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Materials and Corrosion

The crevice corrosion behavior of N80 carbon steel in acidic NaCl solution: The effect of O2

Published: 20 October 2021

Author(s): Yizhou Li, Jie Mu, Zhongyu Cui, Xin Wang

Abstract The effect of O2 on crevice corrosion of N80 carbon steel in acidic NaCl solution is investigated. Crevice corrosion of N80 carbon steel could be initiated with or without O2 in acidic NaCl solution. A deep corrosion groove could be formed near the crevice mouth after crevice corrosion. The crevice corrosion of N80 carbon steel is ascribed to the increased pH inside the crevice in acidic NaCl solution. The presence of O2 in the solution could enhance the cathodic reaction processes...

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Small Structures

Metal−Organic Frameworks: Why Make Them Small?

Published: 20 October 2021

Author(s): Jiemin Wang, Inhar Imaz, Daniel Maspoch

Recent studies have demonstrated that metal−organic frameworks (MOFs) can be miniaturized down to the submicroscale and even nanoscale to create small MOFs. Herein, the basic concepts and recent progresses concerning the core question of “MOFs, why make them small?” are briefly introduced from three perspectives: those of size, shape, and processability. Small sizes endow MOFs with large outer surface area/volume ratios, leading to important differences in their characteristics (e.g., outer...

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Advanced Materials

Interface‐Mediated Twinning‐Induced Plasticity in a Fine Hexagonal Microstructure Generated by Additive Manufacturing

Published: 20 October 2021

Author(s): Pere Barriobero‐Vila, Juan Manuel Vallejos, Joachim Gussone, Jan Haubrich, Klemens Kelm, Andreas Stark, Norbert Schell, Guillermo Requena

Abstract The grain size is a determinant microstructural feature to enable the activation of deformation twinning in hexagonal close‐packed (hcp) metals. Although deformation twinning is one of the most effective mechanisms for improving the strength–ductility trade‐off of structural alloys, its activation is reduced with decreasing grain size. This work reports the discovery of the activation of deformation twinning in a fine‐grained hcp microstructure by introducing ductile body‐centered...

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Advanced Materials

Advancing 2D Perovskites for Efficient and Stable Solar Cells: Challenges and Opportunities

Published: 20 October 2021

Author(s): Xiaoming Zhao, Tianran Liu, Yueh‐Lin Loo

Abstract Perovskite solar cells (PSCs) have rapidly emerged as one of the hottest topics in the photovoltaics community owing to their high power‐conversion efficiencies (PCE), and the promise to be produced at low cost. Among various PSCs, typical 3D perovskite‐based solar cells deliver high PCE but they suffer from severe instability, which restricts their practical applications. In contrast to 3D perovskites, 2D perovskites that incorporate larger, less volatile, and generally more...

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Asia-Pacific Journal of Chemical Engineering

Computational fluid dynamics simulation of multi‐phase flow characteristics in an industrial‐scale randomly packed tower

Published: 20 October 2021

Author(s): Hongbo Tan, Na Wen, Zhi Ding

Abstract A three‐dimensional (3‐D) two‐phase Eulerian–Eulerian‐based computational fluid dynamics (CFD) simulation method coupled with a porous media model was developed in this study to simulate the air–water two‐phase flow in an industrial‐scale randomly packed air cooling tower (RPACT). The authors discussed the effects of gas kinetic energy factor, liquid load, packing materials, and packed bed height on the hydrodynamic performances of the gas–liquid counter‐current flow in the proposed...

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Advanced Materials

Slip‐Stacked J‐Aggregate Materials for Organic Solar Cells and Photodetectors

Published: 20 October 2021

Author(s): Jin Hong Kim, Tim Schembri, David Bialas, Matthias Stolte, Frank Würthner

Abstract Dye–dye interactions affect the optical and electronic properties in organic semiconductor films of light harvesting and detecting optoelectronic applications. This review elaborates how to tailor these properties of organic semiconductors for organic solar cells (OSCs) and organic photodiodes (OPDs). While these devices rely on similar materials, the demands for their optical properties are rather different, the former requiring a broad absorption spectrum spanning from the UV over...

