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ChemSusChem

Flexible TiO 2 /SiO 2 /C Film Anodes for Lithium‐Ion Batteries

Published: 21 June 2018

Author(s): Ying Jiang, Shi Chen, Daobin Mu, Zhikun Zhao, Chunli Li, Zepeng Ding, Chaoxiang Xie, Feng Wu

Abstract Flexible TiO2/SiO2/C films are prepared by using an electrospinning approach and used as self‐supporting electrodes for lithium‐ion batteries (LIBs), which exhibit excellent high‐rate capability with a capacity of 115.5 mAh g−1 at 8 A g−1 (9.8 C rate) and good storage performance. The LIBs also show high long‐term cycling stability of 700 cycles at 200 mA g−1 with a capacity of 380.1 mAh g−1 and a high capacity retention of 88.3 %. Thus, the...

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ChemMedChem

Synthesis, Biological Activity, and Mechanism of Action of 2‐Pyrazyl and Pyridylhydrazone Derivatives, New Classes of Antileishmanial Agents

Published: 21 June 2018

Author(s): Elaine S. Coimbra, Luciana M. R. Antinarelli, Mariana de A. Crispi, Thais C. M. Nogueira, Alessandra C. Pinheiro, Marcus V. N. de Souza

Abstract In this work, we report the antileishmanial activity of 23 compounds based on 2‐pyrazyl and 2‐pyridylhydrazone derivatives. The compounds were tested against the promastigotes of Leishmania amazonensis and L. braziliensis, murine macrophages, and intracellular L. amazonensis amastigotes. The most potent antileishmanial compound was selected for investigation into its mechanism of action. Among the evaluated compounds, five derivatives...

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ChemSusChem

W(OTf) 6 ‐Catalyzed Synthesis of γ‐Lactones by Ring Contraction of Macrolides or Ring Closing of Terminal Hydroxyfatty Acids in Ionic Liquid

Published: 21 June 2018

Author(s): Zhong‐Yu Xie, Jin Deng, Yao Fu

Abstract γ‐Lactones are an important class of fine chemical products and are widely used in perfumes, medicines, pesticides, dyes, and other fields. Herein, a new method for γ‐lactones preparation based on ring contraction was developed. Starting from macrolides, W(OTf)6 was used to catalyze the ring‐opening polymerization then depolymerization. The depolymerization step was not a common ring‐closing process, and the carbon number...

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European Journal of Inorganic Chemistry

Synthesis, Structure, and Water Oxidation Activity of Ruthenium(II) Complexes: Influence of Intramolecular Redox Process on O 2 Evolution

Published: 21 June 2018

Author(s): Rekha Dhiman, C. M. Nagaraja

The synthesis and characterization of two new RuII complexes, a mononuclear complex [RuII(MeMPTP)(bpp)Cl]PF6 (1) and a dinuclear complex [RuII(MeMPTP)(bpp)RuII(bpy)2Cl](PF6)3 (2), [where MeMPTP = 4′‐(4‐methylmercaptophenyl)‐2,2′:6′2′′‐terpyridine, bpp = 2,3‐bis(2‐pyridyl)pyrazine, bpy = 2,2′‐bipyridine] is reported. Single‐crystal X‐ray structural determination of the compounds unambiguously confirms the formation of the complexes 1 and 2. Catalytic...

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European Journal of Inorganic Chemistry

KineticMechanistic and SolidState Study of the Oxidative Addition and Migratory Insertion of Iodomethane to Rhodium S O BdiPT or N Oox COPR 1 R 2 R 3 Complexes

Published: 21 June 2018

Author(s): Stefan Warsink, P. D. Riekert Kotze, J. M. (Inus) Janse van Rensburg, Johan A. Venter, Stefanus Otto, Ebrahiem Botha, Andreas Roodt

Rhodium(I) carbonyl complexes containing bidentate X,O‐Bid [S,O‐BdiPT or N,O‐ox; S,O‐BdiPTH = N‐benzoyl‐N′,N′‐(diphenyl)thiourea; N,O‐oxH = 8‐hydroxyquinoline] ligands of the form [Rh(X,O‐Bid)(CO)(PR1R2R3)] (R1, R2, R3 = Ph or Cy) bearing different phosphine ligands, were investigated, the structural characterization of four example complexes is described and an extensive spectroscopic kinetic‐mechanistic study of the oxidative addition of iodomethane thereto...

