ChemPubSoc Europe Early View Journal Articles
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Chemistry - A European Journal
Published: 18 May 2021
Author(s): Ruben Mirzoyan, Nathanael P. Kazmierczak, Ryan G. Hadt
Abstract In the past decade, transition metal complexes have gained momentum as electron spin‐based quantum bit (qubit) candidates due to their synthetic tunability and long achievable coherence times. The decoherence of magnetic quantum states imposes a limit on the use of these qubits for quantum information technologies, such as quantum computing, sensing, and communication. With rapid recent development in the field of molecular quantum information science, a variety of chemical design...
Chemistry - A European Journal
Intrinsic Molybdenum‐Based POMOFs with Impressive Gas Adsorptions and Photochromism
Published: 18 May 2021
Author(s): Lan Deng, Xin Dong, Zhao‐Hui Zhou
Abstract Novel molybdenum(VI/V) POM‐based self‐constructed frameworks [MoVI12O24(μ2‐O)12(trz)6(H2O)6] ⋅ 6Hma ⋅ 18H2O (1, Htrz=1H‐1,2,3‐triazole, ma=methylamine), [MoVI7O14(μ2‐O)8(trz)5(H2O)] ⋅ 7Hma ⋅ 5H2O (2), Na3[MoV6O6(μ2‐O)9(Htrz)3(trz)3] ⋅ 7.5H2O (3) and [MoV8O8(μ2‐O)12(Htrz)8] ⋅ 30H2O (4) have been covalently decorated with tri‐coordinated deprotonated/protonated 1,2,3‐triazoles. Channels with an inner diameter of 7.5 Å were found in 1, whereas a tunnel composed of stacking molecules with...
Chemistry - A European Journal
Synergistic Effect of NiLDH@YZ Hybrid and Mechanochemical Agitation on Glaser Homocoupling Reaction
Published: 17 May 2021
Author(s): Mohamed Mokhtar, Ghalia Alzhrani, Elham S. Aazam, Tamer S. Saleh, Sulaiman Al‐Faifi, Subir Panja, Debabrata Maiti
Abstract Herein, we report the synthesis of nickel‐layered double hydroxide amalgamated Y‐zeolite (NiLDH@YZ) hybrids and the evaluation of the synergistic effect of various NiLDH@YZ catalysts and mechanochemical agitation on Glaser homocoupling reactions. Nitrogen adsorption‐desorption experiments were carried out to estimate the surface area and porosity of NiLDH@YZ hybrids. The basicity and acidity of these hybrids were determined by CO2‐TPD and NH3‐TPD experiments respectively and this...
Chemistry - A European Journal
Published: 17 May 2021
Author(s): Tetsuji Yata, Yoshihiro Nishimoto, Kouji Chiba, Makoto Yasuda
Abstract Fluorinated heterocycles have attracted much attention in the pharmaceutical and agrochemical industries. Many strategies have already been developed to achieve the synthesis of fluorinated heterocycles. Formidable challenges remain, however, in the synthesis of fluorinated isocoumarin derivatives that are among the most alluring structural motifs. Herein, the indium‐catalyzed C−F bond transformation of 2‐(2,2‐difluorovinyl) benzoates is reported, which are readily accessible...
Chemistry - A European Journal
Published: 17 May 2021
Author(s): Verónica Almeida‐Marrero, Marta Mascaraque, María Jesús Vicente‐Arana, Ángeles Juarranz, Tomás Torres, Andrés Escosura
Abstract In the endeavor of extending the clinical use of photodynamic therapy (PDT) for the treatment of superficial cancers and other neoplastic diseases, deeper knowledge and control of the subcellular processes that determine the response of photosensitizers (PS) are needed. Recent strategies in this direction involve the use of activatable and nanostructured PS. Here, both capacities have been tuned in two dendritic zinc(II) phthalocyanine (ZnPc) derivatives, either asymmetrically or...
Chemistry - A European Journal
Trends in Conjugated Chalcogenophenes: A Theoretical Study
Published: 17 May 2021
Author(s): Valentina Topolskaia, Adam A. Pollit, Susan Cheng, Dwight S. Seferos
Abstract Heavy atom substitution in chalcogenophenes is a versatile strategy for tailoring and ultimately improving conjugated polymer properties. While thiophene monomers are commonly implemented in polymer designs, relatively little is known regarding the molecular properties of the heavier chalcogenophenes. Herein, we use density functional theory (DFT) calculations to examine how group 16 heteroatoms, including the radioactive polonium, affect polychalcogenophene properties including bond...
Chemistry - A European Journal
Published: 17 May 2021
Author(s): Alberto Feliciano, Juan L. Vázquez, Luis J. Benítez‐Puebla, Iván Velazco‐Cabral, David Cruz Cruz, Francisco Delgado, Miguel A. Vázquez
Abstract The structure of Fischer carbene complexes (FCCs) is electron deficient. If bearing an α,β‐unsaturated system, it can generate a wide variety of compounds by undergoing many different transformations, including higher‐order cycloadditions. The latter are described as pericyclic reactions in which more than six electrons participate. These reactions have been employed in various areas of organic synthesis, resulting in highly selective compounds with a broad range of scaffolds. The...
Chemistry - A European Journal
Published: 17 May 2021
Author(s): Takuji Kawamoto, Kohki Noguchi, Ryotaro Takata, Rio Sasaki, Hiroshi Matsubara, Akio Kamimura
Abstract The redox‐neutral tetrafluoroethylation of alkynes with 1,1,2,2‐tetrafluroroethanesulfonic acid (TFESA) and azobis(isobutyronitrile) (AIBN) proceeds via the formation of vinyl tetrafluoroethanesulfonates followed by a radical tetrafluoroethylation. Experimental and theoretical results support an intermolecular reaction.
Chemistry - A European Journal
Published: 17 May 2021
Author(s): Matthias Ferger, Sarina M. Berger, Florian Rauch, Markus Schönitz, Jessica Rühe, Johannes Krebs, Alexandra Friedrich, Todd B. Marder
Abstract A novel and convenient methodology for the one‐pot synthesis of sterically congested triarylboranes by using bench‐stable aryltrifluoroborates as the boron source is reported. This procedure gives systematic access to symmetrically and unsymmetrically substituted triarylboranes of the types BAr2Ar’ and BArAr'Ar’’, respectively. Three unsymmetrically substituted triarylboranes as well as their iridium‐catalyzed C−H borylation products are reported. These borylated triarylboranes...
Chemistry - A European Journal
Cooperative Ligands in Dissolution of Gold
Published: 17 May 2021
Author(s): Eeva Heliövaara, Henri Liljeqvist, Mikko Muuronen, Aleksi Eronen, Karina Moslova, Timo Repo
Abstract Development of new, environmentally benign dissolution methods for metallic gold is driven by needs in the circular economy. Gold is widely used in consumer electronics, but sustainable and selective dissolution methods for Au are scarce. Herein, we describe a quantitative dissolution of gold in organic solution under mild conditions by using hydrogen peroxide as an oxidant. In the dissolution reaction, two thiol ligands, pyridine‐4‐thiol and 2‐mercaptobenzimidazole, work in a...
Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal
March 2021
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Yunqi Shao, Lisanne Knijff, Florian M. Dietrich, Kersti Hermansson, Chao Zhang Modelling Bulk Electrolytes and Electrolyte Interfaces with Atomistic Machine Learning [Minireview] Batteries & Supercaps 2021, vol. 4, no. 4, p. 585 |
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Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview] ChemBioChem 2021, vol. 22, no. 7, p. 1176 |
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Christian M. Heckmann, Francesca Paradisi Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review] ChemCatChem 2020, vol. 12, no. 24, p. 6082 |
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Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395 |
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Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837 |
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Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication] ChemistryOpen 2020, vol. 9, no. 7, p. 743 |
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Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055 |
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Antoine Daina, Vincent Zoete A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication] ChemMedChem 2016, vol. 11, no. 11, p. 1117 |
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Sebastian Gisbertz, Bartholomäus Pieber Heterogeneous Photocatalysis in Organic Synthesis [Review] ChemPhotoChem 2020, vol. 4, no. 7, p. 456 |
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Trevor A. Hamlin, Marcel Swart, F. Matthias Bickelhaupt Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent [Minireview] ChemPhysChem 2018, vol. 19, no. 11, p. 1315 |
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Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453 |
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Thomas Aro, Pedram Fatehi Production and Application of Lignosulfonates and Sulfonated Lignin [Review] ChemSusChem 2017, vol. 10, no. 9, p. 1861 |
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Carolin Hoyer, Peter Schwerk, Lisa Suntrup, Julia Beerhues, Maite Nössler, Uta Albold, Jens Dernedde, Karsten Tedin, Biprajit Sarkar Synthesis, Characterization, and Evaluation of Antibacterial Activity of Ferrocenyl-1,2,3-Triazoles, Triazolium Salts, and Triazolylidene Complexes of Gold(i) and Silver(i) [Full Paper] Eur. J. Inorg. Chem. 2021, p. 1373 |
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Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056 |
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Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016 |
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Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper] Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636 |
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Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696 |
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Daojin Zhou, Pengsong Li, Wenwen Xu, Sana Jawaid, Jamesh Mohammed-Ibrahim, Wen Liu, Yun Kuang, Xiaoming Sun Recent Advances in Non-Precious Metal-Based Electrodes for Alkaline Water Electrolysis [Minireview] ChemNanoMat 2020, vol. 6, no. 3, p. 336 |
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Huaibo Zhao, Daniele Leonori Minimization of Back-Electron Transfer Enables the Elusive sp3 C−H Functionalization of Secondary Anilines [Communication] Angew. Chem. Int. Ed. 2021, vol. 60, no. 14, p. 7669 |
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Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75 |
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Özge Çepelioğullar Mutlu, Thomas Zeng Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A Review [Review] Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674 |
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Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review] Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596 |
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Emiliano Feresin*, Mykhailo Kondratiuk, Julia Nowack, Lukas Gooßen* Handreinigung auf molekularer Ebene - Die Rolle der Solvatation [Artikel] Chem. Unserer Zeit 2021, vol. 55, no. 1, p. 28 |
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Hilbert Meyer Guter Unterricht an guten Schulen? [Aufsatz] CHEMKON 2006, vol. 13, no. 2, p. 77 |
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Bambus in Coffee-to-go-Bechern [Analytik] Lebensmittelchemie 2021, vol. 75, no. 1, p. 2 |
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Jan Paradies, Jennifer Andexer, Uwe Beifuss, Florian Beuerle, Malte Brasholz, Rolf Breinbauer, Martin Ernst, Ruth Ganardi, Tobias A. M. Gulder, Wolfgang Hüttel, Stephanie Kath-Schorr, Karsten Körber, Markus Kordes, Matthias Lehmann, Thomas Lindel, Burkhard Luy, Christian Mück-Lichtenfeld, Claudia Muhle-Goll, Jochen Niemeyer, Roland Pfau, Jörg Pietruszka, Johannes L. Röckl, Norbert Schaschke, Mathias O. Senge, Bernd F. Straub, Siegfried R. Waldvogel, Thomas Werner, Daniel B. Werz, Christian Winter Organische Chemie [Wissenschaft + Forschung] Nachr. Chem. 2021, vol. 69, no. 3, p. 38 |
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Most cited articles from Chemistry Europe, ACES, and GDCh journals
Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.
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Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication] Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941 |
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Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review] Batteries Supercaps 2018, vol. 1, pp. 41–68 |
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Lik Hang Yuen, Raphael M. Franzini Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview] ChemBioChem 2017, vol. 18, pp. 829–836 |
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Konstantinos C. Christoforidis, Paolo Fornasiero Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review] ChemCatChem 2017, vol. 9, pp. 1523–1544 |
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Marwa Elkady, Hassan Shokry, Hesham Hamad Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article] Chem. Eng. Technol. 2018, vol. 41, pp. 553–562 |
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Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview] ChemistryOpen 2018, vol. 7, pp. 169–179 |
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Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, pp. 945–956 |
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Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper] ChemistrySelect 2018, vol. 3, pp. 1820–1826 |
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Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review] Chem. Ing. Tech. 2018, vol. 90, pp. 17–35 |
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Sayantani Sikdar, Madhusree Kundu A Review on Detection and Abatement of Heavy Metals [Review] ChemBioEng Rev. 2018, vol. 5, pp. 18–29 |
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Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication] ChemElectroChem 2017, vol. 4, pp. 1840–1845 |
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Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper] ChemNanoMat 2017, vol. 3, pp. 328–335 |
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Chengwei Liu, Michal Szostak Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview] Chem. Eur. J. 2017, vol. 23, pp. 7157–7173 |
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Jian Shu, Dianping Tang Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review] Chem. Asian J. 2017, vol. 12, pp. 2780–2789 |
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Jian Rong, Chuanfa Ni, Jinbo Hu Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review] Asian J. Org. Chem. 2017, vol. 6, pp. 139–152 |
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Juan Alberto Sirvent, Ulrich Lücking Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper] ChemMedChem 2017, vol. 12, pp. 487–501 |
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Grzegorz Greczynski, Lars Hultman C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication] ChemPhysChem 2017, vol. 18, pp. 1507–1512 |
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Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept] ChemPhotoChem 2017, vol. 1, pp. 148–158 |
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Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication] ChemSusChem 2017, vol. 10, pp. 87–90 |
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Enzo Alessio Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview] Eur. J. Inorg. Chem. 2017, pp. 1549–1560 |
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Marcel Garbe, Kathrin Junge, Matthias Beller Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview] Eur. J. Org. Chem. 2017, pp. 4344–4362 |
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