From Dark to Light: Fluorescent Detection of Hg2+

  • Author: Sarah Millar
  • Published Date: 18 December 2013
  • Source / Publisher: Chemistry – A European Journal/Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
thumbnail image: From Dark to Light: Fluorescent Detection of Hg<sup>2+</sup>

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The development of efficient luminescent materials in the aggregated or solid state is a topic of current interest on account of their potential applications in the fields of electronics, optics, biological sciences, and as simple sensors for the presence of toxic heavy-metal ions, such as Hg2+. However, although fluorescent materials are highly emissive in the solution state, they become weakly emissive or even non-emissive when aggregated in the condensed phase. This aggregation-caused quenching (ACQ) effect has significantly limited the high-tech application of conventional fluorophores.

In 2001, Ben Zhong Tang, Hong Kong University of Science & Technology, and colleagues observed the phenomenon of aggregation-induced emission (AIE) in some propeller-shaped molecules that is the exact opposite of the ACQ effect [1].

Tang and colleagues now report a simple strategy to tune the emission behavior of a tetraphenylethene (TPE)-functionalized benzothiazolium salt (TPEBe–X). All the TPEBe–X luminogens showed faint red emission in solution, but by varying the counteranion from I to ClO4 or PF6, TPEBe–X changed its emission behavior from ACQ to AIE.

Addition of Hg2+ into the aqueous solution of TPEBe–I enhanced the light emission 80-fold; this result suggests that this salt could make an excellent fluorescent Hg2+ sensor with high sensitivity and selectivity.

The sensing process can also be performed in a solid film with a detection limit of 1 μM, thereby demonstrating the use of AIE compounds for Hg2+ detection in real-world conditions and opening a new way to detect Hg2+ in aqueous solution based on the AIE mechanism.

[1] J. Luo, Z. Xie, J. W. Y. Lam, L. Cheng, H. Chen, C. Qiu, H. S. Kwok, X. Zhan, Y. Liu, D. Zhu, B. Z. Tang, Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole, Chem. Commun. 2001, 1740–1741. DOI: 10.1039/B105159H

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