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Nano Select

Recent advances in Ni‐Fe (Oxy)hydroxide electrocatalysts for the oxygen evolution reaction in alkaline electrolyte targeting industrial applications

Published: 20 October 2021

Author(s): Zheyin Yu, Ying Bai, George Tsekouras, Zhenxiang Cheng

Abstract Due to its high gravimetric energy density, abundance, wide applicability, and potential to be a zero‐carbon emission energy carrier, hydrogen is considered to be highly important for future sustainability. Currently, 96% of hydrogen is produced from fossil fuels, with relatively low purity and high associated CO2 emissions. Only 4% of hydrogen is produced by water electrolysis with high purity mainly due to the inefficiency of oxygen evolution reaction (OER). Therefore developing...

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Advanced Functional Materials

Super‐Stable Mineralization of Ni2+ Ions from Wastewater using CaFe Layered Double Hydroxide

Published: 20 October 2021

Author(s): Haoyuan Chi, Jikang Wang, Huijuan Wang, Shaoquan Li, Mufei Yang, Sha Bai, Changjuan Li, Xiaoliang Sun, Yufei Zhao, Yu‐Fei Song

Abstract The dealing/recycling of Ni‐containing wastewater pollution has aroused great attention both from environmental science and resource utilization perspectives. Herein, a classic CaFe‐layered double hydroxide (CaFe‐LDH) stabilizer, which exhibits a super‐stable mineralization efficiency for removing Ni2+ ions with a maximum saturated removal capacity of 321 mg g−1 is prepared. This stabilizer can remove not only 10 000 mg L−1 Ni2+ ions to a few mg L−1, but also 1 mg L−1 Ni2+ ions to...

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Small Science

Chemical Vapor Deposition Mediated Phase Engineering for 2D Transition Metal Dichalcogenides: Strategies and Applications

Published: 20 October 2021

Author(s): Karla Hernandez Ruiz, Ziqian Wang, Matteo Ciprian, Meifang Zhu, Rong Tu, Lianmeng Zhang, Wei Luo, Yuchi Fan, Wan Jiang

2D transition metal dichalcogenides (TMDs) are characterized by the presence of multiple crystal structures or phases, even at the ultrathin limit. Controlling phase transformations, namely, phase engineering, of 2D TMDs is crucial for realizing high‐performance 2D devices by combining phases with distinct physical and chemical properties. As a powerful approach for large‐scale production of high‐quality 2D TMDs, chemical vapor deposition (CVD) offers unique advantages in phase engineering due...

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Advanced Materials

Nanotechnology Enables Novel Modalities for Neuromodulation

Published: 20 October 2021

Author(s): Xiao Yang, Eve McGlynn, Rupam Das, Sergiu P. Paşca, Bianxiao Cui, Hadi Heidari

Abstract Neuromodulation is of great importance both as a fundamental neuroscience research tool for analyzing and understanding the brain function, and as a therapeutic avenue for treating brain disorders. Here, an overview of conceptual and technical progress in developing neuromodulation strategies is provided, and it is suggested that recent advances in nanotechnology are enabling novel neuromodulation modalities with less invasiveness, improved biointerfaces, deeper penetration, and...

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

September 2021

 


Fang Zhang, Juewen Liu
Label-Free Colorimetric Biosensors Based on Aptamers and Gold Nanoparticles: A Critical Review [Review]
Anal. Sens. 2021, vol. 1, no. 1, p. 30

Rola Houhou, Thomas Bocklitz
Trends in artificial intelligence, machine learning, and chemometrics applied to chemical data [Review]
Anal. Sci. Adv. 2021, vol. 2, no. 3-4, p. 128

Alana Zülke, Yi Li, Peter Keil, Robert Burrell, Sacha Belaisch, Mangayarkarasi Nagarathinam, Michael P. Mercer, Harry E. Hoster
High-Energy Nickel-Cobalt-Aluminium Oxide (NCA) Cells on Idle: Anode- versus Cathode-Driven Side Reactions [Article]
Batteries Supercaps 2021, vol. 4, no. 6, p. 934

