Alkene Hydroacylation with Triple Catalysis
Branched-selective hydroacylation uses cooperative photoredox, cobalt, and N-heterocyclic carbene catalysis
Total Synthesis of Foeniculoxin
Toxin produced by a fungus that causes disease in fennel plants
Angewandte Chemie 49/2022: Chemical Approaches
Overview of the latest issue of Angewandte Chemie
Synthesis of Halophosphorylated Dihydrofurans
Cascade cyclization of γ-hydroxyl ynones
Electrochemical Carboxylation of Arenes with CO2
Direct, metal-free, and site-selective reaction
Angewandte Chemie 48/2022: Expanding the Repertoire
Overview of the latest issue of Angewandte Chemie
Direct Reaction of Nitroarenes and Thiols Gives Sulfonamides
Photoexcitation of nitroarenes leads to oxygen transfer from a nitro group to a thiol group
Conformers Undergo Different Reactions Controlled by Quantum Tunneling
Unprecedented reaction gives distinct rearrangement products that cannot be explained by classical reactivity models
![Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes](https://www.chemistryviews.org/wp-content/uploads/2022/11/bicyclohexanes-125x94.jpg)
Visible-Light-Driven Synthesis of Bicyclo[2.1.1]hexanes
Intramolecular crossed [2 + 2] photocycloaddition leads to useful building blocks
Primeval Reaction Pathways
Some reactions in the reverse Krebs cycle can be run under meteorite catalysis
Cycloparaphenylenes with a Twist
Alkene insertion into cycloparaphenylenes gives circular molecules with Möbius topology
![Quasi-[7]Circulenes Prepared from Aza[5]helicenes](https://www.chemistryviews.org/wp-content/uploads/2022/11/quasicirculene-125x94.jpg)
Quasi-[7]Circulenes Prepared from Aza[5]helicenes
Electrophilic borylation followed by formation of an N→B bond
In-situ Phosgene Synthesis from Chloroform
Photochemical oxidation of chloroform in a continuous flow reactor for on-demand phosgenation
Dimethyl Ether Activates Metal–Organic Frameworks
Gentle method for MOF activation removes guest solvent molecules and prevents structural collapse
TiCl4-Catalyzed Reduction of Carboxylic Acids to Alcohols
Safe reduction protocol for a broad range of acids using NH3BH3
Styrene Derivatives Synthesized from Allyl Silanes
Allyl silanes isomerized to alkenyl silanes, followed by a Hiyama coupling
Angewandte Chemie 47/2022: Circularly Polarized
Overview of the latest issue of Angewandte Chemie
Boron-Functionalized Heptaphosphide Zintl Cluster
Transition-metal-free catalyst for hydroborations
Most Accessed Articles: October 2022
Highlights from Chemistry Europe, ACES, and GDCh journals