N,S-doped MOF Electrocatalysts for Water Oxidation

  • Author: ChemSusChem
  • Published Date: 15 April 2020
  • Source / Publisher: ChemSusChem/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: N,S-doped MOF Electrocatalysts for Water Oxidation

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Hydrogen production via water splitting is a promising path to clean energy. However, this conversion suffers from a kinetically sluggish half-reaction: the oxygen evolution reaction (OER). It is, thus, important to find active and durable earth-abundant OER electrocatalysts to improve the overall efficiency of water splitting.

Jun-Ling Song, Jiangnan University, Wuxi, China, and colleagues have developed an efficient N,S-co-doped electrocatalyst for the OER based on a supermicroporous CoFe-based metal–organic framework (MOF) nanomaterial that can be quickly synthesized in high yield using a one-pot solvothermal reaction. The team used thiourea as both a nitrogen- and a sulfur source for doping, syringic acid (SyA or 4-hydroxy-3,5-dimethoxybenzoic acid) as a ligand, and CoCl2 and FeSO4 to prepare the MOF in dimethylformamide (DMF) at 150 °C.

This resulting catalyst shows good performance with a low overpotential and long-term electrochemical durability (at least 16 hrs) for the OER in alkaline media. The high performance is attributed to the N,S-co-doping, which facilitates the formation of active species. According to the researchers, this enables the direct use of MOF nanomaterials as catalysts for the OER and could also provide a new strategy for the design of other highly efficient hetero-doped MOF catalysts.



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