Kim Bartels, Tanya Lasitza-Male, Hagen Hofmann, Christian Löw
Single-Molecule FRET of Membrane Transport Proteins [Minireview]
ChemBioChem 2021, vol. 22, no. 17, p. 2657

Christian M. Heckmann, Francesca Paradisi
Looking Back: A Short History of the Discovery of Enzymes and How They Became Powerful Chemical Tools [Review]
ChemCatChem 2020, vol. 12, no. 24, p. 6082

Pooja Vadhva, Ji Hu, Michael J. Johnson, Richard Stocker, Michele Braglia, Dan J. L. Brett, Alexander J. E. Rettie
Electrochemical Impedance Spectroscopy for All-Solid-State Batteries: Theory, Methods and Future Outlook [Review]
ChemElectroChem 2021, vol. 8, no. 11, p. 1930

Michał Rams, Aleksej Jochim, Michael Böhme, Thomas Lohmiller, Magdalena Ceglarska, Marek M. Rams, Alexander Schnegg, Winfried Plass, Christian Näther
Single-Chain Magnet Based on Cobalt(II) Thiocyanate as XXZ Spin Chain [Full Paper]
Chem. Eur. J. 2020, vol. 26, no. 13, p. 2837

Trishna Rajbongshi, Kashyap Kumar Sarmah, Ramesh Ganduri, Suryanarayan Cherukuvada, Mihails Arhangelskis, Ranjit Thakuria
Cover Feature: Mechanosynthesis of Eutectics of Anti-Inflammatory Drug Ethenzamide - A Comparison with Analogous Cocrystals (Chemistry - Methods 9/2021) [Cover Picture]
Chem. Methods 2021, vol. 1, no. 9, p. 398

Zheng-Wang Qu, Hui Zhu, Sergey A. Katsyuba, Vera L. Mamedova, Vakhid A. Mamedov, Stefan Grimme
Acid-Catalyzed Rearrangements of 3-Aryloxirane-2-Carboxamides: Novel DFT Mechanistic Insights [Communication]
ChemistryOpen 2020, vol. 9, no. 7, p. 743

Jelena Đorović Jovanović, Marko Antonijević, Ali A. El-Emam, Zoran Marković
Comparative MD Study of Inhibitory Activity of Opaganib and Adamantane-Isothiourea Derivatives toward COVID-19 Main Protease Mpro [Full Paper]
ChemistrySelect 2021, vol. 6, no. 33, p. 8603

Antoine Daina, Vincent Zoete
A BOILED‐Egg To Predict Gastrointestinal Absorption and Brain Penetration of Small Molecules [Communication]
ChemMedChem 2016, vol. 11, no. 11, p. 1117

Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors [Communication]
ChemPhotoChem 2021, vol. 5, no. 9, p. 808

Thomas G. Mayerhöfer, Susanne Pahlow, Jürgen Popp
The Bouguer-Beer-Lambert Law: Shining Light on the Obscure [Review]
ChemPhysChem 2020, vol. 21, no. 18, p. 2029

Giuseppe Zuccarello, Imma Escofet, Ulysse Caniparoli, Antonio M. Echavarren
New-Generation Ligand Design for the Gold-Catalyzed Asymmetric Activation of Alkynes [Minireview]
ChemPlusChem 2021, vol. 86, no. 9, p. 1283

Layla Filiciotto, Gadi Rothenberg
Biodegradable Plastics: Standards, Policies, and Impacts [Review]
ChemSusChem 2021, vol. 14, no. 1, p. 56

Marleen H. M. E. Stevendaal, Jan C. M. Hest, Alexander F. Mason
Functional Interactions Between Bottom-Up Synthetic Cells and Living Matter for Biomedical Applications [Review]
ChemSystemsChem 2021, vol. 3, eLoc. e2100009

Wolfgang Jud, C. Oliver Kappe, David Cantillo
One-pot multistep electrochemical strategy for the modular synthesis of epoxides, glycols, and aldehydes from alkenes [Full article]
Electrochem. Sci. Adv. 2021, vol. 1, eLoc. e2100002

