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Chemistry - A European Journal

Fluorescent‐Labeled Octasilsesquioxane Nanohybrids as Potential Materials for Latent Fingerprinting Detection

Published: 17 September 2020

Author(s): Enock O. Dare, Victoria Vendrell‐Criado, M. Consuelo Jiménez, Raúl Pérez‐Ruiz, David Díaz Díaz

Abstract The recent demand for fluorescent‐labeled materials (FLMs) in forensic security concepts such as latent fingerprints (LFs) that encode information for anti‐counterfeiting and encryption of confidential data makes necessary the development of building new and innovative materials. Here, novel FLMs based on polyhedral oligomeric silsesquioxanes (POSS) functionalized with fluorophores via “click” reactions have been successfully synthesized and fully characterized. A comprehensive study...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry

Published: 17 September 2020

Author(s): Johannes D. R. Ascherl, Christian Neiß, Alexander Vogel, Jürgen Graf, Frank Rominger, Thomas Oeser, Frank Hampel, Andreas Görling, Milan Kivala

Abstract A concise synthetic route towards a new family of phosphorus‐containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X‐ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Photocatalytic Reductive Radical‐Polar Crossover for a Base‐Free Corey–Seebach Reaction

Published: 17 September 2020

Author(s): Karsten Donabauer, Kathiravan Murugesan, Urša Rozman, Stefano Crespi, Burkhard König

Abstract A metal‐free generation of carbanion nucleophiles is of prime importance in organic synthesis. Herein we report a photocatalytic approach to the Corey–Seebach reaction. The presented method operates under mild redox‐neutral and base‐free conditions giving the desired product with high functional group tolerance. The reaction is enabled by the combination of photo‐ and hydrogen atom transfer (HAT) catalysis. This catalytic merger allows a C−H to carbanion activation by the abstraction...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Stabilizing DNAzymes through Encapsulation in a Metal–Organic Framework

Published: 17 September 2020

Author(s): Huiye Zhong, Wei‐Shang Lo, Tiantian Man, Benjamin P. Williams, Dan Li, Sheng‐Yu Chen, Hao Pei, Li Li, Chia‐Kuang Tsung

Abstract DNAzymes are a promising class of bioinspired catalyst; however, their structural instability limits their potential. Herein, a method to stabilize DNAzymes by encapsulating them in a metal–organic framework (MOF) host is reported. This biomimetic mineralization process makes DNAzymes active under a wider range of conditions. The concept is demonstrated by encapsulating hemin‐G‐quadruplex (Hemin‐G4) into zeolitic imidazolate framework‐90 (ZIF‐90), which indeed increases the DNAzyme's...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Light‐Driven Active Ion Transport

Published: 17 September 2020

Author(s): Jinlei Yang, Pengchao Liu, Lianshan Li, Zhiyong Tang

Abstract Solar energy can be harvested by biological systems to regulate the directional transport of protons and ions across cells and organelles. Structural and functional bio‐mimic photo‐active ion nanofluidic conductors, usually in the forms of ion channels and ion pumps, have been increasingly applied to realize active ion transport. However, progress in attaining effective light‐driven active transport of ions (protons) has been constrained by the inherent limitations of membrane...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Oak‐Associated Negativicute Equipped with Ancestral Aromatic Polyketide Synthase Produces Antimycobacterial Dendrubins

Published: 17 September 2020

Author(s): Keishi Ishida, Gulimila Shabuer, Sebastian Schieferdecker, Sacha J. Pidot, Timothy P. Stinear, Uwe Knuepfer, Michael Cyrulies, Christian Hertweck

Abstract Anaerobic bacteria have only recently been recognized as a source of antibiotics; yet, the metabolic potential of Negativicutes (Gram‐negative staining Firmicutes) such as the oak‐associated Dendrosporobacter quercicolus has remained unknown. Genome mining of D. quercicolus and phylogenetic analyses revealed a gene cluster for a type II polyketide synthase (PKS) complex that belongs to the most ancestral enzyme systems of this type. Metabolic profiling, NMR analyses, and...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

A Visible‐Light‐Powered Polymerization Method for the Immobilization of Enantioselective Organocatalysts into Microreactors

Published: 17 September 2020

Author(s): Rico Warias, Daniele Ragno, Alessandro Massi, Detlev Belder

Abstract A versatile one‐step photopolymerization approach for the immobilization of enantioselective organocatalysts is presented. Chiral organocatalyst‐containing monoliths based on polystyrene divinylbenzene copolymer were generated inside channels of microfluidic chips. Exemplary performance tests were performed for the monolithic Hayashi–Jørgensen catalyst in continuous flow, which showed good results for the Michael addition of aldehydes to nitroalkenes in terms of stereoselectivity and...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

