Light-Controlled Phase Tag

  • Author: Angew. Chem. Int. Ed.
  • Published Date: 14 May 2010
  • Source / Publisher: Angew. Chem. Int. Ed./Wiley-VCH
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
thumbnail image: Light-Controlled Phase Tag

Supporting Information

Guiyan Liu and Jianhui Wang report the use of light to switch a metathesis catalyst between a polar and a nonpolar phase, plus they show that the catalyst can be recycled – a feature that offers exciting prospects and that may lead to industrial interest.

The team from Tianjin University, China, used a Grubbs-Hoveyda-type catalyst tagged with a UV-active group and the photoreaction resulted in drastic changes in the polarity and solubility of the catalyst. This tagged complex had significant catalytic activity in ring-closing metathesis reactions and was recycled several times. Features of the process include: the uses light as the driving force, no temperature changes, no need for expensive supporting media.

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