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Process Safety Progress

A hybrid human reliability assessment technique for the maintenance operations of marine and offshore systems

Published: 05 December 2019

Author(s): Rabiul Islam, Mohan Anantharaman, Faisal Khan, Rouzbeh Abbassi, Vikram Garaniya

Abstract Regular maintenance is very important to ensure all the required types of machinery and equipment be kept 100% efficient for marine and offshore systems. Maintenance operations for marine and offshore systems are carried out by the seafarers/operators and it is they who are usually liable for any error. Previous studies have identified that about 80% of marine and offshore accidents occurred due to human error. Therefore, to address this concern human reliability assessment (HRA) is...

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Journal of the Science of Food and Agriculture

Evolution of volatile compounds in 'Cuoredolce®' and 'Rugby' mini‐ watermelons (Citrullus lanatus (Thunb.) Matsumura and Nakai) in relation to ripening at harvest

Published: 05 December 2019

Author(s): Giulia Bianchi, Lia Provenzi, Anna Rizzolo

Abstract BACKGROUND Watermelon is appreciated for its nutritional properties and for its flavor. Among the flavor‐active compounds that it contains, volatiles play a key role being responsible for aroma. Recent breeding activity has led to the release of mini‐watermelons with reduced fruit weight. This paper reports on the characterization of aroma profiles of 'Rugby' and 'Cuoredolce®' novel mini‐watermelon cultivars at the ripening stage. The main volatiles were identified and quantified...

Journal of the Science of Food and Agriculture

Long fallows allow soil regeneration in slash‐and‐burn agriculture

Published: 05 December 2019

Author(s): Mariane Gonçalves Lintemani, Arcângelo Loss, Camilo Sepulveda Mendes, Alfredo Celso Fantini

Abstract BACKGROUND Slash‐and‐burn is a typical soil management system in tropical regions, in which the use of fire and the fallow time are key factors for controlling the dynamics of the physical and chemical attributes of the soil. The present study evaluated the ability of the fallow period to regenerate the soil, making it similar to the soil of a mature native forest, and compared it with other agricultural soils using a slash‐and‐burn chronosequence. Soil samples (0–5, 5–10 and...

FEBS Journal

Identifying pseudoenzymes using functional annotation. How loss of function correlates with mutations in the catalytic site

Published: 05 December 2019

Author(s): Antonio J. M. Ribeiro, Jonathan D. Tyzack, Neera Borkakoti, Janet M. Thornton

Pseudoenzymes are proteins that are evolutionary related to enzymes but lack relevant catalytic activity. They are usually evolved from enzymatic ancestors that have lost their catalytic activities. The loss of catalytic function is one extreme amongst the other evolutionary changes that can occur to enzymes, like the changing of substrate specificity or the reaction catalysed. However, the loss of catalytic function events remain poorly characterised, except for some notable examples, like...

Fuel Cells

Evaluation of Graphene Nanoplatelets as a Microporous Layer Material for PEMFC: Performance and Durability Analysis

Published: 05 December 2019

Author(s): M. Mariani, S. Latorrata, P. Gallo Stampino, G. Dotelli

Abstract In this paper, the effect of different carbonaceous phases in microporous layers (MPLs) for polymer electrolyte membrane fuel cells (PEMFCs) is reported. A conventional ink with carbon black (CB) powder and an innovative one featuring graphene nanoplatelets (GNPs) have been produced and used to coat carbon cloth gas diffusion layers (GDLs). Morphological and electrical properties of these samples have been assessed and then compared to determine which characteristics contribute to a...

European Journal of Inorganic Chemistry

Synthesis of RE6–xCa1.5xSi11N20O (RE = Yb, Lu; x ≈ 2.2) with Lu6–xCa1.5xSi11N20O:Ce3+ Offering Interesting Spectral Properties for Yellow‐Emitting Phosphors in 1pcLEDs

Published: 05 December 2019

Author(s): Lisa Gamperl, Georg Krach, Peter J. Schmidt, Wolfgang Schnick

The oxonitridosilicates RE6–xCa1.5xSi11N20O (RE = Yb, Lu; x ≈ 2.2) were synthesized starting from REF3, CaH2, and ”Si(NH)2” in a radiofrequency furnace at 1600 or 1400 °C, respectively. The crystal structure was solved and refined from single‐crystal X‐ray diffraction data of dark red Yb6–xCa1.5xSi11N20O crystals in the trigonal space group P31c (no. 159) with a = 9.8281(10), c = 10.5968(13) Å and Z = 2. The structure represents a filled variant of the Er6Si11N20O structure type, in which the...

