Probe Ionic Liquid Acidity

  • Author: Xin Su
  • Published: 05 June 2014
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
  • Source / Publisher: Chemical Communications/RSC
  • Associated Societies: Royal Society of Chemistry (RSC), UK
thumbnail image: Probe Ionic Liquid Acidity

As an extensively used reaction medium in both research and industrial applications, ionic liquids (ILs) can facilitate a number of reactions, including proton transfer, which is very common in industry. The reactivity of proton transfer is highly dependent on the acidity of the ILs, a property yet to be well characterized.

Tom Welton and co-workers, Imperial College London, UK, have reported a convenient method to measure IL acidity between –1 to –9 of the Hammett scale with NMR technique using mesityl oxide as a probe. They relied on the 13C chemical shift difference (∆δ) between the α- and β-carbons of mesityl oxide to extrapolate deduce IL acidity from IL-acid systems.

This approach evades the requirement of colorless samples and the interference of impurities, general problems present in spectrophotometric methods. With a wide measurable acidity range, it also enables quick screening of a large variety of ILs and IL acid solutions.

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