Silène Engbers, Evgeniya A. Trifonova, Kristopher M. Hess, Folkert Vries, Johannes E. M. N. Klein
Synthesis of a Sterically Encumbered Pincer Au(III)−OH Complex [Communication]
Eur. J. Inorg. Chem. 2021, p. 3561

Luca Capaldo, Davide Ravelli
Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview]
Eur. J. Org. Chem. 2017, p. 2056

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemistryViews 2016

Shoji Kobayashi, Keisuke Shibukawa, Yuta Miyaguchi, Araki Masuyama
Grignard Reactions in Cyclopentyl Methyl Ether [Full Paper]
Asian J. Org. Chem. 2016, vol. 5, no. 5, p. 636

Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore
Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review]
Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

B. Lilli Neumeier, Mikhail Khorenko, Frauke Alves, Oliver Goldmann, Joanna Napp, Ute Schepers, Holger M. Reichardt, Claus Feldmann
Fluorescent Inorganic-Organic Hybrid Nanoparticles [Focus Review]
ChemNanoMat 2019, vol. 5, no. 1, p. 24

Xinlan A. F. Cook, Loïc R. E. Pantaine, David C. Blakemore, Ian B. Moses, Neal W. Sach, Andre Shavnya, Michael C. Willis
Base-Activated Latent Heteroaromatic Sulfinates as Nucleophilic Coupling Partners in Palladium-Catalyzed Cross-Coupling Reactions [Research Article]
Angew. Chem. Int. Ed. 2021, vol. 60, no. 41, p. 22461

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Özge Çepelioğullar Mutlu, Thomas Zeng
Challenges and Opportunities of Modeling Biomass Gasification in Aspen Plus: A  Review [Review]
Chem. Eng. Technol. 2020, vol. 43, no. 9, p. 1674

Nuria Sánchez-Bastardo, Robert Schlögl, Holger Ruland
Methane Pyrolysis for CO2-Free H2 Production: A Green Process to Overcome Renewable Energies Unsteadiness [Review]
Chem. Ing. Tech. 2020, vol. 92, no. 10, p. 1596

Martin Witt, Christopher Heuer, Lina Miethke, John-Alexander Preuß, Johanna Sophie Rehfeld, Torsten Schüling, Cornelia Blume, Stefanie Thoms, Frank Stahl
Nachweismethoden von SARS-CoV-2 [Artikel]
Chem. Unserer Zeit 2020, vol. 54, no. 6, p. 368

Digitalisierung nach der Pandemie [Editorial]
CHEMKON 2021, vol. 28, no. 6, p. 234

Jörg Häseler
Liebe Mitglieder der Lebensmittelchemischen Gesellschaft [Article]
Lebensmittelchemie 2021, vol. 75, no. S2

Denis Priester, Ingo Krossing
Elektromobilität und synthetische Kraftstoffe [Industrie + Technik]
Nachr. Chem. 2021, vol. 69, no. 9, p. 36

Most cited articles from Chemistry Europe, ACES, and GDCh journals


Articles on this list are the most frequently cited ones among those published in 2018 or 2019 according to Web of Science. They have contributed the most to the journal's impact factor in 2020.

 


Jing Pan, Xin Long Tian, Shahid Zaman, Zehua Dong, Hongfang Liu, Ho Seok Park, Bao Yu Xia
Recent Progress on Transition Metal Oxides as Bifunctional Catalysts for Lithium-Air and Zinc-Air Batteries [Minireview]
Batteries Supercaps 2019, vol. 2, pp. 336–347

Veeresh Juturu, Jin Chuan Wu
Heterologous Protein Expression in Pichia pastoris: Latest Research Progress and Applications [Review]
ChemBioChem 2018, vol. 19, pp. 7–21

Tingmin Di, Quanlong Xu, WingKei Ho, Hua Tang, Quanjun Xiang, Jiaguo Yu
Review on Metal Sulphide-based Z-scheme Photocatalysts [Review]
ChemCatChem 2019, vol. 11, pp. 1394–1411

Lantao Liu, Yanli Zhou, Shuang Liu, Maotian Xu
The Applications of Metal−Organic Frameworks in Electrochemical Sensors [Review]
ChemElectroChem 2018, vol. 5, pp. 6–19

