Recyclable Lithium-Ion Capacitors

  • Author: Charlotte Koschnick
  • Published: 03 January 2018
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
  • Source / Publisher: Nature Materials/Nature Publishing Group
thumbnail image: Recyclable Lithium-Ion Capacitors

Supercapacitors are high power energy storage devices capable of sustaining millions of charge/discharge cycles. The development of hybrid capacitors such as lithium-ion capacitors (LICs), in which the negative activated carbon electrode is replaced by a lithium intercalated compound, led to capacitors requiring less active material, wider cell voltages, and greater recyclability. However, since the positive electrode of LICs is not a lithium-ion source, prelithiation of the negative electrode is difficult.

T. Brousse, Université de Nantes, France, and colleagues Have developed a strategy to prelithiate the negative electrode of LICs using a 3,4-dihydroxybenzonitrile dilithium salt (Li2DHBN). The lithium enolate can be added to the active carbon of the electrode and irreversibly oxidized to the ortho-quinone species when a potential is applied. Upon oxidation, lithium is extracted and the oxidized species dissolves in the electrolyte yielding a cell that operates as a LIC.

The researches demonstrated that the LICs fabricated by prelithiation with Li2DHBN maintained a high energy density (40–60 Wh kg–1 per total mass of electrode material) and sustained long-term cycling. Further, no auxiliary lithium electrode is needed favouring a much safer electrochemical system. The method presented offers a pathway for a greener hybrid capacitor.


 

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