition. The resulting pyrazole cycloadducts were found to be highly fluorescent with compelling photophysical properties, including large stokes shift (up to 152 nm), high fluorescence quantum yields (up to 0.85), and notable fluorescence enhancement (up to 196.9‐fold). Density functional...

thumbnail image: European Journal of Organic Chemistry

European Journal of Inorganic Chemistry

Diiminepyridine‐Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry

Published: 26 May 2020

Author(s): Paul A. Gray, Jason D. Braun, Naser Rahimi, David E. Herbert

Diiminepyridines (DIP) are popular redox “non‐innocent” ligands with widespread application in late, first‐row transition metal mediated catalysis and coordination chemistry. Here, we report the isolation and characterization of a pair of phosphorus coordination complexes in the +1 and +3 oxidation states supported by the same ligand framework bearing sterically imposing and electron‐releasing tBu substituents on the imine carbons of the DIP backbone. Electrochemical analysis demonstrates that...

European Journal of Organic Chemistry

Head‐to‐Tail Dimerization of 4‐Fluoroacetophenone in the KOH/DMSO Superbase Suspension and Related SNAr Reaction

Published: 26 May 2020

Author(s): Ivan A. Bidusenko, Elena Yu. Schmidt, Igor' A. Ushakov, Vladimir B. Orel, Damir Z. Absalyamov, Nadezhda M. Vitkovskaya, Boris A. Trofimov

The head‐to‐tail autocondensation of 4‐fluoroacetophenone in the KOH/DMSO superbase suspension stops on dimerization step affording 4‐acetylbenzyl‐4'‐fluorophenylketone in 96 % yield. Further condensation of the diketone formed is prevented by a weaker electron‐withdrawing effect of enolate spacer, –CH=C(OK)–. 2‐Fluoro‐ and 3‐fluoroacetophenones are inactive in this reaction. Other superbases of the type MOR/DMSO (M = Na, K; R = H, OBut) are inferior in promotion of this reaction providing...

European Journal of Inorganic Chemistry

Iridium Carbene and Carbamoyl Complexes Supported by a Tetradentate Pyridine‐Carboxamide Ligand

Published: 26 May 2020

Author(s): Kai‐Hong Wong, Wai‐Man Cheung, Herman H. ‐Y. Sung, Ian D. Williams, Wa‐Hung Leung

The nucleophilic attack of an IrIII isocyanide complex bearing a tetradentate pyridine‐carboxamide ligand with amines to give carbene and carbamoyl complexes has been studied. The treatment of Na[Ir(bpb)Cl2] {bpb2– = dianion of 1,2‐bis(2‐pyridinecarboxamido)benzene} with PR3 (R = p‐tolyl) in refluxing glycol gave [Ir(bpb)(PR3)Cl] (1). Chloride abstraction of 1 with silver tosylate (AgOTs) led to isolation of a mixture of [Ir(bpb)(PR3)(OTs)] (2a) and [Ir(bpb)(PR3)(H2O)](OTs) (2b) that reacted...

ChemPlusChem

Bioorthogonal Phosphorogenic Rhenium(I) Polypyridine Sydnone Complexes for Specific Lysosome Labeling

Published: 25 May 2020

Author(s): Justin Shum, Pei‐Zhi Zhang, Lawrence Cho‐Cheung Lee, Kenneth Kam‐Wing Lo

ChemCatChem

Renewable RGO@CuI Nanocomposites for Redox Triggered Single Electron Transfer (SET) Reaction Under Aerobic and Anaerobic Conditions

Published: 25 May 2020

Author(s): Upasana Gulati, U. Chinna Rajesh, Diwan S. Rawat

Abstract Renewable mineral derived nanocatalysts are of special interest to accomplish green and sustainable goals with unique advantages over homogeneous catalysts such as recyclability, robustness, superior activity and minimum waste generation. Here, we synthesized reduced graphene oxide supported copper iodide (RGO@CuI) nanocomposites from renewable malachite mineral derived RGO@CuO precursor by treatment with NH2OH and KI in water. The characterization results reveal the role of RGO...

ChemPhysChem

Effects of Solid Electrolyte Interphase Components on the Reduction of LiFSI over Lithium Metal

Published: 25 May 2020

Author(s): Ethan P. Kamphaus, Stefany Angarita Gomez, Xueping Qin, Minhua Shao, Perla B. Balbuena

Abstract The use of a lithium metal anode still presents a challenging chemistry and engineering problem that holds back next generation lithium battery technology. One of the issues facing lithium metal is the presence of the solid electrolyte interphase (SEI) layer that forms on the electrode creating a variety of chemical species that change the properties of the electrode and is closely related to the formation and growth of lithium dendrites. In order to advance the scientific progress of...

ChemPhysChem

Raman Optical Activity of Glucose and Sorbose in Extended Wavenumber Range

Published: 25 May 2020

Author(s): Vladimír Palivec, Pavel Michal, Josef Kapitán, Hector Martinez‐Seara, Petr Bouř

Abstract Raman optical activity (ROA) is pursued as a promising method for structural analyses of sugars in aqueous solutions. In the present study, experimental Raman and ROA spectra of glucose and sorbose obtained in an extended range (50–4000 cm−1) are interpreted using molecular dynamics and density functional theory, with the emphasis on CH stretching modes. A reasonable theoretical basis for spectral interpretation was obtained already at the harmonic level. Anharmonic corrections led to...

