Supramolecular capsules that control the coordination geometry of a metal could provide new routes to control the reactivity of catalysts

New Strategy for Controlling Catalyst Reactivity

A Nestlike Metallamacrocycle
Largest cluster complex supported by butylsulfonylcalix[4]arene ligands has unusual topology and antiferromagnetic properties

Most Accessed Articles: August 2011
The most-accessed chemistry articles from ChemPubSoc Europe and GDCh journals for August 2011

Carrier Systems for CO
Polymers that release CO upon irradiation could see use as treatment for cancer or inflammation

Awakening of a Sleeping Beauty in Organometallic Chemistry
A convenient synthesis of cyclopentadienylgallium opens the door for GaCp to become a versatile reagent in organometallic chemistry

Best in Class!
Study of the structure–activity relationship of steroid sulfatase inhibitors explains why Irosustat is the best in its class

Converting CO2 to Methyl Acrylate
Nickel catalyst can produce methyl acrylate in up to 56 % yield from carbon dioxide and ethene

Remarkable Carbon Capture by Borocarbonitrides
The large uptake of both CO2 and CH4 by BC2N betters the performance of graphenes and activated charcoal

Aromatic Halogenation Under Mild Conditions
The selective halogenation of ligands of a trinuclear copper complex has been obtained under extremely mild conditions

New Family of N-Heterocyclic Carbenes for Organocatalysis
New family of NHCs suitable for benzoin-type coupling reactions and might enable new or improved organocatalytic processes