Highlights from Chemistry Europe, ACES, and GDCh journals

Most Accessed Articles: April 2025

Electrochemical Co-Catalyzed C─H Activation for Enantioselective Formation of Indoles With Two Different Chiral C─N Axes
Lutz Ackermann and colleagues have introduced a new class of chiral oxazoline ureas as κ²-N,O-preligands for enantioselective transition metal catalysis

Mild Aqueous Synthesis of Thioamides
Chemoselective thioamidation of potassium acyltrifluoroborates (KATs) and amines using elemental sulfur in aqueous solution

CO₂ Release from Aralkylamine–CO₂ Complexes at Room Temperature
F. Inagaki and R. Murakami discuss a recent study demonstrating that CO₂ can be spontaneously released from aralkylamine–CO₂ complexes, representing a promising advancement in CO₂ capture technology

Total Synthesis of Ectocarpin A
A fully enantioselective total synthesis of ectocarpin A, a new oxylipin, in 12 steps starting from tetrahydro-1H-cyclopentafuranone

Azadiene-Linked COFs for Photocatalysis
Azadiene-linked COFs with extended π-conjugation act as efficient, metal-free photocatalysts for selective oxidations

C-Scorpionate Complexes Catalyze Nitroarene Reduction for the First Time
Luísa Martins, Portugal, discusses a recently published study exploring the effects of catalysts, solvents, and reducing agents on the reaction kinetics of nitroarene reduction

Most Accessed Articles: March 2025
Highlights from Chemistry Europe, ACES, and GDCh journals

Unorthodox Catalysts for Diels-Alder Reactions
E. H. Tiekink, R. Verdijk, T. A. Hamlin, F. M. Bickelhaupt used quantum chemistry to show that hydrogen-bonding organocatalysts speed up the Diels–Alder reaction

Method Simplifies Deprotection and Modification of N-Heterocycles
A mild, efficient system for selectively deprotecting and modifying N-heterocycles in a single step