European Journal of Organic Chemistry

Arylboronic Acids and their Myriad of Applications Beyond Organic Synthesis

Published: 25 May 2020

Author(s): Noemi de Jesus Hiller, Nayane Abreu do Amaral e Silva, Thais Apolinário Tavares, Robson Xavier Faria, Marcos Nogueira Eberlin, Daniela de Luna Martins

Boron organometallic compounds are mainly known for their great value in organic synthesis to construct biaryls in Suzuki couplings, for arylations of olefins, for C–S, C–O, and C–N couplings or as organometallic catalysts. Herein, using arylboronic acids (Ar‐B(OH)2) as a illustrative case, we review the applications of these highly versatile molecules which expands much beyond their commonly perceived uses. Seeing primarily as “mere” intermediates in organic synthesis and organometallic...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

January 2020


	Hendrik Naatz, Bella B. Manshian, Carla Rios Luci, Vasiliki Tsikourkitoudi, Yiannis Deligiannakis, Johannes Birkenstock, Suman Pokhrel, Lutz Mädler, Stefaan J. Soenen Model-Based Nanoengineered Pharmacokinetics of Iron-Doped Copper Oxide for Nanomedical Applications [Research Article] Angew. Chem. Int. Ed. 2020, vol. 59, no. 5, p. 1828

	Marc-André Kasper, Marcus Gerlach, Anselm F. L. Schneider, Christiane Groneberg, Philipp Ochtrop, Stefanie Boldt, Dominik Schumacher, Jonas Helma, Heinrich Leonhardt, Mathias Christmann, Christian P. R. Hackenberger N-Hydroxysuccinimide-Modified Ethynylphosphonamidates Enable the Synthesis of Configurationally Defined Protein Conjugates [Full Paper] ChemBioChem 2020, vol. 21, no. 1-2, p. 113

	Michael Bowker Methanol Synthesis from CO₂ Hydrogenation [Minireview] ChemCatChem 2019, vol. 11, no. 17, p. 4238

	V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, no. 5, p. 401

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Rüdiger-A. Eichel, Walter Leitner, Kurt Wagemann Warum wir uns mit Power-to-X beschäftigen [Editorial] Chem. Ing. Tech. 2020, vol. 92, no. 1-2, p. 3

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Claire M. Cobley Introducing our Inaugural Early Career Advisory Board [Editorial] ChemNanoMat 2020, vol. 6, no. 1, p. 4

	Felix Blei, Sebastian Dörner, Janis Fricke, Florian Baldeweg, Felix Trottmann, Anna Komor, Florian Meyer, Christian Hertweck, Dirk Hoffmeister Simultaneous Production of Psilocybin and a Cocktail of β-Carboline Monoamine Oxidase Inhibitors in “Magic” Mushrooms [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 3, p. 729

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

	Thomas H. Pillow, Pragya Adhikari, Robert A. Blake, Jinhua Chen, Geoffrey Del Rosario, Gauri Deshmukh, Isabel Figueroa, Karen E. Gascoigne, Amrita V. Kamath, Susan Kaufman, Tracy Kleinheinz, Katherine R. Kozak, Brandon Latifi, Douglas D. Leipold, Chun Sing Li, Ruina Li, Melinda M. Mulvihill, Aimee O'Donohue, Rebecca K. Rowntree, Jack D. Sadowsky, John Wai, Xinxin Wang, Cong Wu, Zijin Xu, Hui Yao, Shang-Fan Yu, Donglu Zhang, Richard Zang, Hongyan Zhang, Hao Zhou, Xiaoyu Zhu, Peter S. Dragovich Antibody Conjugation of a Chimeric BET Degrader Enables in vivo Activity [Full Paper] ChemMedChem 2020, vol. 15, no. 1, p. 17

	Vitali Tugarinov, Theodoros K. Karamanos, Alberto Ceccon, G. Marius Clore Optimized NMR Experiments for the Isolation of I=1/2 Manifold Transitions in Methyl Groups of Proteins [Communication] ChemPhysChem 2020, vol. 21, no. 1, p. 13

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, no. 5, p. 386

	Kassem Beydoun, Jürgen Klankermayer Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing [Communication] ChemSusChem 2020, vol. 13, no. 3, p. 488

	Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief The Periodic Table of the Chemical Elements and Sustainable Development [Essay] Eur. J. Inorg. Chem. 2019, p. 4170

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Cover Picture Lebensmittelchemie 6/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73, no. 6

	Christian Hering-Junghans, Christian Sindlinger Trendbericht Anorganische Chemie: Hauptgruppen [Wissenschaft + Forschung] Nachr. Chem. 2020, vol. 68, no. 1, p. 50

	Jana Novotny, Corina Wagner, Marco Oetken Titelbild: Elektrochemisch aktive Polymere am Beispiel Polypyrrol: Modellsystem einer künstlichen Synapse Ein elektrochemischer Alleskönner - Teil 2 (CHEMKON 8/2019) [Titelbild] CHEMKON 2019, vol. 26, no. 8, p. 331

	Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar 3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review] Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.


	Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

	Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836

	Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544

	Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826

	Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845

	Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335

	Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

	Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789

	Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

	Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501

	Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512

	Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158

	Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90

	Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560

	Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362

	Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68

	Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe₃O₄@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826