Cross-coupling reaction of (hetero)aryl chlorides
Author Archive for: Dinesh Talwar (10)
Dual Photoredox/Halide Catalysis
Trifluoromethylthiolation of styrenes using visible light
Continuous-Flow N-Heterocyclic Carbenes
Straightforward continuous-flow setup for the generation of free NHCs, powerful tools especially in organometallic chemistry
Copper Trifluoromethylating Reagent
Decarboxylative trifluoromethylation of (hetero)aryl halides
Symbiodinolide's C79-C104 Fragment
Stereoselective synthesis of the proposed C79-C104 fragment of symbiodinolide, a polyol marine natural product
Formylation with Carbon Dioxide
Aromatic aldehydes by formylation of aryl bromides with carbon dioxide
Rhodium-Catalyzed Functionalization of Arenes
Umpolung converts nucleophilic arenes into electrophilic arenes in a Rh-catalyzed C-H activation
Sandmeyer-Type Trifluoromethylation
Syntheses with late-stage introduction of fluorinated moieties
Ketone Synthesis Without Free CO
Palladium-catalyzed carbonylative Suzuki coupling
Phosphine-Free Amination
Intermolecular amination of unactivated C-H bonds using a palladium catalyst