Stabilization of the cyclo-P₅⁻ anion in the solid state through complexation of the alkaline metal cation with [2.2.2]cryptand, providing the first crystallographic characterization and detailed spectroscopic analysis

Cyclo-P₅⁻ Revisited: Solid-State Characterization

Angewandte Chemie 13/2025: Dispersed Sites
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![Unique Features of the Dinuclear Zirconocene Complex [(Cp₂Zr)₂(µ-Me)(µ-C₂Ph)]](https://www.chemistryviews.org/wp-content/uploads/2025/03/202503_Dinuclear-Zirconocene-Complex-125x94.png)
Unique Features of the Dinuclear Zirconocene Complex [(Cp₂Zr)₂(µ-Me)(µ-C₂Ph)]
The dinuclear zirconocene alkynyl methyl complex represents a multifaceted platform for the activation of small molecules

Conversion of Methane And Benzene C–H Bonds to C–Be And H–Be Bonds
The properties of the beryllyl ligands facilitate this novel C–H elementation reaction to an extent that is not possible with boron analogues

Lanthanoid-Carbodiimide Chemistry
The study examines carbodiimide reactions with LnII aryloxides and the reactivity of carbodiimide with organolanthanoid alkynyl complexes

Mn(I)-Catalyzed Cyclotrimerization of Triynes
First use of the manganese(I)–carbonyl complex MnBr(CO)5 as a catalyst for the [2 + 2 + 2] cycloaddition of functionalized triynes under mild photochemical conditions

Oxygen for Mars? Electrochemical Process Splits CO₂ Directly Into O₂
Electrochemical process splits CO₂ directly into carbon and oxygen and could produce oxygen underwater or in space without the need for strict pressure or temperature conditions

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Inorganic Cyclopentadienyl Analogues
Synthesis of two complexes containing planar Sb₅ and Bi₅ rings under mild reaction conditions

Angewandte Chemie 12/2025: Chemistry for Health and Wealth
Overview of the latest issue of Angewandte Chemie