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European Journal of Organic Chemistry

Diels–Alder Reaction in the Synthesis of Fluorinated (Hetero)Aromatic Compounds

Published: 21 June 2018

Author(s): Ivan S. Kondratov, Nataliya A. Tolmachova, Günter Haufe

Numerous fluorinated (hetero)aromatic compounds have been synthesized by using the Diels–Alder reaction of fluorinated dienes/dienophiles with subsequent aromatization of the initially formed [4+2]‐cycloaddition products by various methods. This microreview presents diverse applications of the approach starting from the first examples in the 1960s up to recent advanced applications to illustrate the high potential of the method for the...

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European Journal of Inorganic Chemistry

Production of Cycloalkanes in Hydrodeoxygenation of Isoeugenol Over Pt‐ and Ir‐Modified Bifunctional Catalysts

Published: 21 June 2018

Author(s): Louis Bomont, Moldir Alda‐Onggar, Vyacheslav Fedorov, Atte Aho, Janne Peltonen, Kari Eränen, Markus Peurla, Narendra Kumar, Johan Wärnå, Vincenzo Russo, Päivi Mäki‐Arvela, Henrik Grénman, Marina Lindblad, Dmitry Yu. Murzin

Hydrodeoxygenation of isoeugenol was investigated at 200 °C under 3 MPa total pressure in dodecane as a solvent, in hydrogen, over bifunctional Pt‐ and Ir‐modified Beta zeolites and mesoporous materials. As a comparison, Pt and Ir supported on Al2O3, SiO2 and mesoporous MCM‐41 were also tested. The catalysts were characterized by XRD, CO pulse chemisorption, transmission electron microscopy, scanning electron microscopy, nitrogen adsorption and FTIR...

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European Journal of Inorganic Chemistry

Next Generation of Guanidine Quinoline Copper Complexes for Highly Controlled ATRP: Influence of Backbone Substitution on Redox Chemistry and Solubility

Published: 21 June 2018

Author(s): Thomas Rösener, Alexander Hoffmann, Sonja Herres‐Pawlis

Ligands DMEG6etqu, TMG6etqu, DMEG6buqu, and TMG6buqu were developed on the basis of guanidine quinoline (GUAqu) ligands 1,3‐dimethyl‐N‐(quinolin‐8‐yl)imidazolidin‐2‐imine (DMEGqu) and 1,1,3,3‐tetramethyl‐2‐(quinolin‐8‐yl)guanidine (TMGqu). These ligands feature an alkyl substituent at the C6 of the quinoline backbone. The synthetic strategy developed here enables inexpensive syntheses of any kind of C6‐substituted GUAqu ligands. On one hand, the...

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European Journal of Organic Chemistry

Employing Small Polyfunctionalized Molecules for a Diastereoselective Synthesis of Highly Substituted Indolines

Published: 21 June 2018

Author(s): Fábio de Souza Fernandes, Rodrigo A. Cormanich, Lucas A. Zeoly, André Luiz B. Formiga, Fernando Coelho

An efficient approach has been developed for the diastereoselective synthesis of 1,2,3‐trisubstituted indolines. The reaction sequence includes the highly diastereoselective reductive amination of 2‐oxo‐1,3‐propanediols, which are prepared by postfunctionalization of Morita–Baylis–Hillman (MBH) adducts, to give substituted 2‐amino‐1,3‐propanediols with an anti relative configuration. A subsequent intramolecular palladium‐catalyzed Buchwald coupling...

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European Journal of Organic Chemistry

Hydroboration, Cyanosilylation, and Sequential Cyanosilylation and Hydroboration of Carbonyl Compounds in the Presence of a Ti IV Amido Complex as an Efficient Catalyst

Published: 21 June 2018

Author(s): Adimulam Harinath, Jayeeta Bhattcharjee, Koteswar Rao Gorantla, Bhabani S. Mallik, Tarun K. Panda

Catalytic hydroboration and cyanosilylation of a wide range of aldehydes and ketones, with pinacolborane (4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane) and trimethylsilyl cyanide, respectively, in the presence of titanium(IV) complexes [κ2‐{(C5H4N)CH2N‐P(=Se)Ph2}Ti(NMe2)3] (1) and [{κ2‐(C6H4F)NP(=Se)Ph2}Ti(NMe2)3] (2) are reported. The catalytic hydroboration and cyanosilylation processes are high‐yielding and general, and result in efficient conversion...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