In Silico Anticipation of Metabolic Pathways Extended to Organic Chemistry Reactions: A Case Study with Caffeine Alkaline Hydrolysis and The Origin of Camellimidazoles

Published: 17 September 2020

Author(s): Victor Turpin, Mehdi A. Beniddir, Grégory Genta‐Jouve, Adam Skiredj, Jean‐François Gallard, Karine Leblanc, Pierre Le Pogam, Erwan Poupon

Abstract Camellimidazoles A–C were recently reported as natural substances in Keemun black tea. Although a “biosynthetic” route to these intriguing imidazole dimers was proposed from caffeine by the authors in this seminal report, we envisioned that a artefactual scenario, consisting of alkaline hydrolysis of caffeine and spontaneous cascade reactions with a methylene donor such as formaldehyde or methylene chloride, could also have led to their formation. To capture the diversity of molecules...

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Cobalt‐Catalyzed α‐Arylation of Substituted α‐Bromo α‐Fluoro β‐Lactams with Diaryl Zinc Reagents: Generalization to Functionalized Bromo Derivatives

Published: 17 September 2020

Author(s): Mélanie M. Lorion, Vanessa Koch, Martin Nieger, Hi‐Yung Chen, Aiwen Lei, Stefan Bräse, Janine Cossy

Abstract A cobalt‐catalyzed cross‐coupling of α‐bromo α‐fluoro β‐lactams with diarylzinc or diallylzinc reagents is herein disclosed. The protocol proved to be general, chemoselective and operationally simple allowing the C4 functionalization of β‐lactams. The substrate scope was expanded to α‐bromo lactams and amides, α‐bromo lactones and esters as well as N‐ and O‐containing heterocycles.

thumbnail image: Chemistry - A European Journal

Chemistry - A European Journal

Formation of Highly Ordered Molecular Porous 2D Networks from Cyano‐Functionalized Porphyrins on Cu(111)

Published: 17 September 2020

Author(s): Rajan Adhikari, Gretel Siglreithmaier, Martin Gurrath, Manuel Meusel, Jan Kuliga, Michael Lepper, Helen Hölzel, Norbert Jux, Bernd Meyer, Hans‐Peter Steinrück, Hubertus Marbach

Abstract We investigated the adsorption of three related cyano‐functionalized tetraphenyl porphyrin derivatives on Cu(111) by scanning tunneling microscopy (STM) in ultra‐high vacuum (UHV) with the goal to identify the role of the cyano group and the central Cu atom for the intermolecular and supramolecular arrangement. The porphyrin derivatives studied were Cu‐TCNPP, Cu‐cisDCNPP, and 2H‐cisDCNPP, that is, Cu‐5,10,15,20‐tetrakis‐(p‐cyano)‐phenylporphyrin,...

thumbnail image: Chemistry - A European Journal

Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

June 2020

 


Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar
3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review]
Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

Friso S. Aalbers, Marco W. Fraaije
Enzyme Fusions in Biocatalysis: Coupling Reactions by Pairing Enzymes [Minireview]
ChemBioChem 2019, vol. 20, no. 1, p. 20

Ulrich S. Schubert, Andreas Winter
Metal-Terpyridine Complexes in Catalytic Application - A Spotlight on the Last Decade [Review]
ChemCatChem 2020, vol. 12, no. 11, p. 2890

Gerhard Hilt
Basic Strategies and Types of Applications in Organic Electrochemistry [Concept]
ChemElectroChem 2020, vol. 7, no. 2, p. 395

Andreas Schaate, Pascal Roy, Adelheid Godt, Jann Lippke, Florian Waltz, Michael Wiebcke, Peter Behrens
Modulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals [Full Paper]
Chem. Eur. J. 2011, vol. 17, no. 24, p. 6643

Marya A. Gromova, Yurii V. Kharitonov, Irina Yu. Bagryanskaya, Elvira E. Shults
Efficient Synthesis of the N-(buta-2,3-dienyl)carboxamide of Isopimaric Acid and the Potential of This Compound towards Heterocyclic Derivatives of Diterpenoids [Full Paper]
ChemistryOpen 2018, vol. 7, no. 11, p. 890