European Journal of Inorganic Chemistry

Expanding the Scope of Water‐Stable Rhenium(V)‐NHC Complexes – Synthesis, Characterization, and Derivatization

Published: 05 December 2019

Author(s): Dustin Bornemann, Lukas Schlemper, Nils Trapp, Antonio Togni

The synthesis of novel ReV–NHC oxo complexes bearing a tridentate scorpionate NHC ligand is reported. The complexes are accessible in a two‐step procedure from the precursor (NnBu4)[ReOCl4] by in situ deprotonation of the imidazolium salt 2,2‐bis(3‐methyl‐1H‐imidazol‐3‐ium‐1‐yl)acetate bromide (L1‐H2) using sodium hydride. The obtained complex [ReO(glyc)L1] (glyc = ethylene glycolato) is readily converted into [ReOCl2(L1)] which serves as starting material for the synthesis of water stable...

European Journal of Inorganic Chemistry

Rhenium(V) Complexes with Selenolato‐ and Tellurolato‐Substituted Schiff Bases – Released PPh3 as a Facile Reductant

Published: 05 December 2019

Author(s): Maximilian Roca Jungfer, Adelheid Hagenbach, Ernesto Schulz Lang, Ulrich Abram

The salicylidene Schiff bases of bis(2‐aminophenyl)diselenide and ‐ditelluride react with [ReOCl3(PPh3)2] or the arylimidorhenium(V) compounds [Re(NPhR)Cl3(PPh3)2] (R = H, F, CF3) with formation of rhenium(V) complexes with tridentate {O,N,Se/Te} chalcogenolato ligands. The ligands adopt a facial coordination mode with the oxygen donors trans to the multiply bonded O2– or NPhR2– ligands. The reduction of the dichalcogenides and the formation of the chalcogenolato ligands occurs in situ by...

Fuel Cells

Corrosion Resistant Al‐Cr‐Mo Alloy Coating on Type 316L Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cell Applications

Published: 05 December 2019

Author(s): A. V. Ingle, V. S. Raja, J. Rangarajan, P. Mishra

Abstract The most important issues that plague wider use of polymer electrolyte membrane fuel cells (PEMFCs) are insufficient corrosion resistance, electrical conductivity and wettability of metallic bipolar plates (BPPs). To address these issues, an amorphous Al‐Cr‐Mo ternary alloy coating is applied on type 316L stainless steel using direct current magnetron sputtering. The electrochemical corrosion behavior of bare and alloy coated specimens has been investigated by polarization and...

European Journal of Inorganic Chemistry

Vinyl‐/Furoindoles and Gold Catalysis: New Achievements and Future Perspectives for the Synthesis of Complex Indole Derivatives

Published: 05 December 2019

Author(s): Valentina Pirovano, Giorgio Abbiati, Elisa Brambilla, Elisabetta Rossi

The reactivity of vinyl‐/furoindole derivatives with gold‐activated π‐systems is the subject of extensive investigation. In the presence of these electrophilic partners, the realized transformations allow for the construction of different and fascinating architectures via cycloaddition and cyclization reactions often included in cascade processes. The reactions realized involving in these processes an external substituent at the indole moiety are the subject of the present minireview.

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

August 2019


	Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless Click Chemistry: Diverse Chemical Function from a Few Good Reactions [Review] Angew. Chem. Int. Ed. 2001, vol. 40, no. 11, p. 2004

	Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication] ChemBioChem 2018, vol. 19, no. 14, p. 1471

	Petra E. de Jongh, Deryn E. Fogg, Li-Zhu Wu, Sandra González-Gallardo Meet the Women of Catalysis [Editorial] ChemCatChem 2019, vol. 11, no. 16, p. 3557

	V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

	Rainer Stosch, Olaf Rienitz, Axel Pramann, Bernd Güttler Wie viele Moleküle enthält ein Mol? [Artikel] Chem. Unserer Zeit 2019, vol. 53, no. 4, p. 256

	Benjamin A. E. Lehner, Vera A. E. C. Janssen, Ewa M. Spiesz, Dominik Benz, Stan J. J. Brouns, Anne S. Meyer, Herre S. J. van der Zant Creation of Conductive Graphene Materials by Bacterial Reduction Using Shewanella Oneidensis [Full Paper] ChemistryOpen 2019, vol. 8, no. 7, p. 888