March 2018

 


Zhang Luo, Bing Liu
Shape-Tunable Colloids from Structured Liquid Droplet Templates [Cover Picture]
Angew. Chem. Int. Ed. 10.1002/anie.201802726

Coline Jumeaux, Olov Wahlsten, Stephan Block, Eunjung Kim, Rona Chandrawati, Philip D. Howes, Fredrik Höök, Molly M. Stevens
MicroRNA Detection by DNA-Mediated Liposome Fusion [Communication]
ChemBioChem 2018, vol. 19, p. 434

Isabela C. Man, Hai-Yan Su, Federico Calle-Vallejo, Heine A. Hansen, José I. Martínez, Nilay G. Inoglu, John Kitchin, Thomas F. Jaramillo, Jens K. Nørskov, Jan Rossmeisl
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces [Full Paper]
ChemCatChem 2011, vol. 3, p. 1159

Matthias Schäfer, Bernhard Hauck, Jochen Kuhn, Roland Ulber
Analytik mit Licht - Das Smartphone-Photometer [Artikel]
Chem. Unserer Zeit 2018, vol. 52, p. 52

Balaram Mukhopadhyay, Rituparna Das
Chemical O-Glycosylations: An Overview [Review]
ChemistryOpen 2016, vol. 5, p. 401

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, p. 6055

Hubert Rauscher, Kirsten Rasmussen, Birgit Sokull-Klüttgen
Regulatory Aspects of Nanomaterials in the EU [Research Article]
Chem. Ing. Tech. 2017, vol. 89, p. 224

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, p. 75

Robert A. W. Dryfe, Briony Setterfield-Price, Joanne Tory, František Hartl
[M(CO)4(2,2'-bipyridine)] (M=Cr, Mo, W) Complexes as Efficient Catalysts for Electrochemical Reduction of CO2 at a Gold Electrode [Communication]
ChemElectroChem 2015, vol. 2, p. 213

Yinghui Xue, Qin Zhang, Tao Zhang, Lei Fu
Black Phosphorus: Properties, Synthesis, and Applications in Energy Conversion and Storage [Focus Review]
ChemNanoMat 2017, vol. 3, p. 352

Maximilian Koy, Frederik Sandfort, Adrian Tlahuext-Aca, Linda Quach, Constantin G. Daniliuc, Frank Glorius
Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light [Communication]
Chem. Eur. J. 2018, vol. 24, p. 4552

Jian Lv, Qi Zhang, Mao Cai, Yanfang Han, Sanzhong Luo
Aromatic Aminocatalysis [Focus Review]
Chem. Asian J. 2018, vol. 13, p. 740

Hidetoshi Noda, Naoya Kumagai, Masakatsu Shibasaki
Abstract [Focus Review]
Asian J. Org. Chem. 10.1002/ajoc.201800013

Albert J. Kooistra, Márton Vass, Ross McGuire, Rob Leurs, Iwan J. P. de Esch, Gert Vriend, Stefan Verhoeven, Chris de Graaf
3D-e-Chem: Structural Cheminformatics Workflows for Computer-Aided Drug Discovery [Full Paper]
ChemMedChem 2018, vol. 13, p. 614

Zhoufeng Bian, Sonali Das, Ming Hui Wai, Plaifa Hongmanorom, Sibudjing Kawi
A Review on Bimetallic Nickel-Based Catalysts for CO2 Reforming of Methane [Review]
ChemPhysChem 2017, vol. 18, p. 3117

Turkan Gamze Ulusoy Ghobadi, Amir Ghobadi, Ekmel Ozbay, Ferdi Karadas
Strategies for Plasmonic Hot-Electron-Driven Photoelectrochemical Water Splitting [Review]
ChemPhotoChem 2018, vol. 2, p. 161

An-Na Cho, Nam-Gyu Park
Impact of Interfacial Layers in Perovskite Solar Cells [Review]
ChemSusChem 2017, vol. 10, p. 3687

Jeffrey A. Rood, Sondra E. Hinman, Bruce C. Noll, Kenneth W. Henderson
The Use of Halide-Substituted Anilines for the Formation of Magnesium Imides [Full Paper]
Eur. J. Inorg. Chem. 2008, p. 3935

