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European Journal of Organic Chemistry

On the Shape and Synthesis of Extended Fluorenones: Recent Advances and Upcoming Challenges

Published: 26 November 2021

Author(s): Benjamin Large, Damien Prim

Abstract Extended fluorenones represent a particular class of polycyclic compounds. The extension of the aromatic system through the fusion of additional benzene rings onto the central tricyclic fluorenone gives rise to an impressive topological diversity and allows to modulate the properties of the original molecule. The multiple ways this aromatic extension can be joined onto the tricyclic core generates multiple spatial arrangements from linear, angular, mixed linear‐angular, to helical....

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The Reaction of o‐Benzyne with Vinylacetylene: An Unexplored Way to Produce Naphthalene

Published: 26 November 2021

Author(s): Lisa Monluc, Anatoliy A. Nikolayev, Iakov A. Medvedkov, Valeriy N. Azyazov, Alexander N. Morozov, Alexander M. Mebel

Abstract The mechanism and kinetics of the reaction of ortho‐benzyne with vinylacetylene have been studied by ab initio and density functional CCSD(T)‐F12/cc‐pVTZ‐f12//B3LYP/6‐311G(d,p) calculations of the pertinent potential energy surface combined with Rice‐Ramsperger‐Kassel‐Marcus ‐ Master Equation calculations of reaction rate constants at various temperatures and pressures. Under prevailing combustion conditions, the reaction has been shown to predominantly proceed by the biradical...

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European Journal of Inorganic Chemistry

Stereoisomerism in Tetrametallic Propeller‐Like Complexes: A Solid‐State and Solution NMR Study on a Tetragallium(III) Derivative

Published: 26 November 2021

Author(s): Andrea Cornia, Adele Mucci, Matteo Briganti, Nathalie Bridonneau, Andrea Nava, Alessio Nicolini

Abstract Tetragallium(III) complex in [Ga4(L4‐Py)2(dpm)6] ⋅ EtOH, with H3L4‐Py=2‐(hydroxymethyl)‐2‐(pyridin‐4‐yl)propane‐1,3‐diol and Hdpm=dipivaloylmethane, was investigated as a diamagnetic analogue of tetrametallic, propeller‐like single‐molecule magnets (SMMs). The chiral molecular structure partitions the six CH2 protons of each tripodal (L4‐Py)3− ligand into two diastereotopic sets. The two signals were clearly detected by 1H NMR spectroscopy in C6D6, proving that Λ and Δ enantiomers...

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European Journal of Organic Chemistry

Azido Functionalized Nucleosides Linked to Controlled Pore Glass as Suitable Starting Materials for Oligonucleotide Synthesis by the Phosphoramidite Approach

Published: 26 November 2021

Author(s): Frederik Müggenburg, Alexander Biallas, Mégane Debiais, Michael Smietana, Sabine Müller

Abstract It has long been debated whether easily reducible azide groups can withstand the conditions of oligonucleotide synthesis by phosphoramidite chemistry. We have synthesized various 2′‐ and 3′‐azido modified nucleosides and immobilized them on controlled pore glass (CPG) to be used as starting material for the synthesis of oligonucleotides (ONs) with 3′‐terminal azide (attached to C2′ or C3′). In a model study, immobilized 3′‐azidoadenosine was used as a starting block for the synthesis...

thumbnail image: European Journal of Organic Chemistry


Nickel(II)‐Catalyzed Selective (E)‐Olefination of Methyl Heteroarenes Using Benzyl Alcohols via Acceptorless Dehydrogenative Coupling Reaction

Published: 26 November 2021

Author(s): Gunasekaran Balamurugan, Rengan Ramesh

Abstract An efficient catalytic protocol for the synthesis of selective (E)‐olefins by the newly synthesized nickel complexes via greener acceptorless dehydrogenative coupling methodology is presented. Two nickel(II) N, S chelating complexes were structurally characterized with the aid of spectral and single crystal X‐ray diffraction methods. Olefination of 2‐methylheteroarenes with benzyl alcohols via acceptorless dehydrogenative coupling is achieved by inexpensive nickel(II) catalysts. The...