	Hanshen Xin, Xike Gao Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview] ChemPlusChem 2017, vol. 82, no. 7, p. 945

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Michael C. Zimmermann, Thomas N. Otto, Simon Wodarz, Thomas A. Zevaco, Stephan Pitter Mesoporous H-ZSM-5 for the Conversion of Dimethyl Ether to Hydrocarbons [Research Article] Chem. Ing. Tech. 2019, vol. 91, no. 9, p. 1302

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Andrey Shatskiy, Helena Lundberg, Markus D. Kärkäs Organic Electrosynthesis: Applications in Complex Molecule Synthesis [Review] ChemElectroChem 2019, vol. 6, no. 16, p. 4067

	S. Ghosh, B. Pradhan Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview] ChemNanoMat 2019, vol. 5, no. 3, p. 300

	João M. J. M. Ravasco, Hélio Faustino, Alexandre Trindade, Pedro M. P. Gois Bioconjugation with Maleimides: A Useful Tool for Chemical Biology [Review] Chem. Eur. J. 2019, vol. 25, no. 1, p. 43

	Stephanie C. C. van der Lubbe, Célia Fonseca Guerra The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview] Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

	Adrian G. Amador, Evan M. Sherbrook, Tehshik P. Yoon A Redox Auxiliary Strategy for Pyrrolidine Synthesis via Photocatalytic [3+2] Cycloaddition [Full Paper] Asian J. Org. Chem. 2019, vol. 8, no. 7, p. 978

	Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu Covalent Inhibition in Drug Discovery [Review] ChemMedChem 2019, vol. 14, no. 9, p. 889

	Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa CO₂ Activation over Catalytic Surfaces [Concept] ChemPhysChem 2017, vol. 18, no. 22, p. 3135

	Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication] ChemPhotoChem 2019, vol. 3, no. 1, p. 24

	Biwei Xiao, Teófilo Rojo, Xiaolin Li Hard Carbon as Sodium-Ion Battery Anodes: Progress and Challenges [Minireview] ChemSusChem 2019, vol. 12, no. 1, p. 133

	Didier Astruc Why is Ferrocene so Exceptional? [Microreview] Eur. J. Inorg. Chem. 2017, p. 6

	Kennedy J. Ngwira, Jonas Kühlborn, Quintino A. Mgani, Charles B. de Koning, Till Opatz Front Cover: Valorisation of Cashew Nut Shell Liquid Phenolics in the Synthesis of UV Absorbers (Eur. J. Org. Chem. 30/2019) [Cover Picture] Eur. J. Org. Chem. 2019, p. 4763

	Cover Picture Lebensmittelchemie 4/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73, no. 4

	Olaf Deutschmann, Roland Dittmeyer, Jan-Dierk Grunwaldt, Gunther Kolb, Stefan Löbbecke, Gregor D. Wehinger Technische Chemie [Wissenschaft + Forschung] Nachr. Chem. 2019, vol. 67, no. 6, p. 50

	Titelbild: (CHEMKON 5/2019) [Titelbild] CHEMKON 2019, vol. 26, no. 5, p. 173

	Zheng Ma, Douglas R. MacFarlane, Mega Kar Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview] Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal

2017


	Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

	Philippe Compain, Anne Bodlenner The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview] ChemBioChem 2014, vol. 15, pp. 1239–1251

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez Gated Silica Mesoporous Materials in Sensing Applications [Review] ChemistryOpen 2015, vol. 4, pp. 418–437

	Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang Direct Growth of NiCo₂S₄ Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper] ChemPlusChem 2014, vol. 79, pp. 577–583

	Francisco Trespalacios, Ignacio E. Grossmann Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review] Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview] Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

	Derong Cao, Herbert Meier Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review] Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

	Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann Bromodomains and Their Pharmacological Inhibitors [Review] ChemMedChem 2014, vol. 9, pp. 438–464

	Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera The Bright Future of Unconventional σ/π-Hole Interactions [Review] ChemPhysChem 2015, vol. 16, pp. 2496–2517

	Ksenia S. Egorova, Valentine P. Ananikov Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review] ChemSusChem 2014, vol. 7, pp. 336–360

	Shunichi Fukuzumi, Dachao Hong Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview] Eur. J. Inorg. Chem. 2014, pp. 645–659

	Fabien Toulgoat, Sébastien Alazet, Thierry Billard Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview] Eur. J. Org. Chem. 2014, pp. 2415–2428

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941