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Environmental Progress & Sustainable Energy

An effective toluene removal from waste‐air by a simple process based on absorption in silicone oil (PDMS) and cross‐linked Brassica rapa peroxidase (BRP‐CLEAs) catalysis in organic medium: Optimization with RSM

Published: 13 December 2019

Author(s): Nassima Tandjaoui, Dominique Wolbert, Annabelle Couvert, Mahmoud Abouseoud, Abdeltif Amrane, Amina Tassist

Abstract In the present study, absorption in an organic solvent followed by enzymatic biodegradation by cross‐linked peroxidase from Brassica rapa (BRP‐CLEAs) was successfully applied as a solution for toluene removal from waste‐air in batch experiments. Silicone oil (PDMS 47V20) showed a high capacity for toluene absorption, regarding its air‐PDMS partition coefficient (2.08 Pa m3 mol−1) when compared to air‐water (666 Pa m3 mol−1). Box–Behnken restricted duplicate design was employed for the...

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Phytotherapy Research

Beneficial effects of Codonopsis lanceolata extract on systolic blood pressure levels in prehypertensive adults: A double‐blind, randomized controlled trial

Published: 13 December 2019

Author(s): You Kyoung Shin, Yu Shan Hsieh, A Young Han, Kwang‐Won Lee, Geun Hee Seol

Codonopsis lanceolata (CL) extract was shown to have antihypertensive effects in hypertensive rats. This randomized controlled trial was designed to investigate the ability of CL extract to prevent hypertension (HTN) in prehypertensive subjects. Eighty subjects aged 19–60 years with a systolic blood pressure (BP) of 120–139 mmHg and a diastolic BP of 80–89 mmHg were recruited over 3 months. Subjects were randomized 1:1 to a CL group and a placebo (PL) group and administered CL extract and...

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Journal of the Chinese Chemical Society

Profound synergetic effect of metal oxide promoters and TiO2–SiO2 binary support in cobalt Fischer‐Tropsch catalyst

Published: 13 December 2019

Author(s): Akbar Zamaniyan, Saeed Zarrinpashne, Yahya Zamani, Elham Yaghoobpour

Abstract A series of cobalt catalysts supported on TiO2, SiO2, or a mixture of them, incorporated with some added oxides from Groups III, IV, and V of transition metals, were prepared using the incipient wetness impregnation method. For better evaluation of catalysts, the physicochemical properties of catalysts were investigated using brunauer‐emmett‐teller (BET), H2‐TPR, NH3‐TPD, X‐ray diffraction, X‐ray photoelectron spectroscopy, and transmission electron microscopy techniques. The...

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Angewandte Chemie International Edition

Fluorous Corannulenes: Ab initio Predictions and the Synthesis of sym‐Pentafluorocorannulene

Published: 13 December 2019

Author(s): Xiaoqi Tian, Jun Xu, Kim K. Baldridge, Jay S. Siegel

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Angewandte Chemie International Edition

Programming DNA Nanoassembly for Enhanced Photodynamic Therapy

Published: 13 December 2019

Author(s): Min Pan, Qunying Jiang, Junlin Sun, Zhen Xu, Yizhuo Zhou, Li Zhang, Xiaoqing Liu

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Journal of Heterocyclic Chemistry

Anti‐corrosive property of bioinspired environmental benign imidazole and isoxazoline heterocyclics: A cumulative studies of experimental and DFT methods

Published: 13 December 2019

Author(s): Chandrabhan Verma, Eno E. Ebenso, Mumtaz A. Quraishi, D. Nalini, Sowmya Ramkumar

Abstract In the present study, four imidazoline (IDZ) and four isoxazolines (ISO) heterocyclics differing in the nature of methoxy (‐OCH3) and aromatic (phenyl and naphthyl) moieties are synthesized, characterized and evaluated as corrosion inhibitors for mild steel in acidic solution of 1 M HCl. Results showed that imidazoline based heterocyclic compounds are better corrosion inhibitors than isoxazoline based heterocyclics and both classes of compounds showed inhibition efficiency of more...

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Angewandte Chemie

Efficient Heterogeneous Palladium‐Catalyzed Oxidative Cascade Reactions of Enallenols to Furan and Oxaborole Derivatives

Published: 13 December 2019

Author(s): Man‐Bo Li, Daniels Posevins, Antoine Geoffroy, Can Zhu, Jan‐E. Bäckvall

Abstract A heterogeneous palladium‐catalyzed oxidative cyclization of enallenols has been developed for the construction of highly substituted furan and oxaborole derivatives. The heterogeneous catalyst (Pd‐AmP‐MCF) exhibits high activity, high site‐ and stereoselectivity, and efficient palladium recyclability in the transformations.

