What Happens When You Put a Nail Through a Lithium Battery?

  • ChemPubSoc Europe Logo
  • Author: Rosalba A. Rincón
  • Published Date: 05 August 2019
  • Source / Publisher: Batteries & Supercaps/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: What Happens When You Put a Nail Through a Lithium Battery?

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Lithium-ion batteries have a reputation for exploding when they are exposed to conditions like mechanical deformation, over-charging, or heat. This is due to the high flammability of the organic electrolyte. Nail penetration is often used as an extreme test for evaluating thermal runaway by inducing an internal short-circuit. The contact resistance between the nail and the electrodes leads to heat generation. So far, researchers have usually assumed a uniform resistance and have not measured it experimentally.


Yuan Yang, Columbia University, New York, USA, and colleagues have experimentally determined for the first time the heterogeneous short-circuit contact resistance between a nail and two different electrodes, a Cu/graphite electrode and an Al/LiCoO2 electrode. The resistances are 2.5±1.5 Ω and 20.3±12.4 Ω, respectively. The resistance varies throughout the battery. This heterogeneity can significantly increase the temperature rise compared to homogeneous contact resistance. 


The resistance depends on the layer sequence: Heat generation in the top Al-based cathode layer (pictured in orange) is the highest among the battery layers. The researchers propose that having the Cu-based anode as the outermost layer in a battery stack can reduce heat generation during nail penetration. The results shed light onto a long-term myth in the battery community and provide direction for improving the safety of Li-ion batteries.


 

 

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