Tran Thi Ai My, Huynh Thi Phuong Loan, Nguyen Thi Thanh Hai, Le Trung Hieu, Tran Thai Hoa, Bui Thi Phuong Thuy, Duong Tuan Quang, Nguyen Thanh Triet, Tran Thi Van Anh, Nguyen Thi Xuan Dieu, Nguyen Tien Trung, Nguyen Van Hue, Pham Van Tat, Vo Thanh Tung, Nguyen Thi Ai Nhung
Evaluation of the Inhibitory Activities of COVID-19 of Melaleuca cajuputi Oil Using Docking Simulation [Full Paper]
ChemistrySelect 2020, vol. 5, no. 21, p. 6312

Dana Shahabi, Mackenzie E. Chapman, Margherita Brindisi, Arun K. Ghosh, Andrew D. Mesecar
Drug Development and Medicinal Chemistry Efforts toward SARS-Coronavirus and Covid-19 Therapeutics [Review]
ChemMedChem 2020, vol. 15, no. 11, p. 907

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, no. 5, p. 386

Thomas G. Mayerhöfer, Alicja Dabrowska, Andreas Schwaighofer, Bernhard Lendl, Jürgen Popp
Beyond Beer's Law: Why the Index of Refraction Depends (Almost) Linearly on Concentration [Communication]
ChemPhysChem 2020, vol. 21, no. 8, p. 707

Thomas Aro, Pedram Fatehi
Production and Application of Lignosulfonates and Sulfonated Lignin [Review]
ChemSusChem 2017, vol. 10, no. 9, p. 1861

Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Braun-Cula, Francesc Lloret, Miguel Julve
Synthesis, Crystal Structure and Magnetic Properties of Three {CrIIIMnII} Heterodimetallic Complexes Based on Heteroleptic Cyanido-Bearing CrIII Building Blocks [Full Paper]
Eur. J. Inorg. Chem. 2018, p. 349

Anna Eisenhofer, Johnny Hioe, Ruth M. Gschwind, Burkhard König
Photocatalytic Phenol-Arene C-C and C-O Cross-Dehydrogenative Coupling [Full Paper]
Eur. J. Org. Chem. 2017, p. 2194

Daewoo Han, Andrew J. Steckl
Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review]
ChemPlusChem 2019, vol. 84, no. 10, p. 1453

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

Elena V. Ushakova, Sergei A. Cherevkov, Anastasiia V. Sokolova, Yanxiu Li, Ruslan R. Azizov, Mikhail A. Baranov, Dmitry A. Kurdyukov, Ekaterina Yu Stovpiaga, Valery G. Golubev, Andrey L. Rogach, Alexander V. Baranov
Stable Luminescent Composite Microspheres Based on Porous Silica with Embedded CsPbBr3 Perovskite Nanocrystals [Full Paper]
ChemNanoMat 2020, vol. 6, no. 7, p. 1080

Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless
Click Chemistry: Diverse Chemical Function from a Few Good Reactions [Review]
Angew. Chem. Int. Ed. 2001, vol. 40, no. 11, p. 2004

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Uwe Hampel, Markus Schubert, Alexander Döß, Johanna Sohr, Vineet Vishwakarma, Jens-Uwe Repke, Sören J. Gerke, Hannes Leuner, Matthias Rädle, Viktoria Kapoustina, Lucas Schmitt, Marcus Grünewald, Jost H. Brinkmann, Dominik Plate, Eugeny Y. Kenig, Nicole Lutters, Lukas Bolenz, Felix Buckmann, Dominique Toye, Wolfgang Arlt, Thomas Linder, Rainer Hoffmann, Harald Klein, Sebastian Rehfeldt, Thomas Winkler, Hans-Jörg Bart, Dominic Wirz, Jonas Schulz, Stephan Scholl, Wolfgang Augustin, Katharina Jasch, Florian Schlüter, Natalie Schwerdtfeger, Stefan Jahnke, Andreas Jupke, Christoph Kabatnik, Andreas Siegfried Braeuer, Mirko D'Auria, Thomas Runowski, Maria Francisco Casal, Karsten Becker, Anna-Lena David, Andrzej Górak, Mirko Skiborowski, Kai Groß, Hina Qammar
Recent Advances in Experimental Techniques for Flow and Mass Transfer Analyses in Thermal Separation Systems [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 7, p. 926

Henrik Petersen, Klaus Roth
To Tattoo or not to Tattoo [Artikel]
Chem. Unserer Zeit 2016, vol. 50, no. 1, p. 44

Johannes Huwer, Amitabh Banerji
Corona sei Dank?! - Digitalisierung im Chemieunterricht [Editorial]
CHEMKON 2020, vol. 27, no. 3, p. 105

Masthead: Lebensmittelchemie 3/2020 [Masthead]
Lebensmittelchemie 2020, vol. 74, no. 3

Hannsjörg Freund, Robert Güttel, Raimund Horn, Ulrike Krewer, Jörg Sauer
Technische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2020, vol. 68, no. 6, p. 46

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2017 or 2018 according to Web of Science. They have contributed the most to the journal's impact factor in 2019.