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Phytotherapy Research

Diosmetin exhibits anti‐proliferative and anti‐inflammatory effects on TNF‐α‐stimulated human rheumatoid arthritis fibroblast‐like synoviocytes through regulating the Akt and NF‐κB signaling pathways

Published: 13 December 2019

Author(s): You Chen, Yongsheng Wang, Min Liu, Bingkang Zhou, Guangjie Yang

Rheumatoid arthritis (RA) is a chronic inflammatory disease characterized by inflammation and proliferation of synovial tissues. Diosmetin is a bioflavonoid possessing an anti‐inflammatory property. Herein, we aimed to study the effects of diosmetin on the inflammation and proliferation of RA fibroblast‐like synoviocytes MH7A cells. MH7A cell proliferation was measured using cell counting kit‐8 assay. Cell apoptosis was examined using flow cytometry. The production of inflammatory cytokines...

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Angewandte Chemie

Palladium‐Catalyzed Asymmetric [4+3] Cyclization of Trimethylenemethane: Regio‐, Diastereo‐, and Enantioselective Construction of Benzofuro[3,2‐b]azepine Skeletons

Published: 13 December 2019

Author(s): Yang‐Zi Liu, Zhongao Wang, Zesheng Huang, Xing Zheng, Wu‐Lin Yang, Wei‐Ping Deng

Abstract The palladium‐catalyzed asymmetric [4+3] cyclization of trimethylenemethane donors with benzofuran‐derived azadienes furnishes chiral benzofuro[3,2‐b]azepine frameworks in high yields (up to 98 %) with exclusive regioselectivities and excellent stereoselectivities (up to 20:1 d.r., 99 % ee). This catalytic asymmetric [4+3] cyclization of Pd‐trimethylenemethane can enrich the arsenal of Pd‐TMM reactions in organic synthesis. In addition, this strategy provides an alternative approach...

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Angewandte Chemie

Hybrid Plasmonic–Aerogel Materials as Optical Superheaters with Engineered Resonances

Published: 13 December 2019

Author(s): Benjamin Klemmed, Lucas V. Besteiro, Albrecht Benad, Maximilian Georgi, Zhiming Wang, Alexander Govorov, Alexander Eychmüller

Abstract Solar radiation is a versatile source of energy, convertible to different forms of power. A direct path to exploit it is the generation of heat, for applications including passive building heating, but it can also drive secondary energy‐conversion steps. We present a novel concept for a hybrid material which is both strongly photo‐absorbing and with superior characteristics for the insulation of heat. The combination of that two properties is rather unique, and make this material an...

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Most-accessed articles from each ChemPubSoc Europe, ACES, and GDCh journal

August 2019


Hartmuth C. Kolb, M. G. Finn, K. Barry Sharpless
Click Chemistry: Diverse Chemical Function from a Few Good Reactions [Review]
Angew. Chem. Int. Ed. 2001, vol. 40, no. 11, p. 2004

Bing Liu, Lihui He, Liping Wang, Tao Li, Changcheng Li, Huayi Liu, Yunzi Luo, Rui Bao
Protein Crystallography and Site-Direct Mutagenesis Analysis of the Poly(ethylene terephthalate) Hydrolase PETase from Ideonella sakaiensis [Communication]
ChemBioChem 2018, vol. 19, no. 14, p. 1471

Petra E. de Jongh, Deryn E. Fogg, Li-Zhu Wu, Sandra González-Gallardo
Meet the Women of Catalysis [Editorial]
ChemCatChem 2019, vol. 11, no. 16, p. 3557

V. N. Danilevich, L. E. Petrovskaya, E. V. Grishin
A Highly Efficient Procedure for the Extraction of Soluble Proteins from Bacterial Cells with Mild Chaotropic Solutions [Research Article]
Chem. Eng. Technol. 2008, vol. 31, no. 6, p. 904

Rainer Stosch, Olaf Rienitz, Axel Pramann, Bernd Güttler
Wie viele Moleküle enthält ein Mol? [Artikel]
Chem. Unserer Zeit 2019, vol. 53, no. 4, p. 256

Benjamin A. E. Lehner, Vera A. E. C. Janssen, Ewa M. Spiesz, Dominik Benz, Stan J. J. Brouns, Anne S. Meyer, Herre S. J. van der Zant
Creation of Conductive Graphene Materials by Bacterial Reduction Using Shewanella Oneidensis [Full Paper]
ChemistryOpen 2019, vol. 8, no. 7, p. 888

Hanshen Xin, Xike Gao
Application of Azulene in Constructing Organic Optoelectronic Materials: New Tricks for an Old Dog [Minireview]
ChemPlusChem 2017, vol. 82, no. 7, p. 945

Miaofang Chi, Harry M. Meyer, Zili Wu, Liangbo Liang, Peter V. Bonnesen, Dale K. Hensley, Rui Peng, Yang Song, Cheng Ma, Bobby G. Sumpter, Adam J. Rondinone
High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode [Full Paper]
ChemistrySelect 2016, vol. 1, no. 19, p. 6055

Michael C. Zimmermann, Thomas N. Otto, Simon Wodarz, Thomas A. Zevaco, Stephan Pitter
Mesoporous H-ZSM-5 for the Conversion of Dimethyl Ether to Hydrocarbons [Research Article]
Chem. Ing. Tech. 2019, vol. 91, no. 9, p. 1302

Abas Mohsenzadeh, Akram Zamani, Mohammad J. Taherzadeh
Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation [Review]
ChemBioEng Rev. 2017, vol. 4, no. 2, p. 75

Andrey Shatskiy, Helena Lundberg, Markus D. Kärkäs
Organic Electrosynthesis: Applications in Complex Molecule Synthesis [Review]
ChemElectroChem 2019, vol. 6, no. 16, p. 4067

S. Ghosh, B. Pradhan
Lead-Free Metal Halide Perovskite Nanocrystals: Challenges, Applications, and Future Aspects [Minireview]
ChemNanoMat 2019, vol. 5, no. 3, p. 300

João M. J. M. Ravasco, Hélio Faustino, Alexandre Trindade, Pedro M. P. Gois
Bioconjugation with Maleimides: A Useful Tool for Chemical Biology [Review]
Chem. Eur. J. 2019, vol. 25, no. 1, p. 43

Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths [Minireview]
Chem. Asian J. 2019, vol. 14, no. 16, p. 2760

Adrian G. Amador, Evan M. Sherbrook, Tehshik P. Yoon
A Redox Auxiliary Strategy for Pyrrolidine Synthesis via Photocatalytic [3+2] Cycloaddition [Full Paper]
Asian J. Org. Chem. 2019, vol. 8, no. 7, p. 978

Avick Kumar Ghosh, Indranil Samanta, Anushree Mondal, Wenshe Ray Liu
Covalent Inhibition in Drug Discovery [Review]
ChemMedChem 2019, vol. 14, no. 9, p. 889

Andrea Álvarez, Marta Borges, Juan José Corral-Pérez, Joan Giner Olcina, Lingjun Hu, Damien Cornu, Rui Huang, Dragos Stoian, Atsushi Urakawa
CO2 Activation over Catalytic Surfaces [Concept]
ChemPhysChem 2017, vol. 18, no. 22, p. 3135

Matthias Freitag, Nadja Möller, Andreas Rühling, Cristian A. Strassert, Bart Jan Ravoo, Frank Glorius
Photocatalysis in the Dark: Near-Infrared Light Driven Photoredox Catalysis by an Upconversion Nanoparticle/Photocatalyst System [Communication]
ChemPhotoChem 2019, vol. 3, no. 1, p. 24

Biwei Xiao, Teófilo Rojo, Xiaolin Li
Hard Carbon as Sodium-Ion Battery Anodes: Progress and Challenges [Minireview]
ChemSusChem 2019, vol. 12, no. 1, p. 133

Didier Astruc
Why is Ferrocene so Exceptional? [Microreview]
Eur. J. Inorg. Chem. 2017, p. 6

Kennedy J. Ngwira, Jonas Kühlborn, Quintino A. Mgani, Charles B. de Koning, Till Opatz
Front Cover: Valorisation of Cashew Nut Shell Liquid Phenolics in the Synthesis of UV Absorbers (Eur. J. Org. Chem. 30/2019) [Cover Picture]
Eur. J. Org. Chem. 2019, p. 4763

Cover Picture Lebensmittelchemie 4/2019 [Cover Picture]
Lebensmittelchemie 2019, vol. 73, no. 4

Olaf Deutschmann, Roland Dittmeyer, Jan-Dierk Grunwaldt, Gunther Kolb, Stefan Löbbecke, Gregor D. Wehinger
Technische Chemie [Wissenschaft + Forschung]
Nachr. Chem. 2019, vol. 67, no. 6, p. 50

Titelbild: (CHEMKON 5/2019) [Titelbild]
CHEMKON 2019, vol. 26, no. 5, p. 173

Zheng Ma, Douglas R. MacFarlane, Mega Kar
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review [Minireview]
Batteries & Supercaps 2019, vol. 2, no. 2, p. 115

Catharina Goedecke
Why Does Iodine Turn Starch Blue?
ChemViews Magazine 2016

Most cited articles from each ChemPubSoc Europe, ACES, and GDCh journal



Eric J. Popczun, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis, Raymond E. Schaak
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Angew. Chem. Int. Ed. 2014, vol. 53, pp. 5427–5430

Philippe Compain, Anne Bodlenner
The Multivalent Effect in Glycosidase Inhibition: A New, Rapidly Emerging Topic in Glycoscience [Minireview]
ChemBioChem 2014, vol. 15, pp. 1239–1251

Zhi-Yuan Gu, Jihye Park, Aaron Raiff, Zhangwen Wei, Hong-Cai Zhou
Metal–Organic Frameworks as Biomimetic Catalysts [Minireview]
ChemCatChem 2014, vol. 6, pp. 67–75

Anthony J. Arduengo, Roland Krafczyk
Auf der Suche nach Stabilen Carbenen [Organische Chemie]
Chem. Unserer Zeit 1998, vol. 32, pp. 6–14

Félix Sancenón, Lluís Pascual, Mar Oroval, Elena Aznar, Ramón Martínez-Máñez
Gated Silica Mesoporous Materials in Sensing Applications [Review]
ChemistryOpen 2015, vol. 4, pp. 418–437

Jun Pu, Tingting Wang, Haiyang Wang, Yao Tong, Chenchen Lu, Wei Kong, Zhenghua Wang
Direct Growth of NiCo2S4 Nanotube Arrays on Nickel Foam as High-Performance Binder-Free Electrodes for Supercapacitors [Full Paper]
ChemPlusChem 2014, vol. 79, pp. 577–583

Francisco Trespalacios, Ignacio E. Grossmann
Review of Mixed-Integer Nonlinear and Generalized Disjunctive Programming Methods [Review]
Chemie Ingenieur Technik 2014, vol. 86, pp. 991–1012

Xiaosi Zhou, Yu-Guo Guo
Highly Disordered Carbon as a Superior Anode Material for Room-Temperature Sodium-Ion Batteries [Communication]
ChemElectroChem 2014, vol. 1, pp. 83–86

Chuanxi Wang, Zhenzhu Xu, Chi Zhang
Polyethyleneimine-Functionalized Fluorescent Carbon Dots: Water Stability, pH Sensing, and Cellular Imaging [Full Paper]
ChemNanoMat 2015, vol. 1, pp. 122–127

Matthew N. Hopkinson, Basudev Sahoo, Jun-Long Li, Frank Glorius
Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis [Minireview]
Chemistry – A European Journal 2014, vol. 20, pp. 3874–3886

Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong
Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)–H Bonds [Focus Review]
Chemistry – An Asian Journal 2014, vol. 9, pp. 26–47

Derong Cao, Herbert Meier
Pillar[n]arenes—a Novel, Highly Promising Class of Macrocyclic Host Molecules [Focus Review]
Asian Journal of Organic Chemistry 2014, vol. 3, pp. 244–262

Daniel Gallenkamp, Kathy A. Gelato, Bernard Haendler, Hilmar Weinmann
Bromodomains and Their Pharmacological Inhibitors [Review]
ChemMedChem 2014, vol. 9, pp. 438–464

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera
The Bright Future of Unconventional σ/π-Hole Interactions [Review]
ChemPhysChem 2015, vol. 16, pp. 2496–2517

Ksenia S. Egorova, Valentine P. Ananikov
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization [Review]
ChemSusChem 2014, vol. 7, pp. 336–360

Shunichi Fukuzumi, Dachao Hong
Homogeneous versus Heterogeneous Catalysts in Water Oxidation [Microreview]
Eur. J. Inorg. Chem. 2014, pp. 645–659

Fabien Toulgoat, Sébastien Alazet, Thierry Billard
Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept [Microreview]
Eur. J. Org. Chem. 2014, pp. 2415–2428

David Schweinfurth, Naina Deibel, Fritz Weisser, Biprajit Sarkar
Mit Klick zu neuen Liganden [Magazin]
Nachr. Chem. 2011, vol. 59, pp. 937–941

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