D. B. Ramachary [Author Profile]
Eur. J. Org. Chem. 10.1002/ejoc.201800182

46. Deutscher Lebensmittelchemikertag 2017 in Würzburg [Tagung]
Lebensmittelchemie 2018, vol. 72, p. 1

Peter Chen
Chemistry 4.0 [Leitartikel]
Nachr. Chem. 2018, vol. 66, p. 203

Ira Caspari, Gisela Weber-Peukert, Nicole Graulich
Der Einsatz von Modellen zum Erkenntnisgewinn / Eine Unterrichtseinheit zur Förderung der Modellkompetenz im Kontext „Batterie“ unter explizitem Einbezug von Schülervorstellungen [Aus der Schule]
CHEMKON 2018, vol. 25, p. 23

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal


2016

 


Shoujun Zhu, Qingnan Meng, Lei Wang, Junhu Zhang, Yubin Song, Han Jin, Kai Zhang, Hongchen Sun, Haiyu Wang, Bai Yang
Highly Photoluminescent Carbon Dots for Multicolor Patterning, Sensors, and Bioimaging
Angew. Chem. Int. Ed. 2013, vol. 52, pp. 3953–3957

Balayeshwanth R. Vummidi, Jawad Alzeer, Nathan W. Luedtke
Fluorescent Probes for G-Quadruplex Structures [Review]
ChemBioChem 2013, vol. 14, pp. 540–558

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Marc Steinmetz, Stefan Grimme
Benchmark Study of the Performance of Density Functional Theory for Bond Activations with (Ni,Pd)-Based Transition-Metal Catalysts [Full Paper]
ChemistryOpen 2013, vol. 2, pp. 115–124

Philipp Scharf, Jens Müller
Nucleic Acids With Metal-Mediated Base Pairs and Their Applications [Review]
ChemPlusChem 2013, vol. 78, pp. 20–34

Philipp Kaiser, Rajabhau?Bajirao Unde, Christoph Kern, Andreas Jess
Production of Liquid Hydrocarbons with CO2 as Carbon Source based on Reverse Water-Gas Shift and Fischer-Tropsch Synthesis [Research Article]
Chem. Ing. Tech. 2013, vol. 85, pp. 489–499

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Konggang Qu, Jiasi Wang, Jinsong Ren, Xiaogang Qu
Carbon Dots Prepared by Hydrothermal Treatment of Dopamine as an Effective Fluorescent Sensing Platform for the Label-Free Detection of Iron(III) Ions and Dopamine [Full Paper]
Chem. Eur. J. 2013, vol. 19, pp. 7243–7249

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chem. Asian J. 2014, vol. 9, pp. 26–47

Naohiko Yoshikai, Ye Wei
Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed C–H Functionalization [Review]
Asian J. Org. Chem. 2013, vol. 2, pp. 466–478

Lluís Ballell, Robert H. Bates, Rob J. Young, Daniel Alvarez-Gomez, Emilio Alvarez-Ruiz, Vanessa Barroso, Delia Blanco, Benigno Crespo, Jaime Escribano, Rubén González, Sonia Lozano, Sophie Huss, Angel Santos-Villarejo, José Julio Martín-Plaza, Alfonso Mendoza, María José Rebollo-Lopez, Modesto Remuiñan-Blanco, José Luis Lavandera, Esther Pérez-Herran, Francisco Javier Gamo-Benito, José Francisco García-Bustos, David Barros, Julia P. Castro, Nicholas Cammack
Fueling Open-Source Drug Discovery: 177 Small-Molecule Leads against Tuberculosis [Full Paper]
ChemMedChem 2013, vol. 8, pp. 313–321

Peter Politzer, Jane S. Murray
Halogen Bonding: An Interim Discussion [Review]
ChemPhysChem 2013, vol. 14, pp. 278–294

Volker Hessel, Dana Kralisch, Norbert Kockmann, Timothy Noël, Qi Wang
Novel Process Windows for Enabling, Accelerating, and Uplifting Flow Chemistry [Review]
ChemSusChem 2013, vol. 6, pp. 746–789

Helena J. Shepherd, Gábor Molnár, William Nicolazzi, Lionel Salmon, Azzedine Bousseksou
Spin Crossover at the Nanometre Scale [Microreview]
Eur. J. Inorg. Chem. 2013, pp. 653–661

Junichiro Yamaguchi, Kei Muto, Kenichiro Itami
Recent Progress in Nickel-Catalyzed Biaryl Coupling [Microreview]
Eur. J. Org. Chem. 2013, pp. 19–30

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941
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