Substantial potential differences observed between identical gold nanoparticles with 2- or 4-mercaptobenzoic acid ligands

How Do Capping Agents Affect the Redox Potential of Nanoparticles?

Enantioselective Hydroxylation of Tertiary Propargylic C–H bonds
Manganese-catalyzed enantio-differentiating hydroxylation in acyclic systems

Vanadium-Dependent Chloroperoxidase for Regioselective Halogenation
Lavanducyanin halogenase (LvcH) discovered and used in chemoenzymatic synthesis

Copper-Catalyzed Amination of Base-Sensitive Aryl Bromides
Expanding the scope of copper-catalyzed C–N coupling reactions

A New Path to Benzocycloheptenes
Base-promoted (5+2) annulation of 2-(alkynylaryl)acetonitriles and arylalkynes

Nickel Catalysis for Asymmetric Aryl Addition to Sulfinylamines
Nickel catalyst with a chiral bisoxazoline ligand for the 2,3-addition of arylboronic acids to sulfinylamines

Triarylimidazole-Based Drugs Activated by Light
New strategy for caging bioactive triarylimidazoles uses a dialkylamino unit as a photoremovable group

Benzyl Halides Coupled with Electron-Deficient Alkenes
Catalytic lutidine substitutes halides and allows for a general set of photocatalytic conditions

Iron Complexes for Olefin Metathesis
Isolation of a metallacyclobutane provides evidence that iron complexes adhere to the Chauvin olefin metathesis mechanism

S-Trifluoromethylation of Aromatic Thiols
Visible-light-mediated method uses trifluoromethanesulfonyl chloride as an inexpensive trifluoromethyl radical source