Difficult-to-achieve uniform coating prepared using hydrogen peroxide as a precipitant

Peroxide-Based Coating Approach Gives Nanoshells with Alkali Metals

Polarity of Over 550 Radicals Calculated
Electrophilicity/nucleophilicity of common open-shell synthetic intermediates calculated and experimentally validated

Frustrated Lewis Pair Anchored on Copper Nanoclusters for Catalysis
Immobilized catalysts for hydrogenation reactions provide high activity and regioselectivity

Enantioselective Alkylation of Primary Phosphines
Nickel-catalyzed asymmetric transformation using alkyl halides gives P-stereogenic secondary phosphine-boranes with high enantioselectivity

Twisting Planar Aromatic Compounds into a Figure Eight
Oxidative cleavage of an internal double bond of a polycyclic aromatic hydrocarbon (PAH) gives a figure-eight-shaped macrocycle

Gold(I) Catalysis Provides Access to Alkynyl C-Glycosides
Silyl-assisted, gold(I)-catalyzed transformation gives useful precursors for complex glycosides

New Strategy to Access Ketyl Radical Anions
Coupling of aldehydes and alkenes via α-hydroxy sulfinate and ketyl radical anion intermediates

2-Aminopyridines Made from Bench-Stable Reagents
2-Halopyridinium ketene hemiaminals allow for nucleophilic aromatic substitutions with amines

Organocatalyst for Electrochemical Hydrogen Evolution
Metal-free, N-heterocyclic phosphine (NHP)-type organocatalyst provides high activity

Metal-Free Synthesis of (Per)Fluoroalkyl-Functionalized Nitro-Indoles
Base-catalyzed intramolecular cyclization of N-acyl amides provides access to indole derivatives