Rapid Production of Porous Films

  • Author: Georg R. Meseck
  • Published: 19 October 2016
  • Copyright: Wiley-VCH Verlag GmbH & Co. KGaA
  • Source / Publisher: Journal of the American Chemical Society/ACS Publishing
  • Associated Societies: American Chemical Society (ACS), USA
thumbnail image: Rapid Production of Porous Films

Hierarchical porous materials often serve as a carrier for functional nanoparticles in applications like catalysis, sensing, or energy storage. However, it is a major challenge to find methods to prepare such hybrid materials at an industrial scale.

James Watkins, University of Massachusetts, Amherst, USA and colleagues have developed a simple strategy to rapidly coat large areas of polyethylene terephthalate (PET) with porous hybrid films containing gold nanoparticles in a silica/carbon matrix. The PET substrate is coated with a mixture of gold nanoparticles, a block copolymer as a sacrificial template, and polyhedral oligomeric silsesquioxane (POSS) as a silica precursor.

The coated samples are heated with a xenon flash lamp using the localized surface plasmon resonance of the gold nanoparticles. This photothermal treatment leads to the removal of the block copolymer and oxidation of POSS to a silica network, while the gold nanoparticles remain well dispersed. The resulting thin films exhibit mesopores on the surface and a foam-like macroporous network underneath.

According to the researchers, this method can be scaled up, is compatible with roll-to-roll manufacturing for flexible devices, and can be adapted for other porous hybrid films with different functionalities.


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