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Reductive Amination, Hydrogenation and Hydrodeoxygenation of 5‐Hydroxymethylfurfural using Silica‐supported Cobalt‐ Nanoparticles

Published: 26 November 2021

Author(s): Vishwas G. Chandrashekhar, Kishore Natte, Asma M. Alenad, Ahmad S. Alshammari, Carsten Kreyenschulte, Rajenahally V. Jagadeesh

Abstract Efficient and selective conversion of renewable feedstocks to essential chemicals and fuels applying green and sustainable catalytic processes is of central importance and attracts scientific interest. Among different biomass‐based feedstocks, 5‐hydroxymethylfurfural (HMF) represents valuable platform compound widely used for the synthesis of valuable chemicals, fuels, and polymers. Here we report cobalt nanoparticles catalyzed reductive amination, hydrogenation and hydrodeoxygenation...

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Insulating Polymers as Additives to Bulk‐Heterojunction Organic Solar Cells: The Effect of Miscibility

Published: 26 November 2021

Author(s): Chunhui Liu, Chengyi Xiao, Chengcheng Xie, Qinglian Zhu, Qiaomei Chen, Wei Ma, Weiwei Li

Abstract Adding insulating polymers to conjugated polymers is an efficient strategy to tailor their mechanical properties for flexible organic electronics. In this work, we selected two insulating polymers as additives for high‐performance photoactive layers and investigated the mechanical and photovoltaic properties in organic solar cells (OSCs). The insulating polymers were found to reduce the electron mobilities in the photoactive layers, and hence the power conversion efficiencies were...

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Effect of SiO2 on the CO Selective Methanation over SiO2/Ni‐ZrO2 Catalysts

Published: 26 November 2021

Author(s): Qing Guo, Shaozhong Li, Jin Li, Yongke Hu, Yanxing Li

Abstract CO selective methanation is a reliable and efficient method for deep CO removal from H2‐rich reformate gases in proton exchange membrane fuel cell (PEMFC). In this study, a series of SiO2/Ni‐ZrO2 catalysts with different mass fractions of SiO2 was prepared for CO selective methanation, and the structures and surface chemical properties of Ni‐ZrO2 could be controlled by SiO2. It was found that SiO2 greatly increased the specific surface areas of the catalyst and the dispersion of...

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European Journal of Inorganic Chemistry

Interconversion of tetrahedral [(M)4∩{Mg4(L1)6}]/[In4(L2)4] and cyclic [In6Cl6(L3)6]. Enantiotopization of diastereotopic protons monitored by means of VT 1H NMR spectroscopy

Published: 26 November 2021

Author(s): Walter Bauer, Harald Maid, Rolf W. Saalfrank

Abstract In this review we report on the enantiomerization of tetrahedral racemic‐[(NH4)4∩{Mg4(L1)6}] monitored by means of variable temperature (VT) 1H NMR spectroscopy. The enantiotopization of the diastereotopic protons is due to simultaneous Bailar twists at the four octahedrally coordinated magnesium centres, synchronized with atropisomerization of the six edge‐bridging ligands (L1)2‐.The VT 1H NMR spectrum of tetrahedral meso‐[In4(L2)4] is coined through the helicity of the four...

thumbnail image: European Journal of Inorganic Chemistry


Elucidating the Role of Rh/C on the Pathways and Kinetics of Ketone‐to‐Secondary Amines Reaction

Published: 25 November 2021

Author(s): Luis E. Arteaga‐Pérez, Raydel Manrique, Maray Ortega, Francisca Castillo‐Puchi, Juan E. Fraile, Romel Jiménez

Abstract Biomass‐based amines have received a lot of attention due to their sustainability and carbon economy. Herein, the roles of the metal sites (Rh0 or Pd0) and operating conditions on the kinetics and reaction pathways of the heterogeneous catalytic amination of cyclohexanone with aniline have been discussed. Rh/C provides secondary amines with remarkable selectivity toward the hydrogenation product (ΣSi=72 %). The hydrogenation rate over Rh0 is 1.5‐fold higher than that observed over...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

October 2021


Fang Zhang, Juewen Liu
Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review]
Anal. Sens. 2021, vol. 1, no. 1, p. 30

Rola Houhou, Thomas Bocklitz
Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review]
Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128

Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster
High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article]
Batteries Supercaps 2021, vol. 4, no. 6, p. 934