 


Yuanjun Chen, Shufang Ji, Yanggang Wang, Juncai Dong, Wenxing Chen, Zhi Li, Rongan Shen, Lirong Zheng, Zhongbin Zhuang, Dingsheng Wang, Yadong Li
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction [Communication]
Angew. Chem. Int. Ed. 2017, vol. 56, pp. 6937–6941

Qian Sun, Kah Chun Lau, Dongsheng Geng, Xiangbo Meng
Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms [Review]
Batteries Supercaps 2018, vol. 1, pp. 41–68

Lik Hang Yuen, Raphael M. Franzini
Achievements, Challenges, and Opportunities in DNA-Encoded Library Research: An Academic Point of View [Minireview]
ChemBioChem 2017, vol. 18, pp. 829–836

Konstantinos C. Christoforidis, Paolo Fornasiero
Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply [Review]
ChemCatChem 2017, vol. 9, pp. 1523–1544

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, pp. 945–956

Hojat Veisi, Mozhgan Pirhayati, Ali Kakanejadifard, Pourya Mohammadi, Mohammad Reza Abdi, Javad Gholami, Saba Hemmati
In Situ Green Synthesis of Pd Nanoparticles on Tannic Acid-Modified Magnetite Nanoparticles as a Green Reductant and Stabilizer Agent: Its Application as a Recyclable Nanocatalyst (Fe3O4@TA/Pd) for Reduction of 4-Nitrophenol and Suzuki Reactions [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 1820–1826

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Tingting Liu, Lisi Xie, Jianhui Yang, Rongmei Kong, Gu Du, Abdullah M. Asiri, Xuping Sun, Liang Chen
Self-Standing CoP Nanosheets Array: A Three-Dimensional Bifunctional Catalyst Electrode for Overall Water Splitting in both Neutral and Alkaline Media [Communication]
ChemElectroChem 2017, vol. 4, pp. 1840–1845

Ruibin Wang, Liheng Chen, J.Y. Zhu, Rendang Yang
Tailored and Integrated Production of Carboxylated Cellulose Nanocrystals (CNC) with Nanofibrils (CNF) through Maleic Acid Hydrolysis [Full Paper]
ChemNanoMat 2017, vol. 3, pp. 328–335

Chengwei Liu, Michal Szostak
Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation [Minireview]
Chem. Eur. J. 2017, vol. 23, pp. 7157–7173

Jian Shu, Dianping Tang
Current Advances in Quantum-Dots-Based Photoelectrochemical Immunoassays [Focus Review]
Chem. Asian J. 2017, vol. 12, pp. 2780–2789

Jian Rong, Chuanfa Ni, Jinbo Hu
Metal-Catalyzed Direct Difluoromethylation Reactions [Focus Review]
Asian J. Org. Chem. 2017, vol. 6, pp. 139–152

Juan Alberto Sirvent, Ulrich Lücking
Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates [Full Paper]
ChemMedChem 2017, vol. 12, pp. 487–501

Grzegorz Greczynski, Lars Hultman
C 1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy [Communication]
ChemPhysChem 2017, vol. 18, pp. 1507–1512

Jia-Rong Chen, Dong-Mei Yan, Qiang Wei, Wen-Jing Xiao
Photocascade Catalysis: A New Strategy for Cascade Reactions [Concept]
ChemPhotoChem 2017, vol. 1, pp. 148–158

Zhiming Pan, Yun Zheng, Fangsong Guo, Pingping Niu, Xinchen Wang
Decorating CoP and Pt Nanoparticles on Graphitic Carbon Nitride Nanosheets to Promote Overall Water Splitting by Conjugated Polymers [Communication]
ChemSusChem 2017, vol. 10, pp. 87–90

Enzo Alessio
Thirty Years of the Drug Candidate NAMI-A and the Myths in the Field of Ruthenium Anticancer Compounds: A Personal Perspective [Microreview]
Eur. J. Inorg. Chem. 2017, pp. 1549–1560

Marcel Garbe, Kathrin Junge, Matthias Beller
Homogeneous Catalysis by Manganese-Based Pincer Complexes [Microreview]
Eur. J. Org. Chem. 2017, pp. 4344–4362

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Magazine of Chemistry Europe (16 European Chemical Societies)published by Wiley-VCH