Ni-Catalyzed Reductive Carboxylation

Ni-Catalyzed Reductive Carboxylation

Author: Veronika Belusa

Ruben Martin, Institute of Chemical Research of Catalonia (ICIQ), Tarragona, Spain, and colleagues have developed a novel, mild, and user-friendly Ni-catalyzed regiodivergent carboxylation of allyl acetates with CO2. This operationally simple method is the first regiodivergent catalytic reductive coupling of allyl electrophiles. Moreover, the protocol provides consistent evidence that the ligand dictates the selectivity pattern.

According to the researchers, this study will lead to new knowledge in catalyst design using unconventional ligand backbones.

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