Hemanth Maddali, Catherine E. Miles, Joachim Kohn, Deirdre M. O'Carroll
Optical Biosensors for Virus Detection: Prospects for SARS-CoV-2/COVID-19 [Minireview]
ChemBioChem 2021, vol. 22, no. 7, p. 1176

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Keita Sakamoto, Akihiro Hakamata, Arihiro Iwasaki, Kiyotake Suenaga, Masashi Tsuda, Haruhiko Fuwa
Cover Feature: Total Synthesis, Stereochemical Revision, and Biological Assessment of Iriomoteolide-2a (Chem. Eur. J. 36/2019) [Cover Picture]
Chem. Eur. J. 2019, vol. 25, no. 36, p. 8429

Guilherme L. Tripodi, Max T. G. M. Derks, Floris P. J. T. Rutjes, Jana Roithová
Tracking Reaction Pathways by a Modular Flow Reactor Coupled to Electrospray Ionization Mass Spectrometry [Cover Profile]
Chemistry–Methods 2021, vol. 1, no. 10, p. 428

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors [Communication]
ChemPhotoChem 2021, vol. 5, no. 9, p. 808

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Francesco Bisconti, Antonella Giuri, Gianluigi Marra, Alberto Savoini, Paolo Fumo, Rosamaria Marrazzo, Stefano Zanardi, Gianni Corso, Riccardo Po, Paolo Biagini, Eleonora Quadrivi, Riikka Suhonen, Thomas M. Kraft, Mari Ylikunnari, Andrea Listorti, Carola Esposito Corcione, Silvia Colella, Aurora Rizzo
Polymer-Assisted Single-Step Slot-Die Coating of Flexible Perovskite Solar Cells at Mild Temperature from Dimethyl Sulfoxide [Full Paper]
ChemPlusChem 2021, vol. 86, no. 10, p. 1442

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Anton I. Hanopolskyi, Viktoryia A. Smaliak, Alexander I. Novichkov, Sergey N. Semenov
Autocatalysis: Kinetics, Mechanisms and Design [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2000026

Saheed E. Elugoke, Abolanle S. Adekunle, Omolola E. Fayemi, Ekemini D. Akpan, Bhekie B. Mamba, El-Sayed M. Sherif, Eno E. Ebenso
Molecularly imprinted polymers (MIPs) based electrochemical sensors for the determination of catecholamine neurotransmitters - Review [REVIEW]
Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2000026

Mauricio Cattaneo, Giovanny A. Parada, Adam L. Tenderholt, Werner Kaminsky, James M. Mayer
Structural, Electronic, and Thermochemical Preference for Multi-PCET Reactivity of Ruthenium(II)-Amine and Ruthenium(IV)-Amido Complexes [Full Paper]
Eur. J. Inorg. Chem. 2021, p. 4066

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Michael C. Willis, Edward J. Emmett
The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry [Focus Review]
Asian J. Org. Chem. 2015, vol. 4, no. 7, p. 602

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

B. Lilli Neumeier, Mikhail Khorenko, Frauke Alves, Oliver Goldmann, Joanna Napp, Ute Schepers, Holger M. Reichardt, Claus Feldmann
Fluorescent Inorganic-Organic Hybrid Nanoparticles [Focus Review]
ChemNanoMat 2019, vol. 5, no. 1, p. 24

Xiaoye Yu, Constantin G. Daniliuc, Fatmah Ali Alasmary, Armido Studer
Direct Access to α-Aminosilanes Enabled by Visible-Light-Mediated Multicomponent Radical Cross-Coupling [Research Article]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 43, p. 23335

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Manami Ishida, Dieter Weiß
Blausäure im Haushalt [Magazin]
Chem. Unserer Zeit 2021, vol. 55, no. 5, p. 359

Digitalisierung nach der Pandemie [Editorial]
CHEMKON 2021, vol. 28, no. 6, p. 234

Cover Picture Lebensmittelchemie 5/2021 [Cover Picture]
Lebensmittelchemie 2021, vol. 75, no. 5

Sonja Herres-Pawlis, Johannes Liermann
Den Datenschatz endlich heben [Leitartikel]
Nachr. Chem. 2021, vol. 69, no. 10, p. 3

Most cited articles from Chemistry Europe, ACES, and GDCh journals

Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH