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Chemistry - A European Journal

Luminescent Anion Sensing by Transition‐Metal Dipyridylbenzene Complexes Incorporated into Acyclic, Macrocyclic and Interlocked Hosts

Published: 01 April 2020

Author(s): Richard C. Knighton, Sophie Dapin, Paul D. Beer

Abstract A series of novel acyclic, macrocyclic and mechanically interlocked luminescent anion sensors have been prepared by incorporation of the isophthalamide motif into dipyridylbenzene to obtain cyclometallated complexes of platinum(II) and ruthenium(II). Both the acyclic and macrocyclic derivatives 7⋅Pt, 7⋅Ru⋅PF6, 10⋅Pt and 10⋅Ru⋅PF6 are effective sensors for a range of halides and oxoanions. The near‐infra red emitting ruthenium congeners exhibited an increased binding strength compared...

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ChemSusChem

Exploiting Polythiophenyl‐Triazine‐Based Conjugated Microporous Polymer with Superior Lithium‐Storage Performance

Published: 01 April 2020

Author(s): Shi‐Bin Ren, Wenyan Ma, Chong Zhang, Lei Chen, Kai Wang, Rong‐Rong Li, Mao Shen, De‐Man Han, Yuxiang Chen, Jia‐Xing Jiang

Abstract Conjugated microporous polymers (CMPs) have been heralded as promising energy‐storage materials with advantages such as chemical flexibility, porous structure, and environmentally friendliness. Herein, a novel conjugated microporous polymer was synthesized by integrating triazine, thiophene, and benzothiadiazole into a polymer skeleton, and the Li+‐storage performance for the as‐synthesized polymer anode in Li‐ion batteries (LIBs) was investigated. Benefiting from the inherent large...

Asia-Pacific Journal of Chemical Engineering

Influence of overflow port selection on the gas desulfurization of gas cyclone–liquid jet absorption separator

Published: 01 April 2020

Author(s): Liang Ma, Lv Peng, Zheng‐Wei Zhang, Cheng‐Cheng Tian

Abstract The purification of industrial sulfur‐containing tail gas mainly adopts the wet flue gas desulfurization of gas–liquid mass transfer, and a new separator utilizes the gas–liquid coupling field to rapidly update the effective phase boundary area in the reaction process to enhance the mass transfer effect. This study used NaOH solution as the reaction liquid phase to determine the effects of the selection of overflow port of gas cyclone–liquid jet absorption separator on gas...

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ChemSusChem

Aminomethyl‐Functionalized Carbon Nanotubes as a Host of Small Sulfur Clusters for High‐Performance Lithium–Sulfur Batteries

Published: 01 April 2020

Author(s): Fen Li, Jiayou Tao, Zhijun Zou, Chang Li, Zhaohui Hou, Jijun Zhao

Abstract Here we propose an effective strategy to stabilize small sulfur species by using aminomethyl‐functionalized carbon nanotubes (AM‐CNT) without impairing the conductive channel of the carbon nanotube (CNT) cathode. The linear Sn clusters can be anchored strongly to the AM‐CNT for the favorable size of n=5 and the maximum size of n=6 in the production of the cathode, which depresses the mass loss of active sulfur effectively and eliminates the formation of high‐order polysulfides...

Zeitschrift für anorganische und allgemeine Chemie

Luminescent Symmetrically and Unsymmetrically Substituted Diboranes(4)

Published: 01 April 2020

Author(s): Yvonne Kaiser, Alexander Grandjean, Volker Huch, Michael Zimmer, Gregor Jung, David Scheschkewitz

A series of 4‐(dimethylamino)phenyl and pentafluorophenyl‐substituted 1,2‐bis(dimethylamino)diboranes(4) of type A, benzo‐fused cyclic 1,4‐diaza‐2,3‐diborinanes of type B, and 1,2‐diduryldiboranes(4) of type C were synthesized and structurally characterized. Spectroscopic studies revealed that the substitution pattern is a decisive factor for the observation of fluorescence in most of the derivatives A to C. For diboranes(4) of type A, unsymmetrical substitution with electron‐donating and...

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Advanced Materials

Heat Engine Drives Transport of an FeII4L4 Cage and Cargo

Published: 01 April 2020

Author(s): Bao‐Nguyen T. Nguyen, Angela B. Grommet, Arnaud Tron, Maureen C. A. Georges, Jonathan R. Nitschke

Abstract The directed motion of species against a chemical potential gradient is a fundamental feature of living systems, underpinning processes that range from transport through cell membranes to neurotransmission. The development of artificial active cargo transport could enable new modes of chemical purification and pumping. Here, a heat engine is described that drives chemical cargo between liquid phases to generate a concentration gradient. The heat engine, composed of a functionalized...

European Journal of Organic Chemistry

Photocatalytic Synthesis of 3‐Sulfanyl‐ and 1,3‐Bis(sulfanyl)indolizines Mediated by Visible Light

Published: 01 April 2020

Author(s): Filipe Penteado, Caroline S. Gomes, Loana I. Monzon, Gelson Perin, Claudio C. Silveira, Eder J. Lenardão

A metal‐free method for the synthesis of 3‐sulfanyl indolizines from thiols and 2‐arylindolizines, is reported. The reaction is mediated by eosin Y under blue LED light irradiation and uses atmospheric oxygen as oxidant. By the use of a catalytic amount of I2, the corresponding 1,3‐bis‐sulfanyl indolizines are obtained, in good yields.

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Molecular Nutrition & Food Research

Hormonal Dysregulation and Unbalanced Specialized Pro‐Resolving Mediator Biosynthesis Contribute toward Impaired B Cell Outcomes in Obesity

Published: 01 April 2020

Author(s): Miranda Crouch, Abrar Al‐Shaer, Saame Raza Shaikh

Abstract Diet‐induced obesity is associated with impaired B‐cell‐driven humoral immunity, which coincides with chronic inflammation and has consequences for responses to infections and vaccinations. Key nutritional, cellular, and molecular mechanisms by which obesity may impair aspects of humoral immunity such as B cell development, class switch recombination, and formation of long‐lived antibody secreting cells are reviewed. A key theme to emerge is the central role of white adipose tissue on...

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Chemistry - A European Journal

A Regulable Internal Cavity inside a Resorcinarene‐Based Hemicarcerand

Published: 01 April 2020

Author(s): Kentaro Harada, Ryo Sekiya, Takeharu Haino

Abstract Covalent organic capsules, such as carcerands and hemicarcerands, are an interesting class of molecular hosts. These container molecules have confined spaces capable of hosting small molecules, although the fact that the size of the inner cavities cannot be changed substantially limits the scope of their applications. The title covalently linked container was produced by metal‐directed dimerization of a resorcinarene‐based cavitand having four 2,2′‐bipyridyl arms on the wide rim...

European Journal of Organic Chemistry

Palladium‐Catalyzed Cyanation of Aryl Halides Using Formamide and Cyanuric Chloride as a New “CN” Source

Published: 01 April 2020

Author(s): Esmaeil Niknam, Farhad Panahi, Ali Khalafi‐Nezhad

A new source of “CN” employing formamide and cyanuric chloride is introduced for the cyanation reactions. The treatment of formamide and 2,4,6‐trichloro‐1,3,5‐triazine (TCT; cyanuric chloride) afforded an efficient cyanating agent which it can be used as a nontoxic, readily available, and non‐expensive reagent in the cyanation transformations. In this study, palladium‐catalyzed cyanation of aryl halides was successfully accomplished using this new “CN” source in high yields.

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Most-accessed articles from each Chemistry Europe, ACES, and GDCh journal

January 2020


	Hendrik Naatz, Bella B. Manshian, Carla Rios Luci, Vasiliki Tsikourkitoudi, Yiannis Deligiannakis, Johannes Birkenstock, Suman Pokhrel, Lutz Mädler, Stefaan J. Soenen Model-Based Nanoengineered Pharmacokinetics of Iron-Doped Copper Oxide for Nanomedical Applications [Research Article] Angew. Chem. Int. Ed. 2020, vol. 59, no. 5, p. 1828

	Marc-André Kasper, Marcus Gerlach, Anselm F. L. Schneider, Christiane Groneberg, Philipp Ochtrop, Stefanie Boldt, Dominik Schumacher, Jonas Helma, Heinrich Leonhardt, Mathias Christmann, Christian P. R. Hackenberger N-Hydroxysuccinimide-Modified Ethynylphosphonamidates Enable the Synthesis of Configurationally Defined Protein Conjugates [Full Paper] ChemBioChem 2020, vol. 21, no. 1-2, p. 113

	Michael Bowker Methanol Synthesis from CO₂ Hydrogenation [Minireview] ChemCatChem 2019, vol. 11, no. 17, p. 4238

	V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article] Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

	Dieter Wöhrle Kunststoffe [Artikel] Chem. Unserer Zeit 2019, vol. 53, no. 1, p. 50

	Balaram Mukhopadhyay, Rituparna Das Chemical O-Glycosylations: An Overview [Review] ChemistryOpen 2016, vol. 5, no. 5, p. 401

	Daewoo Han, Andrew J. Steckl Coaxial Electrospinning Formation of Complex Polymer Fibers and their Applications [Review] ChemPlusChem 2019, vol. 84, no. 10, p. 1453

	Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone High-Selectivity Electrochemical Conversion of CO₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper] ChemistrySelect 2016, vol. 1, no. 19, p. 6055

	Rüdiger-A. Eichel, Walter Leitner, Kurt Wagemann Warum wir uns mit Power-to-X beschäftigen [Editorial] Chem. Ing. Tech. 2020, vol. 92, no. 1-2, p. 3

	Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review] ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

	Gerhard Hilt Basic Strategies and Types of Applications in Organic Electrochemistry [Concept] ChemElectroChem 2020, vol. 7, no. 2, p. 395

	Claire M. Cobley Introducing our Inaugural Early Career Advisory Board [Editorial] ChemNanoMat 2020, vol. 6, no. 1, p. 4

	Felix Blei, Sebastian Dörner, Janis Fricke, Florian Baldeweg, Felix Trottmann, Anna Komor, Florian Meyer, Christian Hertweck, Dirk Hoffmeister Simultaneous Production of Psilocybin and a Cocktail of β-Carboline Monoamine Oxidase Inhibitors in “Magic” Mushrooms [Full Paper] Chem. Eur. J. 2020, vol. 26, no. 3, p. 729

	Sandip G. Agalave, Suleman R. Maujan, Vandana S. Pore Click Chemistry: 1,2,3‐Triazoles as Pharmacophores [Focus Review] Chem. Asian J. 2011, vol. 6, no. 10, p. 2696

	Arun K. Sinha, Danish Equbal Thiol−Ene Reaction: Synthetic Aspects and Mechanistic Studies of an Anti-Markovnikov-Selective Hydrothiolation of Olefins [Focus Review] Asian J. Org. Chem. 2019, vol. 8, no. 1, p. 32

	Thomas H. Pillow, Pragya Adhikari, Robert A. Blake, Jinhua Chen, Geoffrey Del Rosario, Gauri Deshmukh, Isabel Figueroa, Karen E. Gascoigne, Amrita V. Kamath, Susan Kaufman, Tracy Kleinheinz, Katherine R. Kozak, Brandon Latifi, Douglas D. Leipold, Chun Sing Li, Ruina Li, Melinda M. Mulvihill, Aimee O'Donohue, Rebecca K. Rowntree, Jack D. Sadowsky, John Wai, Xinxin Wang, Cong Wu, Zijin Xu, Hui Yao, Shang-Fan Yu, Donglu Zhang, Richard Zang, Hongyan Zhang, Hao Zhou, Xiaoyu Zhu, Peter S. Dragovich Antibody Conjugation of a Chimeric BET Degrader Enables in vivo Activity [Full Paper] ChemMedChem 2020, vol. 15, no. 1, p. 17

	Vitali Tugarinov, Theodoros K. Karamanos, Alberto Ceccon, G. Marius Clore Optimized NMR Experiments for the Isolation of I=1/2 Manifold Transitions in Methyl Groups of Proteins [Communication] ChemPhysChem 2020, vol. 21, no. 1, p. 13

	Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors [Review] ChemPhotoChem 2018, vol. 2, no. 5, p. 386

	Kassem Beydoun, Jürgen Klankermayer Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing [Communication] ChemSusChem 2020, vol. 13, no. 3, p. 488

	Stephen A. Matlin, Goverdhan Mehta, Henning Hopf, Alain Krief The Periodic Table of the Chemical Elements and Sustainable Development [Essay] Eur. J. Inorg. Chem. 2019, p. 4170

	Luca Capaldo, Davide Ravelli Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis [Microreview] Eur. J. Org. Chem. 2017, p. 2056

	Cover Picture Lebensmittelchemie 6/2019 [Cover Picture] Lebensmittelchemie 2019, vol. 73, no. 6

	Christian Hering-Junghans, Christian Sindlinger Trendbericht Anorganische Chemie: Hauptgruppen [Wissenschaft + Forschung] Nachr. Chem. 2020, vol. 68, no. 1, p. 50

	Jana Novotny, Corina Wagner, Marco Oetken Titelbild: Elektrochemisch aktive Polymere am Beispiel Polypyrrol: Modellsystem einer künstlichen Synapse Ein elektrochemischer Alleskönner - Teil 2 (CHEMKON 8/2019) [Titelbild] CHEMKON 2019, vol. 26, no. 8, p. 331

	Meng Cheng, Ramasubramonian Deivanayagam, Reza Shahbazian-Yassar 3D Printing of Electrochemical Energy Storage Devices: A Review of Printing Techniques and Electrode/Electrolyte Architectures [Review] Batteries & Supercaps 2020, vol. 3, no. 2, p. 130

	Catharina Goedecke Why Does Iodine Turn Starch Blue? ChemViews Magazine 2016

Most cited articles from each Chemistry Europe, ACES, and GDCh journal

2017


	Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

	Philippe Compain, Anne Bodlenner The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview] ChemBioChem 2014, vol. 15, pp. 1239–1251

	Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou Metal–Organic Frameworks as Biomimetic Catalysts [Minireview] ChemCatChem 2014, vol. 6, pp. 67–75

	Anthony J. Arduengo, Roland Krafczyk Auf der Suche nach Stabilen Carbenen [Organische Chemie] Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

	Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez Gated Silica Mesoporous Materials in Sensing Applications [Review] ChemistryOpen 2015, vol. 4, pp. 418–437

	Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang Direct Growth of NiCo₂S₄ Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper] ChemPlusChem 2014, vol. 79, pp. 577–583

	Francisco Trespalacios, Ignacio E. Grossmann Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review] Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

	Xiaosi Zhou, Yu-Guo Guo Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication] ChemElectroChem 2014, vol. 1, pp. 83–86

	Chuanxi Wang, Zhenzhu Xu, Chi Zhang Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper] ChemNanoMat 2015, vol. 1, pp. 122–127

	Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview] Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

	Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp²)–H Bonds [Focus Review] Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

	Derong Cao, Herbert Meier Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review] Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

	Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann Bromodomains and Their Pharmacological Inhibitors [Review] ChemMedChem 2014, vol. 9, pp. 438–464

	Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera The Bright Future of Unconventional σ/π-Hole Interactions [Review] ChemPhysChem 2015, vol. 16, pp. 2496–2517

	Ksenia S. Egorova, Valentine P. Ananikov Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review] ChemSusChem 2014, vol. 7, pp. 336–360

	Shunichi Fukuzumi, Dachao Hong Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview] Eur. J. Inorg. Chem. 2014, pp. 645–659

	Fabien Toulgoat, Sébastien Alazet, Thierry Billard Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview] Eur. J. Org. Chem. 2014, pp. 2415–2428

	David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar Mit Klick zu neuen Liganden [Magazin] Nachr. Chem. 2011, vol. 59, pp. 937–941