Min Feng, Ming-Liang Tong
Single Ion Magnets from 3d to 5f: Developments and Strategies [Minireview]
Chem. Eur. J. 2018, vol. 24, pp. 7574–7594

Massimo Baroncini, Lorenzo Casimiro, Christiaan de Vet, Jessica Groppi, Serena Silvi, Alberto Credi
Making and Operating Molecular Machines: A Multidisciplinary Challenge [Minireview]
ChemistryOpen 2018, vol. 7, pp. 169–179

Patil S. Basavarajappa, Bhojya Naik H. Seethya, Nagaraju Ganganagappa, Kumaraswamy B. Eshwaraswamy, Raghava Reddy Kakarla
Enhanced Photocatalytic Activity and Biosensing of Gadolinium Substituted BiFeO3 Nanoparticles [Full Paper]
ChemistrySelect 2018, vol. 3, pp. 9025–9033

Deepti Goyal, Amandeep Kaur, Bhupesh Goyal
Benzofuran and Indole: Promising Scaffolds for Drug Development in Alzheimer's Disease [Review]
ChemMedChem 2018, vol. 13, pp. 1275–1299

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori
Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review]
ChemPhotoChem 2018, vol. 2, pp. 386–402

Weiyin Gao, Chenxin Ran, Jun Xi, Bo Jiao, Wenwen Zhang, Mincai Wu, Xun Hou, Zhaoxin Wu
High-Quality Cs2AgBiBr6 Double Perovskite Film for Lead-Free Inverted Planar Heterojunction Solar Cells with 2.2 % Efficiency [Communication]
ChemPhysChem 2018, vol. 19, pp. 1696–1700

Achini Japahuge, Tao Zeng
Theoretical Studies of Singlet Fission: Searching for Materials and Exploring Mechanisms [Review]
ChemPlusChem 2018, vol. 83, pp. 146–182

Peixun Xiong, Xinxin Zhao, Yunhua Xu
Nitrogen-Doped Carbon Nanotubes Derived from Metal-Organic Frameworks for Potassium-Ion Battery Anodes [Full Paper]
ChemSusChem 2018, vol. 11, pp. 202–208

Nadja Stucke, Benedikt M. Flöser, Thomas Weyrich, Felix Tuczek
Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments [Microreview]
Eur. J. Inorg. Chem. 2018, pp. 1337–1355

Davin Tan, Tomislav Friščić
Mechanochemistry for Organic Chemists: An Update [Microreview]
Eur. J. Org. Chem. 2018, pp. 18–33

Esther von Grotthuss, Alexandra John, Thomas Kaese, Matthias Wagner
Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis [Focus Review]
Asian J. Org. Chem. 2018, vol. 7, pp. 37–53

Min-Hua Huang, Wen-Juan Hao, Bo Jiang
Recent Advances in Radical-Enabled Bicyclization and Annulation/1,n-Bifunctionalization Reactions [Focus Review]
Chem. Asian J. 2018, vol. 13, pp. 2958–2977

Amit Kumar, Qiang Xu
Two-Dimensional Layered Materials as Catalyst Supports [Focus Review]
ChemNanoMat 2018, vol. 4, pp. 28–40

Leyre Marzo, Santosh K. Pagire, Oliver Reiser, Burkhard König
Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis? [Review]
Angew. Chem. Int. Ed. 2018, vol. 57, pp. 10034–10072

Sayantani Sikdar, Madhusree Kundu
A Review on Detection and Abatement of Heavy Metals [Review]
ChemBioEng Rev. 2018, vol. 5, pp. 18–29

Marwa Elkady, Hassan Shokry, Hesham Hamad
Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater [Research Article]
Chem. Eng. Technol. 2018, vol. 41, pp. 553–562

Jaqueline Daniel-Gromke, Nadja Rensberg, Velina Denysenko, Walter Stinner, Tina Schmalfuß, Mattes Scheftelowitz, Michael Nelles, Jan Liebetrau
Current Developments in Production and Utilization of Biogas and Biomethane in Germany [Review]
Chem. Ing. Tech. 2018, vol. 90, pp. 17–35

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH