Lighting Up Carbon Monoxide

  • Author: Joseph Unsay
  • Published Date: 20 January 2017
  • Source / Publisher: Chemistry – A European Journal/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
thumbnail image: Lighting Up Carbon Monoxide

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Exposure to carbon monoxide (CO) can lead to circulatory system failure, brain damage, and death. Early detection of this odorless and colorless gas can prevent accidental exposure. However, current detection technologies are often costly and have issues with long-term reliability.


Herbert Plenio, Technical University Darmstadt, Germany, and colleagues used iridium complexes such as [IrCl(cod)(bdp-NHC)] to detect CO. These complexes include a fluorescent molecule, bdp (1,3,5,7,8-pentamethyl-BODIPY), and a cyclooctadiene (cod) ligand. Reaction with CO leads to the substitution of the cyclooctadiene ligand, which then increases the fluorescence intensity of the bdp ligands. By exchanging the Cl ion for different thiol-containing molecules, the researchers were able to tune the fluorescence response (up to an increase of 26 times after exposure to CO).


The team then tested the iridium complex using gaseous samples. Filter papers soaked with the complex showed a remarkable response to air with sub-lethal levels of CO (pictured right). The use of fluorescence could be a starting point for making simpler probes that detect harmful molecules in air.


 

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Magazine of Chemistry Europe (16 European Chemical Societies) published by Wiley-VCH