Syngas from Water, CO2 and Sunlight

Syngas from Water, CO2 and Sunlight

Author: ChemistryViews

The need to transport solar energy from the sunny and uninhabited regions of the earth’s sunbelt to the world’s industrialized and populated centers, has motivated the search for ways to transform sunlight into chemical energy carriers in the form of storable and transportable liquid fuels, such as gasoline and jet fuel.

Aldo Steinfeld and co-workers, ETH Zurich, Switzerland, in collaboration with Caltech, USA, have developed a promising catalyst and associated reactor technology based on a solar-driven thermochemical cycle for splitting CO2 and H2O.

The 2-step cycle requires thermally reducing non-stoichiometric cerium oxide at above 1500 °C and re-oxidizing it with H2O and CO2 at below 900 °C to produce syngas, the precursor of liquid hydrocarbon fuels. The solar reactor used consists of a cavity-receiver with a small windowed aperture for the access of concentrated solar radiation. A porous, monolithic ceria cylinder is placed inside the cavity and subjected to multiple heat-cool cycles under appropriate gases to induce fuel production.

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