Nickel-catalyzed asymmetric transformation using alkyl halides gives P-stereogenic secondary phosphine-boranes with high enantioselectivity

Oxidative cleavage of an internal double bond of a polycyclic aromatic hydrocarbon (PAH) gives a figure-eight-shaped macrocycle

Silyl-assisted, gold(I)-catalyzed transformation gives useful precursors for complex glycosides

Coupling of aldehydes and alkenes via α-hydroxy sulfinate and ketyl radical anion intermediates

2-Halopyridinium ketene hemiaminals allow for nucleophilic aromatic substitutions with amines

Metal-free, N-heterocyclic phosphine (NHP)-type organocatalyst provides high activity

Base-catalyzed intramolecular cyclization of N-acyl amides provides access to indole derivatives

Pincer bismuthinidene complexes allow reactions with inert greenhouse gas and the related PhSF₅

Amino-functionalized derivatives of the well-known BINOL ligands oxidized to induce a skeletal rearrangement

"Plasmid addiction system" ensures successful biosynthesis